data_global _amcsd_formula_title 'Cd2 Cl6 H24 Ni O12' loop_ _publ_author_name 'Leclaire A' 'Borel M' _journal_name_full 'Acta Crystallographica, Section B' _journal_volume 36 _journal_year 1980 _journal_page_first 3088 _journal_page_last 3090 _publ_section_title ; Structure de l'Hexachlorure de Dicadmium et de Nickel Dodecahydrate _cod_database_code 1001169 ; _database_code_amcsd 0009726 _chemical_formula_sum 'Cd2 Ni Cl6 O12' _cell_length_a 24.4219 _cell_length_b 22.3429 _cell_length_c 7.5416 _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_volume 4115.120 _exptl_crystal_density_diffrn 2.222 _symmetry_space_group_name_H-M 'F d d 2' loop_ _space_group_symop_operation_xyz 'x,y,z' 'x,1/2+y,1/2+z' '1/2+x,y,1/2+z' '1/2+x,1/2+y,z' '1/4+x,1/4-y,1/4+z' '1/4+x,3/4-y,3/4+z' '3/4+x,1/4-y,3/4+z' '3/4+x,3/4-y,1/4+z' '1/4-x,1/4+y,1/4+z' '1/4-x,3/4+y,3/4+z' '3/4-x,1/4+y,3/4+z' '3/4-x,3/4+y,1/4+z' '-x,1/2-y,1/2+z' '-x,-y,+z' '1/2-x,1/2-y,+z' '1/2-x,-y,1/2+z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z Cd1 0.24622 0.00365 0.00000 Ni1 0.25000 0.25000 0.21648 Cl1 0.30506 0.05522 0.25095 Cl2 0.28987 0.06805 -0.25000 Cl3 0.16767 0.08018 0.05064 O1 0.32005 -0.06301 -0.03829 O2 0.17013 0.22183 0.23042 O3 0.26691 0.18910 0.02849 O4 0.26828 0.18748 0.41027 O5 0.34427 -0.15285 0.19255 O6 0.31748 0.22600 -0.27721