Na7Fe3(As2O7)4 Masquelier C, d'Yvoire F, Rodier N Acta Crystallographica C46 (1990) 1584-1587 Structure of the sodium ion conductor Na7Fe3(As2O7)4 _database_code_amcsd 0010172 CELL PARAMETERS: 9.9400 8.5483 28.7620 90.000 93.683 90.000 SPACE GROUP: C2/c X-RAY WAVELENGTH: 1.541838 Cell Volume: 2438.863 Density (g/cm3): 3.744 MAX. ABS. INTENSITY / VOLUME**2: 11.06814501 RIR: 0.963 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 6.16 27.19 14.3513 0 0 2 2 12.34 81.92 7.1756 0 0 4 2 13.67 31.61 6.4755 1 1 0 4 14.15 1.26 6.2607 1 1 1 4 14.77 80.88 5.9975 -1 1 2 4 15.25 7.11 5.8118 1 1 2 4 16.20 25.52 5.4702 -1 1 3 4 16.85 62.68 5.2613 1 1 3 4 17.88 5.09 4.9597 2 0 0 2 18.06 1.09 4.9109 -1 1 4 4 18.55 27.31 4.7838 0 0 6 2 18.55 23.71 4.7835 -2 0 2 2 19.31 35.76 4.5974 2 0 2 2 20.78 39.60 4.2741 0 2 0 2 21.01 17.18 4.2275 0 2 1 4 21.11 7.08 4.2084 -2 0 4 2 21.70 4.56 4.0963 0 2 2 4 22.44 2.48 3.9627 2 0 4 2 22.64 1.87 3.9272 -1 1 6 4 22.79 11.63 3.9024 0 2 3 4 24.24 17.98 3.6721 0 2 4 4 24.82 7.08 3.5878 0 0 8 2 25.02 10.83 3.5593 -2 0 6 2 25.22 1.37 3.5319 -1 1 7 4 26.21 8.68 3.4004 1 1 7 4 27.59 18.26 3.2325 -2 2 1 4 27.86 2.17 3.2024 2 2 1 4 27.99 6.77 3.1872 -2 2 2 4 28.51 100.00 3.1303 2 2 2 4 28.74 3.90 3.1067 -2 2 3 4 28.93 2.03 3.0859 -3 1 1 4 28.95 1.96 3.0840 1 1 8 4 28.95 9.22 3.0838 3 1 0 4 29.25 19.46 3.0528 -3 1 2 4 29.31 47.59 3.0469 3 1 1 4 29.78 25.14 2.9999 -2 0 8 2 29.79 12.98 2.9988 -2 2 4 4 29.90 1.36 2.9879 -3 1 3 4 30.00 2.16 2.9786 3 1 2 4 30.20 43.66 2.9589 0 2 7 4 30.73 23.08 2.9098 -1 1 9 4 30.77 5.30 2.9059 2 2 4 4 31.00 1.07 2.8851 3 1 3 4 31.14 95.99 2.8721 -2 2 5 4 31.16 81.42 2.8703 0 0 10 2 31.71 2.13 2.8221 2 0 8 2 32.11 23.69 2.7872 -3 1 5 4 32.31 49.61 2.7708 2 2 5 4 32.70 10.32 2.7387 1 3 0 4 32.74 8.22 2.7351 -2 2 6 4 32.79 8.61 2.7309 -1 3 1 4 33.81 68.22 2.6512 3 1 5 4 34.08 9.53 2.6306 2 2 6 4 34.57 3.42 2.5945 -2 2 7 4 34.71 11.76 2.5842 1 1 10 4 34.86 12.91 2.5739 -1 3 4 4 35.28 10.99 2.5437 1 3 4 4 35.36 12.78 2.5387 -3 1 7 4 35.57 1.06 2.5240 3 1 6 4 36.09 10.73 2.4890 -1 3 5 4 36.22 9.48 2.4799 4 0 0 2 36.37 1.48 