data_global
_amcsd_formula_title 'H26 N6 O19 P6'
loop_
_publ_author_name
'Averbuch-Pouchot M'
_journal_name_full 'Acta Crystallographica, Section C'
_journal_volume 45 
_journal_year 1989
_journal_page_first 539
_journal_page_last 540
_publ_section_title
;
 Structure of ammonium cyclo-hexaphosphate monohydrate
 _cod_database_code 1008850
;
_database_code_amcsd 0016716
_chemical_formula_sum 'P6 O19 N6 H24'
_cell_length_a 15.445
_cell_length_b 15.445
_cell_length_c 7.553
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 1560.364
_exptl_crystal_density_diffrn      1.909
_symmetry_space_group_name_H-M 'R -3'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '2/3+x,1/3+y,1/3+z'
  '1/3+x,2/3+y,2/3+z'
  'y,-x+y,-z'
  '2/3+y,1/3-x+y,1/3-z'
  '1/3+y,2/3-x+y,2/3-z'
  '-x+y,-x,z'
  '2/3-x+y,1/3-x,1/3+z'
  '1/3-x+y,2/3-x,2/3+z'
  '-x,-y,-z'
  '2/3-x,1/3-y,1/3-z'
  '1/3-x,2/3-y,2/3-z'
  '-y,x-y,z'
  '2/3-y,1/3+x-y,1/3+z'
  '1/3-y,2/3+x-y,2/3+z'
  'x-y,x,-z'
  '2/3+x-y,1/3+x,1/3-z'
  '1/3+x-y,2/3+x,2/3-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
P1   0.19978   0.05297   0.93177
O1   0.20799   0.09611   0.75290
O2   0.28823   0.05384   0.01050
O3   0.16345   0.10577   0.07380
N1   0.13201   0.41185   0.07840
H1   0.29000   0.92900   0.07100
H2   0.39800   0.22500   0.97900
H3   0.14800   0.42400   0.18600
H4   0.67200   0.13300   0.97300
O4   0.00000   0.00000   0.50000