data_global
_amcsd_formula_title 'TaBr4(PhPMe2)2'
loop_
_publ_author_name
'Hovnanian N'
'Hubert-Pfalzgraf L G'
'Borgne G L'
_journal_name_full 'Acta Crystallographica, Section C'
_journal_volume 46 
_journal_year 1990
_journal_page_first 1207
_journal_page_last 1209
_publ_section_title
;
 Structures of two polymorphs of cis-TaBr4(PhPMe2)2
 Sample: 2
;
_database_code_amcsd 0010158
_chemical_formula_sum 'Ta Br4 P2 C16'
_cell_length_a 14.38
_cell_length_b 19.17
_cell_length_c 8.28
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 2282.503
_exptl_crystal_density_diffrn      2.196
_symmetry_space_group_name_H-M 'P 21 21 21'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-x,1/2+y,1/2-z'
  '1/2+x,1/2-y,-z'
  '1/2-x,-y,1/2+z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Ta1   0.04718   0.27998  -0.08420   0.03570
Br1  -0.02830   0.39960  -0.08080   0.06160
Br2  -0.03940   0.24890   0.17200   0.06020
Br3  -0.06390   0.22820  -0.28250   0.06470
Br4   0.19840   0.30830   0.03880   0.05140
P1   0.09930   0.14790  -0.05900   0.04770
P2   0.13030   0.32310  -0.35420   0.04440
C1   0.16600   0.13100   0.12700   0.05760
C2   0.00200   0.08800  -0.04000   0.06190
C3   0.17200   0.10930  -0.23100   0.05060
C4   0.11900   0.07850  -0.35100   0.05990
C5   0.17600   0.05470  -0.47500   0.07020
C6   0.27300   0.06270  -0.46700   0.07480
C7   0.32000   0.09480  -0.33900   0.07690
C8   0.26600   0.11990  -0.21300   0.06410
C9   0.05400   0.36800  -0.49000   0.06550
C10   0.17900   0.25500  -0.47700   0.04610
C11   0.22600   0.39160  -0.33700   0.05620
C12   0.19400   0.45400  -0.27000   0.06280
C13   0.26100   0.50580  -0.26100   0.07340
C14   0.35000   0.49000  -0.31900   0.07550
C15   0.37500   0.42500  -0.38500   0.07770
C16   0.31100   0.37100  -0.39700   0.07090