2.4704 -4 0 2 2 36.58 6.53 2.4562 -1 1 11 4 36.60 14.65 2.4555 -2 2 8 4 36.60 2.70 2.4549 1 3 5 4 37.19 4.93 2.4178 2 0 10 2 37.60 3.33 2.3919 0 0 12 2 37.61 8.61 2.3918 -4 0 4 2 37.70 10.49 2.3858 1 1 11 4 37.75 13.04 2.3828 0 2 10 4 38.22 3.00 2.3551 2 2 8 4 38.79 1.08 2.3213 -2 2 9 4 39.62 7.12 2.2749 -1 1 12 4 39.66 1.95 2.2723 3 1 8 4 39.86 5.67 2.2618 -4 0 6 2 39.91 3.72 2.2590 1 3 7 4 40.53 6.13 2.2259 2 2 9 4 40.82 9.25 2.2107 -2 0 12 2 41.96 1.83 2.1534 3 1 9 4 42.11 1.52 2.1460 4 0 6 2 42.11 1.60 2.1457 3 3 1 4 42.25 1.21 2.1389 -4 2 2 4 42.29 1.06 2.1371 0 4 0 2 42.43 2.74 2.1302 4 2 1 4 42.98 1.07 2.1044 4 2 2 4 42.98 1.13 2.1042 -4 0 8 2 43.39 13.69 2.0857 0 4 3 4 43.63 3.62 2.0746 -2 2 11 4 43.88 1.15 2.0635 1 1 13 4 44.22 1.15 2.0482 0 4 4 4 44.33 3.71 2.0435 3 3 4 4 45.36 1.93 1.9992 -1 3 10 4 45.51 1.32 1.9931 3 3 5 4 46.22 8.90 1.9641 1 3 10 4 46.23 3.20 1.9636 -2 2 12 4 46.26 3.01 1.9626 2 4 0 4 46.29 1.27 1.9615 -2 4 1 4 46.54 3.40 1.9512 0 4 6 4 46.85 9.85 1.9391 -4 0 10 2 46.94 3.76 1.9356 3 1 11 4 47.02 2.37 1.9325 5 1 0 4 47.41 3.14 1.9177 -5 1 3 4 47.71 1.79 1.9061 -1 3 11 4 47.98 3.08 1.8961 -5 1 4 4 48.01 23.86 1.8951 0 4 7 4 48.24 9.57 1.8864 2 2 12 4 48.29 3.89 1.8848 -3 3 8 4 48.39 1.12 1.8810 2 4 4 4 48.65 11.00 1.8717 -2 4 5 4 48.65 17.21 1.8717 5 1 3 4 48.95 2.57 1.8608 -2 2 13 4 49.30 4.65 1.8485 0 2 14 4 49.46 6.23 1.8428 2 4 5 4 49.77 2.87 1.8322 -2 4 6 4 50.13 2.75 1.8196 4 0 10 2 50.19 1.59 1.8176 -1 3 12 4 50.23 3.10 1.8162 3 3 8 4 50.73 5.78 1.7998 2 4 6 4 50.90 3.23 1.7939 0 0 16 2 50.96 10.82 1.7919 -5 1 7 4 51.34 1.95 1.7797 -4 0 12 2 51.77 2.26 1.7659 -2 2 14 4 51.77 4.57 1.7659 -4 2 10 4 51.92 1.14 1.7610 -3 3 10 4 52.07 4.54 1.7565 -3 1 14 4 53.45 1.00 1.7141 0 4 10 4 53.68 10.56 1.7074 5 1 7 4 53.79 1.18 1.7042 1 3 13 4 53.80 5.55 1.7041 -4 2 11 4 54.46 1.79 1.6848 1 5 0 4 54.52 7.10 1.6830 -1 5 1 4 54.60 1.38 1.6809 1 5 1 4 54.68 15.37 1.6784 -2 2 15 4 54.79 1.80 1.6754 -1 5 2 4 55.51 2.11 1.6554 -1 3 14 4 55.60 3.55 1.6528 2 4 9 4 55.65 3.42 1.6516 -5 1 10 4 56.30 2.99 1.6342 -6 0 4 2 56.36 3.75 1.6324 -4 0 14 