data_global
_amcsd_formula_title 'O46 Sn10 W16'
loop_
_publ_author_name
'Goreaud M'
'Labbe P'
'Raveau B'
_journal_name_full 'Acta Crystallographica, Section B'
_journal_volume 36 
_journal_year 1980
_journal_page_first 15
_journal_page_last 19
_publ_section_title
;
 A mixed-valence tungsten oxide of divalent tin: Sn10 W16 O46
 _cod_database_code 1001079
;
_database_code_amcsd 0009696
_chemical_formula_sum 'Sn5 W8 O23'
_cell_length_a 7.667
_cell_length_b 7.667
_cell_length_c 18.640
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 948.915
_exptl_crystal_density_diffrn      8.513
_symmetry_space_group_name_H-M 'P 63/m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-x+y,-x,1/2-z'
  'x-y,x,1/2+z'
  'y,-x+y,-z'
  '-y,x-y,z'
  'x,y,1/2-z'
  '-x,-y,1/2+z'
  'x-y,x,-z'
  '-x+y,-x,z'
  '-y,x-y,1/2-z'
  'y,-x+y,1/2+z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Sn1   0.19280   0.31240   0.25000
Sn2   0.33333   0.66667   0.07050
W1   0.22453   0.05645   0.05991
W2   0.33333   0.66667   0.67023
O1   0.45900   0.30100   0.25000
O2   0.46200   0.13100   0.11950
O3   0.12900   0.41200   0.00600
O4   0.00000   0.00000   0.00000
O5   0.18600   0.24500   0.12430
O6   0.00000   0.00000   0.25000