data_global
_amcsd_formula_title '[C(NH2)3]6[Ce(CO3)5]*4H2O'
loop_
_publ_author_name
'Marsh R E'
'Herbstein F H'
_journal_name_full 'Acta Crystallographica, Section B'
_journal_volume 44 
_journal_year 1988
_journal_page_first 77
_journal_page_last 88
_publ_section_title
;
 More space group changes
;
_database_code_amcsd 0009814
_chemical_formula_sum 'C11 Ce O19 N18 H8'
_cell_length_a 16.05
_cell_length_b 13.14
_cell_length_c 16.631
_cell_angle_alpha 90
_cell_angle_beta 108.10
_cell_angle_gamma 90
_cell_volume 3333.866
_exptl_crystal_density_diffrn      1.666
_symmetry_space_group_name_H-M 'C 1 2/c 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,1/2+z'
  '1/2+x,1/2-y,1/2+z'
  '-x,y,1/2-z'
  '1/2-x,1/2+y,1/2-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
C13   0.33450   0.37320   0.20680   0.02620
C2   0.50000   0.05620   0.25000   0.02100
C45   0.50100   0.27890   0.07830   0.03210
C68   0.32100   0.38970  -0.01338   0.03240
C711   0.11240   0.53450  -0.00380   0.03460
C910   0.37170   0.62340   0.10110   0.04010
Ce   0.50000   0.27420   0.25000   0.01540
O1133   0.26020   0.41900   0.18450   0.03990
O1232   0.34120   0.27940   0.19440   0.03950
O1331   0.40550   0.42130   0.24700   0.02760
O2123   0.43410   0.10730   0.20370   0.02840
O22   0.50000  -0.04100   0.25000   0.03420
O4152   0.55680   0.22380   0.13600   0.03480
O4251   0.45260   0.33830   0.10570   0.04850
O4353   0.49440   0.27150   0.00120   0.04570
Wat14   0.30160   0.65930  -0.11500   0.06180
Wat23   0.13550   0.67350  -0.24600   0.05970
N6182   0.30730   0.31320  -0.08730   0.04950
N6283   0.39870   0.43330  -0.11440   0.04070
N6381   0.25400   0.42290  -0.19740   0.03870
N71113   0.14190   0.56400   0.07620   0.04150
N72112   0.14800   0.45390  -0.02850   0.04840
N73111   0.04930   0.58580  -0.05780   0.04010
N91103   0.39620   0.61970   0.18410   0.04980
N92102   0.37910   0.54210   0.05990   0.04720
N93101   0.34080   0.70870   0.06210   0.05420