2 56.44 2.20 1.6304 -5 3 1 4 56.45 1.20 1.6300 3 3 11 4 56.52 26.60 1.6281 5 3 0 4 56.55 7.63 1.6275 1 3 14 4 56.78 2.68 1.6214 -1 5 5 4 56.83 1.47 1.6201 -4 4 1 4 56.88 5.80 1.6189 4 4 0 4 56.91 3.91 1.6179 2 2 15 4 57.08 1.63 1.6136 4 2 11 4 57.12 1.79 1.6125 4 4 1 4 57.15 1.10 1.6119 1 5 5 4 57.27 1.37 1.6088 5 1 9 4 57.28 2.10 1.6083 5 3 2 4 57.32 3.80 1.6073 -4 4 3 4 57.56 2.01 1.6012 2 4 10 4 57.83 2.06 1.5945 -6 0 6 2 57.90 1.69 1.5927 -3 1 16 4 57.96 2.11 1.5913 5 3 3 4 58.25 9.62 1.5840 3 1 15 4 58.34 2.68 1.5818 -1 3 15 4 58.80 3.69 1.5703 0 2 17 4 58.81 4.97 1.5701 3 3 12 4 58.82 1.33 1.5700 5 3 4 4 58.95 1.39 1.5667 -5 3 6 4 59.29 2.35 1.5585 5 1 10 4 59.46 6.67 1.5546 4 2 12 4 59.95 3.66 1.5429 -6 2 2 4 60.02 1.96 1.5413 -5 3 7 4 60.23 1.34 1.5365 -2 4 12 4 60.27 3.32 1.5356 0 4 13 4 60.40 1.00 1.5325 4 0 14 2 60.40 3.01 1.5325 6 0 6 2 60.80 2.77 1.5235 -2 2 17 4 60.96 7.05 1.5198 -3 1 17 4 61.01 1.74 1.5187 -3 3 14 4 61.08 1.16 1.5171 5 3 6 4 61.18 8.66 1.5149 -3 5 2 4 61.27 8.26 1.5130 -1 3 16 4 61.32 2.32 1.5118 3 1 16 4 61.55 2.60 1.5068 -3 5 3 4 61.86 1.11 1.5000 -4 0 16 2 61.97 1.30 1.4975 4 2 13 4 62.02 1.28 1.4965 -1 5 9 4 62.38 1.72 1.4886 1 3 16 4 62.48 1.97 1.4866 5 3 7 4 62.51 1.98 1.4857 -2 4 13 4 62.55 7.27 1.4850 -1 1 19 4 62.56 3.21 1.4847 4 4 7 4 62.64 3.07 1.4830 1 5 9 4 62.83 2.20 1.4790 -3 5 5 4 62.93 1.60 1.4770 3 5 4 4 63.17 1.27 1.4720 2 2 17 4 63.75 1.45 1.4600 -1 5 10 4 63.75 1.69 1.4599 -3 5 6 4 63.86 3.73 1.4576 3 5 5 4 63.92 1.35 1.4563 3 3 14 4 63.99 1.38 1.4549 -2 2 18 4 64.09 1.75 1.4530 4 4 8 4 64.12 1.81 1.4524 -5 1 14 4 64.27 3.31 1.4493 -5 3 10 4 64.94 2.24 1.4361 -4 4 10 4 64.98 2.39 1.4351 0 0 20 2 65.52 4.47 1.4247 0 6 0 2 65.61 1.94 1.4230 0 6 1 4 65.66 2.60 1.4220 -6 2 9 4 66.01 2.51 1.4152 -5 3 11 4 66.23 2.04 1.4111 5 1 13 4 66.33 2.24 1.4092 0 6 3 4 66.70 2.76 1.4022 -4 4 11 4 67.43 2.57 1.3889 1 1 20 4 67.44 1.80 1.3888 -1 3 18 4 67.49 6.66 1.3878 -2 4 15 4 67.62 1.29 1.3854 4 4 10 4 67.64 19.91 1.3852 5 3 10 4 67.67 3.45 1.3845 -1 5 12 4 67.70 6.17 1.3840 3 5 8 4 67.76 1.26 1.3830 7 1 2 4 67.91 1.25 