data_global
_amcsd_formula_title 'SnCo4(CO)16'
loop_
_publ_author_name
'Leigh J S'
'Whitmire K H'
_journal_name_full 'Acta Crystallographica, Section C'
_journal_volume 46 
_journal_year 1990
_journal_page_first 732
_journal_page_last 736
_publ_section_title
;
 The structures of [Sn{Co(CO4)4}4] and [Pb{Co(CO)4}4]
;
_database_code_amcsd 0010126
_chemical_formula_sum 'Sn Co4 O16 C16'
_cell_length_a 17.255
_cell_length_b 17.255
_cell_length_c 17.255
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 5137.417
_exptl_crystal_density_diffrn      2.075
_symmetry_space_group_name_H-M 'F -4 3 c'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2+y,1/2+z'
  '1/2+x,y,1/2+z'
  '1/2+x,1/2+y,z'
  '-z,x,-y'
  '-z,1/2+x,1/2-y'
  '1/2-z,x,1/2-y'
  '1/2-z,1/2+x,-y'
  '-y,z,-x'
  '-y,1/2+z,1/2-x'
  '1/2-y,z,1/2-x'
  '1/2-y,1/2+z,-x'
  '-x,y,-z'
  '-x,1/2+y,1/2-z'
  '1/2-x,y,1/2-z'
  '1/2-x,1/2+y,-z'
  'x,-z,1/2-y'
  'x,1/2-z,-y'
  '1/2+x,-z,-y'
  '1/2+x,1/2-z,1/2-y'
  'z,-y,1/2-x'
  'z,1/2-y,-x'
  '1/2+z,-y,-x'
  '1/2+z,1/2-y,1/2-x'
  'y,-x,1/2-z'
  'y,1/2-x,-z'
  '1/2+y,-x,-z'
  '1/2+y,1/2-x,1/2-z'
  'x,z,1/2+y'
  'x,1/2+z,+y'
  '1/2+x,z,+y'
  '1/2+x,1/2+z,1/2+y'
  'z,y,1/2+x'
  'z,1/2+y,+x'
  '1/2+z,y,+x'
  '1/2+z,1/2+y,1/2+x'
  'y,x,1/2+z'
  'y,1/2+x,+z'
  '1/2+y,x,+z'
  '1/2+y,1/2+x,1/2+z'
  '-z,-x,y'
  '-z,1/2-x,1/2+y'
  '1/2-z,-x,1/2+y'
  '1/2-z,1/2-x,y'
  '-y,-z,x'
  '-y,1/2-z,1/2+x'
  '1/2-y,-z,1/2+x'
  '1/2-y,1/2-z,x'
  '-x,-y,z'
  '-x,1/2-y,1/2+z'
  '1/2-x,-y,1/2+z'
  '1/2-x,1/2-y,z'
  'z,-x,-y'
  'z,1/2-x,1/2-y'
  '1/2+z,-x,1/2-y'
  '1/2+z,1/2-x,-y'
  'y,-z,-x'
  'y,1/2-z,1/2-x'
  '1/2+y,-z,1/2-x'
  '1/2+y,1/2-z,-x'
  'x,-y,-z'
  'x,1/2-y,1/2-z'
  '1/2+x,-y,1/2-z'
  '1/2+x,1/2-y,-z'
  '-x,z,1/2-y'
  '-x,1/2+z,-y'
  '1/2-x,z,-y'
  '1/2-x,1/2+z,1/2-y'
  '-z,y,1/2-x'
  '-z,1/2+y,-x'
  '1/2-z,y,-x'
  '1/2-z,1/2+y,1/2-x'
  '-y,x,1/2-z'
  '-y,1/2+x,-z'
  '1/2-y,x,-z'
  '1/2-y,1/2+x,1/2-z'
  '-x,-z,1/2+y'
  '-x,1/2-z,+y'
  '1/2-x,-z,+y'
  '1/2-x,1/2-z,1/2+y'
  '-z,-y,1/2+x'
  '-z,1/2-y,+x'
  '1/2-z,-y,+x'
  '1/2-z,1/2-y,1/2+x'
  '-y,-x,1/2+z'
  '-y,1/2-x,+z'
  '1/2-y,-x,+z'
  '1/2-y,1/2-x,1/2+z'
  'z,x,y'
  'z,1/2+x,1/2+y'
  '1/2+z,x,1/2+y'
  '1/2+z,1/2+x,y'
  'y,z,x'
  'y,1/2+z,1/2+x'
  '1/2+y,z,1/2+x'
  '1/2+y,1/2+z,x'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Sn   0.00000   0.00000   0.00000   0.02749
Co  -0.08932  -0.08930  -0.08930   0.03732
O1  -0.18630  -0.18630  -0.18630   0.11848
O2  -0.19280   0.04270  -0.10900   0.07599
C1  -0.14990  -0.14990  -0.14990   0.06424
C2  -0.15070  -0.00730  -0.09910   0.04813