data_global
_amcsd_formula_title 'Cu3Bi4V2O14'
loop_
_publ_author_name
'Deacon G B'
'Gatehouse B M'
'Ward G N'
_journal_name_full 'Acta Crystallographica, Section C'
_journal_volume 50 
_journal_year 1994
_journal_page_first 1178
_journal_page_last 1180
_publ_section_title
;
 Cu3Bi4V2O14, a new compound
;
_database_code_amcsd 0010293
_chemical_formula_sum 'Cu3 Bi4 V2 O14'
_cell_length_a 5.317
_cell_length_b 7.916
_cell_length_c 8.095
_cell_angle_alpha 74.58
_cell_angle_beta 89.38
_cell_angle_gamma 70.39
_cell_volume 308.243
_exptl_crystal_density_diffrn      7.286
_symmetry_space_group_name_H-M 'P -1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Cul  -0.36250  -0.22360  -0.02570   0.00860
Cu2   0.00000   0.00000   0.00000   0.00780
Bil   0.10793  -0.20460   0.69944   0.00960
Bi2   0.42486   0.15405   0.63975   0.01060
V   0.25060  -0.42850   0.24560   0.00870
O1   0.29040  -0.06960  -0.14880   0.00800
O2   0.22610   0.04370   0.16690   0.01000
O3  -0.00100  -0.33730   0.08680   0.04000
O4  -0.47420  -0.39060   0.15480   0.02200
O5   0.18110  -0.32130   0.40450   0.02400
O6   0.33020   0.32920   0.32500   0.01300
O7   0.24740  -0.00250   0.50430   0.00600
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Cul 0.00580 0.00790 0.01010 -0.00240 0.00050 0.00090
Cu2 0.00340 0.00910 0.01080 -0.00200 0.00040 -0.00290
Bil 0.01040 0.00600 0.01120 -0.00260 0.00007 -0.00060
Bi2 0.01040 0.00830 0.01210 -0.00140 0.00030 -0.00360
V 0.00730 0.00420 0.01410 -0.00340 0.00030 0.00020