data_global
_amcsd_formula_title 'PbCo4(CO)16'
loop_
_publ_author_name
'Leigh J S'
'Whitmire K H'
_journal_name_full 'Acta Crystallographica, Section C'
_journal_volume 46 
_journal_year 1990
_journal_page_first 732
_journal_page_last 736
_publ_section_title
;
 The structures of [Sn{Co(CO4)4}4] and [Pb{Co(CO)4}4]
;
_database_code_amcsd 0010127
_chemical_formula_sum 'Pb Co4 O16 C16'
_cell_length_a 12.184
_cell_length_b 12.267
_cell_length_c 17.220
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 2573.721
_exptl_crystal_density_diffrn      2.300
_symmetry_space_group_name_H-M 'P c c n'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2-y,1/2+z'
  '-x,1/2+y,1/2-z'
  '1/2-x,y,1/2+z'
  '1/2+x,-y,1/2-z'
  '1/2+x,1/2+y,-z'
  '1/2-x,1/2-y,z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Pb1   0.25000   0.75000   0.41570   0.03572
Co1   0.06600   0.76950   0.32310   0.04559
Co2   0.23140   0.56910   0.50790   0.04306
O11  -0.12500   0.78500   0.22700   0.08866
O12   0.05900   0.53000   0.31600   0.12665
O13   0.19300   0.90800   0.22600   0.10132
O14  -0.03700   0.87100   0.45500   0.12665
O21   0.20700   0.37500   0.60600   0.12665
O22   0.00500   0.63500   0.53100   0.07599
O23   0.30600   0.44200   0.37300   0.08866
O24   0.40300   0.66200   0.61200   0.08866
C11  -0.06000   0.77700   0.26000   0.07599
C12   0.06900   0.62400   0.31800   0.05193
C13   0.14500   0.85500   0.26200   0.04433
C14   0.00200   0.83100   0.40700   0.07599
C21   0.21600   0.45200   0.56900   0.05193
C22   0.09500   0.60200   0.51800   0.06079
C23   0.27700   0.49400   0.42800   0.04686
C24   0.33200   0.63300   0.57200   0.07599