data_global
_amcsd_formula_title 'As6 H30 N4 O34 V4'
loop_
_publ_author_name
'Durif A'
'Averbuch-Pouchot M'
_journal_name_full 'Acta Crystallographica, Section B'
_journal_volume 35 
_journal_year 1979
_journal_page_first 1441
_journal_page_last 1444
_publ_section_title
;
 Structure d'un arsenato vanadate d'ammonium. (NH4)4H6(As6V4O30)(H2O)4
 _cod_database_code 1007036
;
_database_code_amcsd 0009671
_chemical_formula_sum 'As3 V2 N2 O17'
_cell_length_a 14.40
_cell_length_b 16.31
_cell_length_c 9.831
_cell_angle_alpha 90
_cell_angle_beta 136.29
_cell_angle_gamma 90
_cell_volume 1595.503
_exptl_crystal_density_diffrn      2.609
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
As1   0.82430   0.50000   0.28590
As2   0.00000   0.27438   0.50000
As3   0.75190   0.00000   0.40170
V1   0.51070   0.90410   0.76700
N1   0.15070   0.21550   0.22700
O1   0.30390   0.50000   0.29490
O2   0.11000   0.00000   0.35640
O3   0.15710   0.00000   0.14660
O4   0.37280   0.28370   0.31190
O5   0.41510   0.00000   0.52150
O6   0.43410   0.00000   0.09860
O7   0.34450   0.08530   0.20990
O8   0.07270   0.32600   0.45440
O9   0.15840   0.41300   0.32570
O10   0.41940   0.16010   0.05940
O11   0.44460   0.36060   0.16600