data_global _amcsd_formula_title 'P(C6H5)4ReCl4(N2S2)' loop_ _publ_author_name 'Muller V U' 'Vogler S' 'Dehnicke K' 'Fenske D' _journal_name_full 'Acta Crystallographica, Section C' _journal_volume 46 _journal_year 1990 _journal_page_first 1989 _journal_page_last 1992 _publ_section_title ; Tetraphenylphosphonium- und natrium-15-krone-5-tetrachloro- cyclodithiadiazenorhenat ; _database_code_amcsd 0010187 _chemical_formula_sum 'Re Cl4 S2 N2 P C24' _cell_length_a 7.674 _cell_length_b 12.697 _cell_length_c 14.606 _cell_angle_alpha 77.64 _cell_angle_beta 80.68 _cell_angle_gamma 89.78 _cell_volume 1371.122 _exptl_crystal_density_diffrn 1.791 _symmetry_space_group_name_H-M 'P -1' loop_ _space_group_symop_operation_xyz 'x,y,z' '-x,-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv Re1 0.19889 0.32740 0.25206 0.04070 Cl1 0.23860 0.16630 0.19250 0.06600 Cl2 0.19860 0.48200 0.31850 0.06500 Cl3 0.47710 0.39040 0.16140 0.06340 Cl4 0.31280 0.23740 0.38540 0.07700 S1 -0.22060 0.29980 0.29050 0.06250 S2 -0.09510 0.41310 0.12610 0.07600 N1 -0.02600 0.29080 0.30570 0.04700 N2 0.09130 0.39210 0.15500 0.04300 P1 0.03400 0.81770 0.26550 0.03860 C10 0.20220 0.79430 0.17270 0.04200 C11 0.34600 0.86500 0.14180 0.05400 C12 0.48500 0.84580 0.07560 0.06600 C13 0.48400 0.75350 0.03910 0.06700 C14 0.33900 0.68210 0.06920 0.06500 C15 0.20100 0.70240 0.13510 0.05000 C20 0.14980 0.83990 0.35570 0.04100 C21 0.27100 0.76530 0.38810 0.05100 C22 0.36900 0.78220 0.45460 0.05700 C23 0.34700 0.87710 0.49110 0.06000 C24 0.23100 0.95020 0.45900 0.05700 C25 0.13000 0.93470 0.39290 0.04800 C30 -0.09370 0.93180 0.22310 0.04200 C31 -0.24800 0.94750 0.28240 0.05300 C32 -0.35500 0.03300 0.25400 0.06300 C33 -0.30700 0.09990 0.16520 0.05800 C34 -0.15300 0.08240 0.10560 0.06200 C35 -0.04700 0.99830 0.13540 0.05000 C40 -0.11940 0.70560 0.30840 0.04000 C41 -0.23100 0.68370 0.24700 0.05200 C42 -0.35400 0.59960 0.27780 0.05700 C43 -0.36500 0.53680 0.36720 0.05700 C44 -0.25700 0.55850 0.42810 0.06000 C45 -0.13400 0.64280 0.39930 0.05000