Cu4Bi4S9 Takeuchi Y, Ozawa T Zeitschrift fur Kristallographie 141 (1975) 217-232 The structure of Cu4Bi4S9 and its relation to the structures of covellite, CuS and bismuthinite, Bi2S3 _database_code_amcsd 0010774 CELL PARAMETERS: 11.5890 32.0500 3.9510 90.000 90.000 90.000 SPACE GROUP: Pbnm X-RAY WAVELENGTH: 1.541838 Cell Volume: 1467.510 Density (g/cm3): 6.239 MAX. ABS. INTENSITY / VOLUME**2: 35.77171972 RIR: 1.867 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 5.51 25.48 16.0250 0 2 0 2 9.42 2.21 9.3907 1 2 0 4 13.43 35.86 6.5906 1 4 0 4 15.29 18.49 5.7945 2 0 0 2 15.54 18.94 5.7021 2 1 0 4 15.80 65.48 5.6092 1 5 0 4 16.60 5.25 5.3417 0 6 0 2 17.41 1.82 5.0935 2 3 0 4 18.29 5.16 4.8511 1 6 0 4 18.90 13.25 4.6953 2 4 0 4 20.66 1.45 4.2985 2 5 0 4 20.86 2.97 4.2583 1 7 0 4 22.19 5.47 4.0062 0 8 0 2 23.19 3.53 3.8361 0 2 1 4 23.19 20.28 3.8352 3 1 0 4 23.50 46.89 3.7864 1 8 0 4 23.69 48.81 3.7554 3 2 0 4 23.96 14.30 3.7144 1 1 1 8 24.44 47.70 3.6418 1 2 1 8 24.50 1.51 3.6328 3 3 0 4 24.78 81.47 3.5924 2 7 0 4 25.13 17.68 3.5436 0 4 1 4 25.23 19.94 3.5296 1 3 1 8 25.60 52.45 3.4797 3 4 0 4 26.18 3.81 3.4040 1 9 0 4 26.30 18.94 3.3887 1 4 1 8 26.95 13.44 3.3086 3 5 0 4 27.06 1.26 3.2953 2 8 0 4 27.46 79.71 3.2476 2 1 1 8 27.62 13.55 3.2301 1 5 1 8 27.84 36.20 3.2050 0 10 0 2 27.89 29.50 3.1987 2 2 1 8 28.09 100.00 3.1765 0 6 1 4 28.52 34.22 3.1302 3 6 0 4 28.59 41.71 3.1219 2 3 1 8 28.90 10.31 3.0890 1 10 0 4 29.15 22.08 3.0635 1 6 1 8 29.44 12.95 3.0340 2 9 0 4 30.27 1.39 2.9525 3 7 0 4 30.74 46.43 2.9089 2 5 1 8 30.86 46.06 2.8972 4 0 0 2 30.87 2.08 2.8963 1 7 1 8 31.38 6.04 2.8510 4 2 0 4 31.66 51.28 2.8257 1 11 0 4 31.81 64.17 2.8131 0 8 1 4 31.91 10.03 2.8046 2 10 0 4 32.01 5.46 2.7962 4 3 0 4 32.13 16.73 2.7854 2 6 1 8 32.41 55.63 2.7621 3 0 1 4 32.54 14.58 2.7519 3 1 1 8 32.76 16.41 2.7337 1 8 1 8 32.87 20.51 2.7246 4 4 0 4 32.90 4.27 2.7220 3 2 1 8 33.51 5.49 2.6742 3 3 1 8 33.55 2.12 2.6708 0 12 0 2 33.72 7.78 2.6580 2 7 1 8 34.25 7.46 2.6183 3 9 0 4 34.34 15.52 2.6113 3 4 1 8 34.45 6.52 2.6031 2 11 0 4 34.46 2.50 2.6026 1 12 0 4 34.79 3.30 2.5789 1 9 1 8 35.24 1.20 2.5468 4 6 0 4 35.39 21.69 2.5367 3 5 1 8 36.09 44.86 2.4890 0 10 1 4 36.63 38.49 2.4535 3 6 1 8 36.94 2.55 2.4335 1 10 1 8 37.06 3.75 2.4256 2 12 0 4 