Lorandite Fleet M E Zeitschrift fur Kristallographie 138 (1973) 147-160 The crystal structure and bonding of lorandite, Tl2As2S4 _database_code_amcsd 0010746 CELL PARAMETERS: 12.2800 11.3000 6.1000 90.000 104.500 90.000 SPACE GROUP: P2_1/a X-RAY WAVELENGTH: 1.541838 Cell Volume: 819.499 Density (g/cm3): 5.566 MAX. ABS. INTENSITY / VOLUME**2: 47.22687983 RIR: 2.763 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 10.80 8.24 8.1906 1 1 0 4 14.90 12.72 5.9444 2 0 0 2 16.85 22.80 5.2609 2 1 0 4 16.93 19.63 5.2381 -1 1 1 4 18.33 3.32 4.8389 -2 0 1 2 19.96 3.66 4.4482 -2 1 1 4 19.99 4.82 4.4407 1 1 1 4 21.70 3.94 4.0953 2 2 0 4 21.76 27.82 4.0845 -1 2 1 4 21.77 11.86 4.0826 0 2 1 4 23.75 11.69 3.7467 2 0 1 2 23.79 7.31 3.7396 3 1 0 4 24.22 63.08 3.6752 -2 2 1 4 24.25 88.44 3.6710 1 2 1 4 24.80 61.60 3.5908 1 3 0 4 24.99 100.00 3.5628 -3 1 1 4 25.04 61.93 3.5563 2 1 1 4 27.49 3.87 3.2444 3 2 0 4 28.04 1.17 3.1817 2 3 0 4 28.10 41.22 3.1757 0 3 1 4 28.55 5.40 3.1269 -3 2 1 4 28.59 7.26 3.1225 2 2 1 4 30.06 7.95 2.9723 -2 3 1 4 30.07 19.23 2.9722 4 0 0 2 30.09 1.73 2.9703 -4 0 1 2 30.09 16.46 2.9701 1 3 1 4 30.24 9.56 2.9558 -2 0 2 2 30.27 39.03 2.9529 0 0 2 2 30.35 23.72 2.9446 -1 1 2 4 31.11 58.41 2.8744 4 1 0 4 31.19 22.88 2.8680 3 1 1 4 31.28 59.56 2.8596 -2 1 2 4 31.31 7.74 2.8569 0 1 2 4 32.58 76.14 2.7485 1 4 0 4 32.80 7.51 2.7302 3 3 0 4 33.39 8.22 2.6839 -1 2 2 4 33.71 5.74 2.6590 -3 3 1 4 33.74 4.53 2.6564 2 3 1 4 33.95 5.05 2.6407 -3 1 2 4 34.00 7.05 2.6365 1 1 2 4 34.08 18.14 2.6304 4 2 0 4 34.10 21.31 2.6291 -4 2 1 4 34.15 5.56 2.6255 3 2 1 4 34.24 1.25 2.6191 -2 2 2 4 34.26 1.56 2.6170 0 2 2 4 35.21 1.04 2.5489 -1 4 1 4 36.77 1.06 2.4445 1 2 2 4 37.11 5.09 2.4225 4 0 1 2 37.16 9.26 2.4195 -4 0 2 2 37.24 15.69 2.4146 2 0 2 2 37.93 2.26 2.3721 -5 1 1 4 37.96 5.89 2.3703 -1 3 2 4 37.99 9.82 2.3687 4 1 1 4 38.03 12.66 2.3658 -4 1 2 4 38.60 8.36 2.3324 -4 3 1 4 38.70 1.78 2.3268 5 1 0 4 38.72 6.69 2.3253 -2 3 2 4 38.75 1.95 2.3239 0 3 2 4 39.16 41.68 2.3004 