data_global
_chemical_name_mineral 'Lotharmeyerite'
loop_
_publ_author_name
'Yang Y W'
'Evans S H'
'Downs R T'
'Yang H'
_journal_name_full 'Acta Crystallographica, Section E'
_journal_volume 68 
_journal_year 2012
_journal_page_first i9
_journal_page_last i10
_publ_section_title
;
 Lotharmeyerite, Ca(Zn,Mn)2(AsO4)2(H2O,OH)2
 Note: RRUFF.info/R060862
;
_database_code_amcsd 0018604
_chemical_compound_source 'Mapimi, Durango, Mexico'
_chemical_formula_sum 'Ca (Zn1.024 Mn.976) As2 O10 H3'
_cell_length_a 9.0727
_cell_length_b 6.2530
_cell_length_c 7.4150
_cell_angle_alpha 90
_cell_angle_beta 116.739
_cell_angle_gamma 90
_cell_volume 375.681
_exptl_crystal_density_diffrn      4.186
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Ca1   0.00000   0.00000   0.00000   1.00000   0.01360
Zn1   0.25000   0.25000   0.50000   0.51200   0.00936
Mn1   0.25000   0.25000   0.50000   0.48800   0.00936
As1   0.41579   0.00000   0.20474   1.00000   0.00864
O1   0.33900   0.50000   0.41320   1.00000   0.01400
O2   0.31820   0.00000   0.35360   1.00000   0.01530
O3   0.03469   0.27980   0.24370   1.00000   0.01270
O4   0.25690   0.00000  -0.02650   1.00000   0.01990
H1   0.44000   0.50000   0.46400   0.50000   0.04000
H2   0.29800   0.50000   0.31300   1.00000   0.04000
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Ca1 0.01850 0.01200 0.01080 0.00000 0.00700 0.00000
Zn1 0.00931 0.00899 0.00800 0.00002 0.00232 -0.00002
Mn1 0.00931 0.00899 0.00800 0.00002 0.00232 -0.00002
As1 0.00787 0.00860 0.00895 0.00000 0.00336 0.00000
O1 0.00980 0.02010 0.00920 0.00000 0.00170 0.00000
O2 0.01920 0.01160 0.02200 0.00000 0.01550 0.00000
O3 0.01220 0.01100 0.01460 0.00230 0.00570 -0.00050
O4 0.01500 0.02940 0.01110 0.00000 0.00200 0.00000