data_global _amcsd_formula_title 'Pd(C3H3NS2)4Cl2C3H3NS2' loop_ _publ_author_name 'Raper E S' 'Britton A M' 'Clegg W' _journal_name_full 'Acta Crystallographica, Section C' _journal_volume 46 _journal_year 1990 _journal_page_first 2344 _journal_page_last 2346 _publ_section_title ; Structure of tetrakis(2,3-dihydro-1,3-thiazole-2-thione)palladium(II) dichloride 2,3-dihydro-1,3-thiazole-2-thione solvate ; _database_code_amcsd 0010238 _chemical_formula_sum 'Pd Cl2 S10 C15 N5' _cell_length_a 11.546 _cell_length_b 17.749 _cell_length_c 13.724 _cell_angle_alpha 90 _cell_angle_beta 100.91 _cell_angle_gamma 90 _cell_volume 2761.625 _exptl_crystal_density_diffrn 1.800 _symmetry_space_group_name_H-M 'P 1 21/c 1' loop_ _space_group_symop_operation_xyz 'x,y,z' 'x,1/2-y,1/2+z' '-x,1/2+y,1/2-z' '-x,-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv Pd 0.49804 0.10163 0.24193 0.03686 Cl1 0.84174 0.36497 0.13197 0.05260 Cl2 0.14146 0.36475 0.37645 0.05870 S21 0.61811 0.19900 0.20456 0.05370 S11 0.52596 0.14003 -0.00396 0.04790 S22 0.62103 0.01174 0.18948 0.05270 S12 0.71305 0.03517 0.41008 0.05030 S23 0.36522 0.19204 0.27781 0.04940 S13 0.45166 0.13057 0.48623 0.05130 S24 0.38721 0.00478 0.29456 0.05010 S14 0.29956 0.02166 0.07240 0.04960 S25 0.95302 0.17540 0.40387 0.07570 S15 0.04292 0.08678 0.24779 0.08580 C21 0.61810 0.19340 0.08120 0.03820 N31 0.68970 0.23320 0.03610 0.04400 C41 0.67370 0.22420 -0.06460 0.05160 C51 0.58910 0.17510 -0.09880 0.05200 C22 0.71780 -0.00470 0.29790 0.04010 N32 0.80860 -0.05190 0.30640 0.04710 C42 0.87420 -0.05820 0.40020 0.05360 C52 0.83460 -0.01570 0.46660 0.05810 C23 0.36110 0.18470 0.40040 0.04020 N33 0.28840 0.22420 0.44480 0.04780 C43 0.30290 0.21360 0.54600 0.05670 C53 0.38730 0.16500 0.58080 0.05650 C24 0.29370 -0.01570 0.18610 0.04010 N34 0.20520 -0.06450 0.17860 0.04710 C44 0.14160 -0.07420 0.08400 0.05430 C54 0.18120 -0.03260 0.01680 0.05540 C25 0.99060 0.16720 0.29370 0.04980 N35 0.98630 0.22040 0.22430 0.06560 C45 0.02030 0.19960 0.13700 0.06950 C55 0.05470 0.13010 0.13730 0.07890