3 4 0 4 39.94 1.12 2.2573 -3 4 1 4 40.46 3.21 2.2293 -5 2 1 4 40.52 13.74 2.2265 4 2 1 4 40.64 5.74 2.2202 1 5 0 4 40.97 4.63 2.2030 -3 3 2 4 41.02 8.00 2.2005 1 3 2 4 41.19 10.15 2.1916 5 2 0 4 42.81 3.36 2.1125 2 5 0 4 42.84 3.93 2.1110 -1 5 1 4 42.84 6.28 2.1107 0 5 1 4 43.21 3.25 2.0939 -5 1 2 4 43.30 10.09 2.0898 3 1 2 4 43.67 43.29 2.0726 -1 4 2 4 44.23 6.05 2.0477 -2 5 1 4 44.25 4.84 2.0469 1 5 1 4 44.29 3.79 2.0453 3 4 1 4 44.41 7.68 2.0397 -5 3 1 4 44.44 9.85 2.0388 -6 0 1 2 44.46 1.30 2.0375 4 3 1 4 44.57 11.08 2.0328 2 3 2 4 45.09 7.23 2.0107 5 3 0 4 45.19 1.46 2.0064 -6 1 1 4 45.49 10.08 1.9938 -1 1 3 4 45.58 3.29 1.9902 3 2 2 4 46.11 5.65 1.9686 0 0 3 2 46.24 7.28 1.9632 3 5 0 4 46.38 8.78 1.9579 -3 4 2 4 46.53 1.34 1.9517 6 1 0 4 46.80 5.19 1.9412 -3 1 3 4 46.85 7.66 1.9394 0 1 3 4 46.93 1.34 1.9362 -3 5 1 4 46.95 5.74 1.9352 2 5 1 4 47.68 8.46 1.9073 -2 2 3 4 48.50 5.64 1.8771 -6 0 2 2 48.67 4.08 1.8710 -4 0 3 2 48.95 2.75 1.8606 -3 2 3 4 49.00 3.33 1.8590 0 2 3 4 49.12 17.29 1.8546 -5 3 2 4 49.20 4.68 1.8518 -6 1 2 4 49.21 6.59 1.8517 3 3 2 4 49.31 1.37 1.8481 4 1 2 4 49.37 2.27 1.8459 -4 1 3 4 49.45 1.14 1.8432 1 1 3 4 49.52 1.71 1.8406 -5 4 1 4 49.61 1.01 1.8376 -4 4 2 4 50.25 2.77 1.8158 -1 5 2 4 50.76 6.68 1.7986 -4 5 1 4 50.80 2.13 1.7974 3 5 1 4 50.86 4.78 1.7953 -2 5 2 4 50.89 5.83 1.7945 -1 6 1 4 50.89 3.64 1.7943 0 6 1 4 50.93 8.76 1.7930 -6 3 1 4 50.99 4.31 1.7912 5 3 1 4 51.19 1.84 1.7845 -2 3 3 4 51.29 1.07 1.7814 -6 2 2 4 51.39 5.18 1.7782 4 2 2 4 51.45 1.62 1.7762 -4 2 3 4 51.52 1.31 1.7738 1 2 3 4 52.11 7.41 1.7551 -2 6 1 4 52.13 5.05 1.7546 1 6 1 4 52.24 12.33 1.7510 6 0 1 2 52.45 3.40 1.7447 0 3 3 4 52.50 2.04 1.7430 2 0 3 2 52.69 2.75 1.7372 -3 5 2 4 52.73 3.45 1.7360 1 5 2 4 52.85 7.23 1.7323 -7 1 1 4 53.07 1.39 1.7258 -5 1 3 4 53.97 4.18 1.6989 3 4 2 4 54.53 2.87 1.6827 2 6 1 4 54.63 3.87 1.6801 -6 3 2 4 54.65 1.83 1.6795 7 1 0 4 54.78 5.80 1.6757 -4 3 3 4 54.83 4.05 1.6743 -7 2 1 4 54.85 7.01 1.6737 1 3 3 4 54.89 1.11 