data_global
_amcsd_formula_title 'TaBr4(PhPMe2)2'
loop_
_publ_author_name
'Hovnanian N'
'Hubert-Pfalzgraf L G'
'Borgne G L'
_journal_name_full 'Acta Crystallographica, Section C'
_journal_volume 46 
_journal_year 1990
_journal_page_first 1207
_journal_page_last 1209
_publ_section_title
;
 Structures of two polymorphs of cis-TaBr4(PhPMe2)2
 Sample: 1
;
_database_code_amcsd 0010157
_chemical_formula_sum 'Ta Br4 P2 C16'
_cell_length_a 8.493
_cell_length_b 30.369
_cell_length_c 8.898
_cell_angle_alpha 90
_cell_angle_beta 99.22
_cell_angle_gamma 90
_cell_volume 2265.356
_exptl_crystal_density_diffrn      2.213
_symmetry_space_group_name_H-M 'P 1 21/c 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2-y,1/2+z'
  '-x,1/2+y,1/2-z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Ta  -0.00012   0.12351   0.25369   0.03952
Br1   0.25800   0.16384   0.35030   0.07954
Br2   0.02740   0.07989   0.49910   0.08625
Br3   0.12930   0.07248   0.09530   0.06839
Br4  -0.19410   0.17569   0.33240   0.06903
P1  -0.24550   0.07060   0.16770   0.04104
P2  -0.02100   0.17930   0.02080   0.04559
C1  -0.40300   0.07870   0.27600   0.07092
C2  -0.19500   0.01330   0.20500   0.06333
C3  -0.34100   0.06940  -0.03100   0.04179
C4  -0.48800   0.09120  -0.07900   0.05193
C5  -0.56500   0.08680  -0.22400   0.06079
C6  -0.49700   0.06400  -0.32900   0.06713
C7  -0.35200   0.04360  -0.28800   0.07092
C8  -0.27500   0.04820  -0.13800   0.05699
C9   0.03800   0.23470   0.08700   0.08612
C10   0.11300   0.16630  -0.11100   0.08359
C11  -0.21200   0.18890  -0.09500   0.03926
C12  -0.25300   0.17040  -0.23900   0.05066
C13  -0.39900   0.17900  -0.32800   0.05826
C14  -0.50700   0.20510  -0.27500   0.05953
C15  -0.46800   0.22260  -0.13400   0.05699
C16  -0.32500   0.21560  -0.04600   0.04813