data_global _amcsd_formula_title 'Na(C10H20O5)ReCl4(N2S2)' loop_ _publ_author_name 'Muller V U' 'Vogler S' 'Dehnicke K' 'Fenske D' _journal_name_full 'Acta Crystallographica, Section C' _journal_volume 46 _journal_year 1990 _journal_page_first 1989 _journal_page_last 1992 _publ_section_title ; Tetraphenylphosphonium- und natrium-15-krone-5-tetrachloro- cyclodithiadiazenorhenat ; _database_code_amcsd 0010188 _chemical_formula_sum 'Re Cl4 S2 N2 Na O5 C10' _cell_length_a 10.167 _cell_length_b 15.241 _cell_length_c 14.536 _cell_angle_alpha 90 _cell_angle_beta 103.67 _cell_angle_gamma 90 _cell_volume 2188.625 _exptl_crystal_density_diffrn 1.952 _symmetry_space_group_name_H-M 'P 1 21/c 1' loop_ _space_group_symop_operation_xyz 'x,y,z' 'x,1/2-y,1/2+z' '-x,1/2+y,1/2-z' '-x,-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv Rel 0.09192 0.18895 0.08500 0.03630 Cl1 0.32480 0.19700 0.16970 0.06500 Cl2 -0.14530 0.18630 0.02240 0.07700 Cl3 0.06430 0.32940 0.15250 0.05500 Cl4 0.05070 0.10990 0.21490 0.06900 S1 0.12660 0.05370 -0.07600 0.08000 S2 0.12480 0.22480 -0.12550 0.07100 N1 0.11580 0.09160 0.01920 0.04600 N2 0.11930 0.23600 -0.02260 0.04200 Na 0.36540 0.38100 0.15770 0.05200 O1 0.34300 0.47810 0.28540 0.08300 O2 0.27500 0.52100 0.09640 0.07800 O3 0.33200 0.38760 -0.01220 0.07500 O4 0.57000 0.35050 0.10320 0.07500 O5 0.56700 0.37820 0.28800 0.08700 C1 0.31400 0.56500 0.25200 0.11000 C2 0.20600 0.56300 0.16100 0.10700 C3 0.19100 0.50300 0.01000 0.13000 C4 0.27100 0.46600 -0.05500 0.12000 C5 0.43600 0.36100 -0.05420 0.12000 C6 0.52700 0.30400 0.01200 0.12000 C7 0.66500 0.31000 0.17700 0.10000 C8 0.68800 0.36800 0.25900 0.10800 C9 0.57200 0.44400 0.35000 0.18000 C10 0.45800 0.47300 0.36500 0.15000