1.6725 6 2 1 4 55.04 6.30 1.6684 -5 2 3 4 55.57 2.16 1.6537 -5 5 1 4 55.64 19.56 1.6518 5 4 1 4 55.71 6.97 1.6500 2 5 2 4 55.85 4.72 1.6462 -1 4 3 4 55.99 2.65 1.6424 5 1 2 4 56.58 7.48 1.6265 7 2 0 4 56.98 3.46 1.6162 -3 4 3 4 57.10 1.41 1.6130 -6 0 3 2 57.74 3.68 1.5968 -6 1 3 4 57.86 5.24 1.5937 3 1 3 4 57.97 3.56 1.5909 4 6 0 4 58.02 2.19 1.5898 3 6 1 4 58.03 1.50 1.5893 -7 3 1 4 58.09 1.27 1.5879 0 6 2 4 58.33 4.65 1.5819 2 3 3 4 59.32 5.49 1.5579 2 7 0 4 59.35 2.84 1.5573 -1 7 1 4 59.61 1.50 1.5510 -6 2 3 4 59.64 7.53 1.5504 -5 5 2 4 59.71 1.23 1.5487 3 5 2 4 59.79 4.25 1.5468 1 6 2 4 60.45 1.52 1.5313 -2 7 1 4 60.47 1.33 1.5310 1 7 1 4 60.73 2.28 1.5250 -2 0 4 2 60.91 3.62 1.5210 -8 1 1 4 61.23 4.69 1.5138 -6 5 1 4 61.28 2.39 1.5127 5 5 1 4 61.91 1.27 1.4988 -1 1 4 4 62.34 3.17 1.4895 -7 4 1 4 62.42 6.50 1.4877 -5 6 1 4 62.46 1.52 1.4869 4 6 1 4 62.53 1.28 1.4854 -5 4 3 4 62.54 1.56 1.4852 -8 0 2 2 62.58 1.03 1.4844 0 5 3 4 62.64 2.85 1.4830 -3 7 1 4 62.72 1.52 1.4813 -8 2 1 4 62.77 4.05 1.4802 3 3 3 4 62.79 1.45 1.4799 7 2 1 4 62.81 2.62 1.4795 4 0 3 2 62.88 5.88 1.4779 -4 0 4 2 62.95 1.44 1.4764 0 0 4 2 62.96 1.41 1.4763 5 6 0 4 63.15 1.40 1.4723 -2 2 4 4 63.26 2.98 1.4700 -7 1 3 4 63.40 5.72 1.4670 4 1 3 4 63.55 2.26 1.4640 0 1 4 4 63.67 2.72 1.4615 -3 2 4 4 64.68 4.60 1.4412 -4 5 3 4 64.74 3.42 1.4399 1 5 3 4 64.88 2.99 1.4372 8 2 0 4 64.92 1.21 1.4364 -8 2 2 4 65.04 3.16 1.4340 -7 2 3 4 65.04 3.66 1.4340 6 2 2 4 65.08 1.05 1.4332 -7 4 2 4 65.32 3.18 1.4285 0 2 4 4 65.75 3.68 1.4203 7 3 1 4 65.84 4.05 1.4186 4 7 0 4 65.88 1.06 1.4178 3 7 1 4 65.93 3.93 1.4168 -2 7 2 4 65.95 1.60 1.4164 0 7 2 4 66.16 6.96 1.4125 0 8 0 2 66.23 1.16 1.4112 -5 6 2 4 66.23 2.16 1.4111 1 1 4 4 66.30 1.37 1.4099 3 6 2 4 66.61 3.47 1.4040 -3 3 4 4 67.64 1.06 1.3851 -7 5 1 4 67.69 1.58 1.3842 6 5 1 4 67.79 3.04 1.3824 8 3 0 4 67.91 2.70 1.3802 2 5 3 4 67.95 1.39 1.3795 6 3 2 4 67.95 1.41 1.3795 -2 6 3 4 67.97 1.90 1.3792 1 2 4 4 68.25 1.35 1.3742 2 8 0 4 68.91 3.66 1.3627 8 0 1 