data_global
_amcsd_formula_title 'Na.5(NH4)5Al6Si10O32*9H2O'
loop_
_publ_author_name
'Gualtieri A F'
_journal_name_full 'Acta Crystallographica, Section B'
_journal_volume 56 
_journal_year 2000
_journal_page_first 584
_journal_page_last 593
_publ_section_title
;
 Study of NH4+ in the zeolite phillipsite by combined synchrotron powder
 diffraction and IR spectroscopy
 Sample: 1
;
_database_code_amcsd 0009922
_chemical_compound_source 'Vallerano, Rome, Italy'
_chemical_formula_sum 'Na.26 N2.38 (Al3 Si5) O20.64 H18.8'
_cell_length_a 10.0507
_cell_length_b 14.2016
_cell_length_c 8.7281
_cell_angle_alpha 90
_cell_angle_beta 125.123
_cell_angle_gamma 90
_cell_volume 1018.975
_exptl_crystal_density_diffrn      1.988
_symmetry_space_group_name_H-M 'P 1 21/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2-y,z'
  '-x,1/2+y,-z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
NaII*   0.67630   0.19230   0.45500   0.13000   0.03000
NI   0.87530   0.25000   0.17160   1.00000   0.08000
NII   0.40680   0.68910   0.48800   0.69000   0.03700
AlT1   0.74490   0.02440   0.29060   0.30000   0.04200
SiT1   0.74490   0.02440   0.29060   0.70000   0.04200
AlT2   0.42130   0.13830   0.00630   0.60000   0.03500
SiT2   0.42130   0.13830   0.00630   0.40000   0.03500
AlT3   0.05550   0.00550   0.28140   0.15000   0.02700
SiT3   0.05550   0.00550   0.28140   0.85000   0.02700
AlT4   0.12490   0.13350   0.04790   0.45000   0.03100
SiT4   0.12490   0.13350   0.04790   0.55000   0.03100
O1   0.13900   0.08720   0.22560   1.00000   0.03900
O2   0.65030   0.57240   0.18070   1.00000   0.02000
O3   0.61060   0.10590   0.16840   1.00000   0.05100
O4   0.01550   0.91100   0.16070   1.00000   0.07700
O5   0.89520   0.05170   0.26670   1.00000   0.03700
O6   0.32220   0.37490   0.11460   1.00000   0.03900
O7   0.79640   0.46880   0.50900   1.00000   0.03700
O8   0.57100   0.75000   0.06100   1.00000   0.09000
O9   0.07550   0.25000   0.02690   1.00000   0.05100
Wat1   0.76370   0.75000   0.44620   1.00000   0.04000
Wat2   0.94990   0.25000   0.55460   1.00000   0.08000
Wat3   0.37600   0.80500   0.15400   0.90000   0.06000
Wat4   0.46400   0.25000   0.50100   0.11000   0.08000
Wat5   0.50000   0.50000   0.50000   0.73000   0.09000
HI1   0.85300   0.25000   0.25800   1.00000   0.05000
HI2   0.98400   0.25000   0.23000   1.00000   0.05000
HI3   0.83200   0.30200   0.09900   1.00000   0.05000
HII1   0.32100   0.72300   0.46300   0.69000   0.05000
HII2   0.42500   0.64200   0.56700   0.69000   0.05000
HII3   0.49500   0.72700   0.54200   0.69000   0.05000
HII4   0.38600   0.66500   0.38100   0.69000   0.05000