Na.5(NH4)4Al4.4Si11.6O32*8H2O Gualtieri A F Acta Crystallographica B56 (2000) 584-593 Study of NH4+ in the zeolite phillipsite by combined synchrotron powder diffraction and IR spectroscopy Sample: 2 Locality: Perrier, Puy du Dome, France _database_code_amcsd 0009923 CELL PARAMETERS: 10.0122 14.1943 8.7284 90.000 125.024 90.000 SPACE GROUP: P2_1/m X-RAY WAVELENGTH: 1.541838 Cell Volume: 1015.816 Density (g/cm3): 2.010 MAX. ABS. INTENSITY / VOLUME**2: 4.186450993 RIR: 0.678 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 10.79 16.62 8.2027 -1 0 1 2 10.79 18.28 8.1991 1 0 0 2 12.38 68.46 7.1478 0 0 1 2 12.46 25.28 7.1021 -1 1 1 4 12.47 14.69 7.0998 1 1 0 4 12.47 58.45 7.0971 0 2 0 2 13.87 9.83 6.3840 0 1 1 4 16.52 22.94 5.3671 -1 2 1 4 16.52 23.11 5.3661 1 2 0 4 17.61 20.16 5.0363 0 2 1 4 17.72 37.64 5.0061 -2 0 1 2 20.64 1.27 4.3035 -1 0 2 2 20.65 3.12 4.3020 1 0 1 2 21.58 8.02 4.1184 -1 1 2 4 21.58 29.89 4.1170 1 1 1 4 21.67 1.16 4.1013 -2 0 2 2 21.68 3.34 4.0996 2 0 0 2 21.68 12.53 4.0985 -1 3 1 4 21.69 2.28 4.0980 1 3 0 4 21.72 9.12 4.0908 -2 2 1 4 22.54 15.42 3.9454 0 3 1 4 24.19 9.44 3.6798 -1 2 2 4 24.19 7.11 3.6789 1 2 1 4 25.70 5.39 3.4657 0 1 2 4 27.38 6.34 3.2569 -1 4 1 4 27.39 8.17 3.2566 1 4 0 4 27.44 37.19 3.2503 -3 0 2 2 27.45 10.58 3.2497 -3 0 1 2 27.95 41.70 3.1920 0 2 2 4 28.03 4.10 3.1836 -1 3 2 4 28.03 5.72 3.1830 1 3 1 4 28.07 100.00 3.1784 0 4 1 4 28.17 11.94 3.1683 -3 1 2 4 28.17 52.91 3.1677 -3 1 1 4 28.82 1.60 3.0983 2 3 0 4 30.24 8.06 2.9552 -3 2 2 4 30.25 20.99 2.9547 -3 2 1 4 31.37 1.59 2.8518 0 3 2 4 31.40 2.54 2.8489 2 1 1 4 32.57 8.52 2.7496 -1 0 3 2 32.57 17.02 2.7489 1 0 2 2 32.71 5.83 2.7378 -1 4 2 4 32.71 8.22 2.7374 1 4 1 4 32.77 1.84 2.7330 3 0 0 2 33.19 4.23 2.6994 -1 1 3 4 33.20 7.72 2.6987 1 1 2 4 33.28 9.35 2.6919 -2 2 3 4 33.30 2.00 2.6909 2 2 1 4 33.37 12.33 2.6849 -3 1 3 4 33.39 3.17 2.6837 3 1 0 4 33.39 1.10 2.6835 -2 4 2 4 33.40 5.40 2.6827 -1 5 1 4 33.40 7.34 2.6826 1 5 0 4 33.45 8.12 2.6791 -3 3 2 4 35.00 7.31 2.5639 -1 2 3 4 35.01 2.89 2.5633 1 2 2 4 35.17 3.03 2.5514 -3 2 3 4 35.65 2.39 2.5181 0 4 2 4 37.52 6.42 2.3968 -3 4 2 4 37.53 3.47 2.3966 -3 4 1 4 38.02 3.52 2.3666 3 3 0 4 38.58 4.47 2.3339 2 5 0 4 40.08 1.09 2.2499 -2 4 3 4 40.15 1.68 2.2459 0 6 1 4 40.58 1.41 2.2229 0 5 2 4 41.70 4.87 2.1659 -3 4 3 4 42.11 2.58 2.1458 3 1 1 4 42.27 2.51 2.1382 -3 5 2 4 42.78 1.72 2.1138 -4 3 3 4 43.58 1.59 2.0767 -3 2 4 4 43.99 2.09 2.0585 2 2 2 4 45.32 1.21 2.0008 1 0 3 2 45.75 1.09 1.9832 -5 0 3 2 45.80 1.36 1.9813 1 1 3 4 46.07 1.10 1.9701 -4 2 4 4 46.09 2.36 1.9693 4 2 0 4 46.11 3.23 1.9685 1 7 0 4 46.23 1.40 1.9639 -5 1 2 4 46.56 1.19 1.9508 0 7 1 4 47.54 1.78 1.9126 -3 6 1 4 47.61 1.85 1.9100 -5 2 3 4 47.61 1.62 1.9098 -5 2 2 4 49.80 1.46 1.8309 -5 1 4 4 49.97 3.86 1.8250 0 5 3 4 50.92 1.24 1.7933 -1 6 3 4 50.93 1.58 1.7931 1 6 2 4 51.06 1.07 1.7887 3 6 0 4 51.12 3.33 1.7869 0 0 4 2 51.47 4.68 1.7755 -4 4 4 4 51.49 4.11 1.7749 4 4 0 4 51.51 8.53 1.7743 0 8 0 2 51.55 1.84 1.7730 0 1 4 4 51.84 1.40 1.7637 0 7 2 4 52.50 1.63 1.7429 1 4 3 4 53.05 1.70 1.7262 -4 0 5 2 53.08 3.41 1.7254 4 0 1 2 53.09 1.93 1.7249 -3 5 4 4 53.25 2.85 1.7203 -3 7 1 4 53.28 1.56 1.7193 -4 6 2 4 54.52 1.62 1.6832 -2 0 5 2 54.67 2.64 1.6788 0 6 3 4 55.03 5.03 1.6687 -6 0 3 2 56.24 1.42 1.6357 -1 5 4 4 56.25 1.08 1.6355 1 5 3 4 56.66 2.35 1.6244 -6 2 3 4 57.61 1.40 1.5999 -3 6 4 4 57.93 1.16 1.5918 -2 6 4 4 58.04 1.00 1.5892 0 8 2 4 59.34 1.56 1.5574 -3 8 2 4 60.07 1.25 1.5401 0 9 1 4 62.28 1.29 1.4907 1 8 2 4 62.55 1.46 1.4850 -3 5 5 4 62.75 1.37 1.4808 1 9 1 4 62.83 1.26 1.4791 -6 2 5 4 62.90 1.70 1.4776 -6 4 4 4 65.00 1.59 1.4347 1 4 4 4 66.75 1.32 1.4014 0 2 5 4 67.30 2.82 1.3912 -6 4 5 4 67.33 1.29 1.3908 -6 4 1 4 68.71 1.92 1.3662 -3 9 3 4 68.72 1.22 1.3660 3 9 0 4 68.85 1.11 1.3636 -6 6 3 4 70.85 2.23 1.3299 -3 4 6 4 70.88 1.95 1.3295 3 4 3 4 71.10 1.26 1.3260 0 4 5 4 73.94 1.37 1.2819 -2 4 6 4 74.21 1.04 1.2779 -7 4 2 4 74.33 1.04 1.2761 -3 9 4 4 74.36 1.01 1.2757 -2 10 3 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.