data_global
_amcsd_formula_title 'N(C2H5)4I.2GeI4'
loop_
_publ_author_name
'Muller V U'
'Krug V'
_journal_name_full 'Acta Crystallographica, Section C'
_journal_volume 46 
_journal_year 1990
_journal_page_first 523
_journal_page_last 525
_publ_section_title
;
 Tetraethylammoniumiodid-germaniumtetraiodid(1/2), eine strukture mit einem
 von acht iodatomen koordinierten iodidion
;
_database_code_amcsd 0010115
_chemical_formula_sum 'Ge2 I9 N C8'
_cell_length_a 17.953
_cell_length_b 9.990
_cell_length_c 17.509
_cell_angle_alpha 90
_cell_angle_beta 108.87
_cell_angle_gamma 90
_cell_volume 2971.474
_exptl_crystal_density_diffrn      3.124
_symmetry_space_group_name_H-M 'C 1 2/c 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,1/2+z'
  '1/2+x,1/2-y,1/2+z'
  '-x,y,1/2-z'
  '1/2-x,1/2+y,1/2-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Ge   0.13010   0.22770   0.12450   1.00000   0.04820
I1   0.00000   0.72240   0.25000   1.00000   0.04570
I2   0.07460   0.42050   0.18110   1.00000   0.07600
I3   0.06940   0.01370   0.15260   1.00000   0.07940
I4   0.09774   0.26020  -0.02551   1.00000   0.07170
I5   0.27719   0.21700   0.18910   1.00000   0.08310
N   0.25000   0.25000   0.50000   1.00000   0.05500
C1   0.29600   0.28500   0.44100   0.50000   0.08000
C2   0.17900   0.35100   0.46700   0.50000   0.08000
C3   0.37700   0.18800   0.47300   1.00000   0.15000
C4   0.21200   0.10400   0.46700   0.50000   0.09000
C5   0.28700   0.22700   0.58400   0.50000   0.10000
C6   0.17200   0.10700   0.38100   1.00000   0.14000