1.3802 -5 3 12 4 68.01 11.76 1.3785 -7 1 5 4 68.55 2.47 1.3689 -2 6 1 4 68.75 1.28 1.3654 -2 6 2 4 68.75 2.56 1.3654 -7 1 6 4 69.01 1.42 1.3609 2 6 2 4 69.25 1.57 1.3567 6 2 9 4 69.29 1.50 1.3562 7 1 4 4 69.66 1.95 1.3497 5 3 11 4 69.90 2.17 1.3458 0 6 7 4 70.17 4.33 1.3412 -2 4 16 4 70.31 6.39 1.3389 7 1 5 4 70.40 1.26 1.3373 -2 6 5 4 70.68 1.52 1.3328 -6 2 12 4 70.68 1.04 1.3328 -1 3 19 4 71.09 2.65 1.3261 1 1 21 4 71.17 3.99 1.3248 0 4 17 4 71.21 1.15 1.3241 0 6 8 4 71.77 3.94 1.3152 -4 2 18 4 72.08 1.25 1.3103 2 6 6 4 72.25 2.59 1.3077 2 4 16 4 72.44 1.12 1.3047 0 0 22 2 72.77 1.49 1.2995 -3 5 12 4 73.06 1.23 1.2951 5 5 0 4 73.60 1.49 1.2870 -2 6 8 4 73.80 1.56 1.2840 -5 5 4 4 73.92 1.76 1.2822 -2 0 22 2 74.19 1.20 1.2783 -3 1 21 4 74.20 1.03 1.2780 0 4 18 4 74.33 2.57 1.2762 0 6 10 4 74.69 1.07 1.2708 -7 3 1 4 74.73 1.07 1.2703 -7 3 2 4 74.83 2.95 1.2688 -3 5 13 4 75.02 1.02 1.2661 -7 1 11 4 75.08 1.57 1.2653 3 5 12 4 75.15 2.32 1.2642 2 4 17 4 75.30 2.20 1.2620 1 3 20 4 75.61 1.29 1.2576 3 3 18 4 75.62 3.27 1.2576 7 3 2 4 75.69 4.18 1.2566 -6 0 16 2 76.05 1.35 1.2515 7 1 9 4 76.12 3.44 1.2505 0 6 11 4 76.27 1.70 1.2484 6 0 14 2 76.57 1.13 1.2443 -7 3 6 4 77.03 1.00 1.2379 -3 5 14 4 77.22 1.53 1.2354 4 6 0 4 77.25 1.40 1.2351 -1 1 23 4 77.34 3.69 1.2338 5 1 17 4 77.47 2.21 1.2321 -6 4 9 4 78.03 1.14 1.2246 -4 2 20 4 78.08 1.11 1.2240 -4 6 4 4 78.27 1.08 1.2215 -2 6 11 4 78.65 1.29 1.2165 -7 1 13 4 79.00 1.07 1.2120 1 7 0 4 79.40 2.05 1.2069 1 7 2 4 79.63 1.95 1.2040 4 2 19 4 79.85 3.00 1.2013 1 7 3 4 80.52 1.31 1.1928 -8 2 2 4 81.35 1.35 1.1828 -4 2 21 4 81.59 1.46 1.1799 -5 5 11 4 82.01 1.93 1.1750 7 1 12 4 82.91 2.74 1.1645 -7 1 15 4 84.01 1.48 1.1520 8 2 5 4 84.02 1.41 1.1519 1 5 18 4 84.04 1.10 1.1517 0 2 24 4 84.10 1.10 1.1510 -1 7 8 4 84.32 1.46 1.1486 -7 3 12 4 86.29 1.16 1.1273 3 7 4 4 87.02 2.63 1.1197 -3 7 6 4 87.99 2.23 1.1099 8 2 8 4 88.29 1.64 1.1069 2 2 24 4 88.90 1.38 1.1009 6 4 13 4 89.36 1.87 1.0964 3 3 22 4 89.38 1.17 1.0962 7 1 15 4 89.49 1.02 1.0951 7 3 12 4 89.51 1.26 1.0950 -9 1 1 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.