2 68.98 1.75 1.3615 -3 6 3 4 69.19 1.26 1.3577 7 5 0 4 69.75 2.44 1.3483 -6 1 4 4 69.88 1.39 1.3460 2 1 4 4 70.04 3.69 1.3434 4 7 1 4 70.07 1.81 1.3428 -4 7 2 4 70.65 5.94 1.3332 -1 4 4 4 70.72 3.53 1.3322 -5 3 4 4 70.99 3.23 1.3278 -9 1 2 4 71.08 1.27 1.3263 1 6 3 4 71.26 4.87 1.3234 -8 2 3 4 71.42 1.13 1.3208 5 2 3 4 71.97 1.74 1.3120 9 1 0 4 72.03 2.23 1.3111 3 5 3 4 72.80 3.18 1.2991 7 2 2 4 73.62 1.09 1.2867 -5 7 2 4 73.85 1.18 1.2832 -7 6 1 4 74.03 3.79 1.2805 -5 6 3 4 74.35 1.02 1.2758 4 8 0 4 74.46 3.60 1.2742 0 8 2 4 74.63 2.12 1.2718 -5 4 4 4 75.16 1.12 1.2641 -2 5 4 4 75.28 2.72 1.2624 -1 7 3 4 75.36 2.15 1.2613 7 6 0 4 75.64 1.26 1.2573 -3 5 4 4 75.67 1.61 1.2568 -1 5 4 4 76.11 1.92 1.2506 3 2 4 4 76.76 2.77 1.2417 8 5 0 4 76.78 1.28 1.2413 6 1 3 4 76.91 1.14 1.2397 -7 5 3 4 77.75 3.22 1.2283 -9 4 1 4 78.06 4.88 1.2243 5 4 3 4 78.16 1.04 1.2229 4 7 2 4 78.24 1.34 1.2218 -9 2 3 4 78.39 2.61 1.2198 -4 8 2 4 78.44 2.14 1.2193 -10 1 1 4 78.44 2.35 1.2192 2 8 2 4 78.51 1.78 1.2183 -2 0 5 2 79.27 3.35 1.2085 -9 4 2 4 80.66 1.88 1.1911 -3 2 5 4 80.70 2.55 1.1907 -3 9 1 4 80.72 2.04 1.1905 2 9 1 4 81.15 1.76 1.1852 -2 6 4 4 82.03 1.36 1.1747 0 1 5 4 82.47 3.95 1.1696 -7 4 4 4 82.72 1.96 1.1666 8 6 0 4 82.84 1.21 1.1653 9 3 1 4 82.87 2.15 1.1649 6 6 2 4 83.00 1.31 1.1634 10 2 0 4 83.08 1.86 1.1626 2 5 4 4 83.21 1.89 1.1611 -6 8 1 4 83.54 1.70 1.1573 5 7 2 4 83.60 1.23 1.1566 4 9 0 4 83.64 1.69 1.1562 3 9 1 4 83.69 1.83 1.1556 -2 9 2 4 83.88 1.41 1.1535 -10 0 3 2 84.22 1.33 1.1497 4 3 4 4 84.61 1.60 1.1453 7 1 3 4 84.72 1.96 1.1442 -9 4 3 4 86.16 1.73 1.1287 -6 8 2 4 86.43 1.56 1.1259 -6 2 5 4 86.59 3.12 1.1242 9 4 1 4 88.11 2.51 1.1087 -1 4 5 4 88.12 1.37 1.1086 -2 7 4 4 88.23 1.56 1.1075 10 1 1 4 88.31 1.18 1.1067 2 0 5 2 88.66 2.74 1.1032 -8 6 3 4 88.66 1.61 1.1032 -7 1 5 4 88.95 1.20 1.1004 -2 10 1 4 88.96 1.63 1.1003 1 10 1 4 89.05 2.44 1.0994 6 8 1 4 89.25 1.51 1.0974 2 8 3 4 89.95 1.40 1.0907 4 7 3 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.