data_global
_amcsd_formula_title 'Na2S*5H2O'
loop_
_publ_author_name
'Bedlivy D'
'Preisinger A'
_journal_name_full 'Zeitschrift fur Kristallographie'
_journal_volume 121 
_journal_year 1965
_journal_page_first 131
_journal_page_last 144
_publ_section_title
;
 Die kristallstruktur von Na2S*5H2O, Na2Se*5H2O und Na2Te*5H2O
;
_database_code_amcsd 0010615
_chemical_formula_sum 'Na2 S (O5 H10)'
_cell_length_a 6.475
_cell_length_b 12.545
_cell_length_c 8.655
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 703.036
_exptl_crystal_density_diffrn      1.588
_symmetry_space_group_name_H-M 'C m c m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,1/2+z'
  '1/2+x,1/2-y,1/2+z'
  '-x,y,1/2-z'
  '1/2-x,1/2+y,1/2-z'
  '-x,y,z'
  '1/2-x,1/2+y,z'
  'x,-y,-z'
  '1/2+x,1/2-y,-z'
  'x,y,1/2-z'
  '1/2+x,1/2+y,1/2-z'
  '-x,-y,1/2+z'
  '1/2-x,1/2-y,1/2+z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Na1   0.00000   0.00000   0.00000   0.01900
Na2   0.50000   0.04200   0.75000   0.01900
S   0.00000   0.31300   0.75000   0.01520
Wat1   0.00000   0.09300   0.25000   0.02153
Wat2   0.26200   0.12400   0.57000   0.02026