38.05 1.81 2.3651 3 7 1 8 38.64 2.37 2.3302 4 1 1 8 38.71 7.63 2.3262 3 11 0 4 38.96 18.88 2.3120 4 2 1 8 38.96 5.01 2.3118 5 1 0 4 39.20 1.42 2.2984 1 11 1 8 39.28 7.23 2.2939 5 2 0 4 39.36 3.27 2.2893 0 14 0 2 39.48 3.52 2.2825 4 3 1 8 39.73 1.39 2.2686 2 13 0 4 39.80 1.05 2.2651 5 3 0 4 40.15 1.13 2.2459 1 14 0 4 40.52 6.25 2.2265 5 4 0 4 40.78 7.99 2.2127 0 12 1 4 41.09 8.80 2.1969 3 12 0 4 41.12 2.58 2.1951 4 5 1 8 41.37 7.82 2.1826 3 9 1 8 41.43 11.47 2.1797 5 5 0 4 41.54 16.28 2.1737 2 11 1 8 41.55 6.53 2.1734 1 12 1 8 42.22 8.40 2.1406 4 6 1 8 42.46 6.01 2.1291 2 14 0 4 42.52 2.91 2.1263 5 6 0 4 43.24 44.99 2.0923 3 10 1 8 43.49 13.34 2.0811 4 7 1 8 43.55 2.40 2.0782 3 13 0 4 43.78 2.81 2.0679 5 7 0 4 43.79 9.23 2.0671 2 12 1 8 44.08 1.27 2.0544 4 11 0 4 44.91 3.35 2.0183 4 8 1 8 45.20 4.26 2.0062 5 8 0 4 45.23 5.53 2.0047 2 15 0 4 45.24 1.24 2.0045 3 11 1 8 45.27 10.59 2.0031 0 16 0 2 45.36 2.69 1.9992 5 0 1 4 45.46 11.37 1.9953 5 1 1 8 45.74 12.40 1.9838 5 2 1 8 45.81 1.30 1.9808 0 14 1 4 45.94 62.17 1.9755 0 0 2 2 45.98 7.73 1.9739 1 16 0 4 46.09 2.47 1.9694 3 14 0 4 46.14 4.50 1.9673 2 13 1 8 46.20 11.65 1.9651 5 3 1 8 46.51 20.08 1.9525 1 14 1 8 46.76 2.11 1.9426 5 9 0 4 46.84 2.78 1.9397 5 4 1 8 47.05 1.76 1.9315 6 0 0 2 47.41 1.70 1.9176 6 2 0 4 47.65 1.91 1.9085 5 5 1 8 47.86 5.68 1.9007 6 3 0 4 48.08 2.86 1.8923 1 4 2 8 48.20 67.55 1.8880 4 10 1 8 48.48 10.34 1.8777 6 4 0 4 48.48 1.66 1.8776 4 13 0 4 48.57 3.54 1.8743 2 14 1 8 48.63 10.01 1.8724 5 6 1 8 48.70 1.72 1.8698 2 0 2 4 48.70 1.32 1.8697 3 15 0 4 48.79 2.35 1.8666 2 1 2 8 48.88 6.97 1.8633 1 5 2 8 49.11 10.75 1.8552 1 15 1 8 49.17 1.04 1.8528 0 6 2 4 49.77 8.36 1.8321 5 7 1 8 50.04 5.46 1.8227 4 11 1 8 50.10 1.56 1.8209 2 4 2 8 50.30 10.74 1.8139 5 11 0 4 50.83 2.24 1.7962 4 14 0 4 50.94 11.54 1.7928 2 17 0 4 51.09 1.35 1.7878 2 15 1 8 51.12 8.83 1.7866 0 16 1 4 51.31 1.72 1.7806 0 18 0 2 51.38 1.03 1.7783 3 16 0 4 51.77 2.84 1.7658 1 16 1 8 52.08 3.84 1.7562 3 1 2 8 52.23 9.24 1.7514 1 8 2 8 52.26 11.57 1.7505 5 12 0 4 52.33 9.57 1.7484 3 2 2 8 52.84 3.72 1.7327 6 1 1 8 52.89 15.62 1.7310 2 7 2 8 53.09 1.36 1.7252 6 2 1 8 53.33 11.45 1.7180 3 4 2 8 53.50 3.93 1.7128 6 3 1 8 53.69 1.62 1.7073 2 16 1 8 53.87 2.54 1.7020 2 18 0 4 54.01 3.88 1.6978 6 9 0 4 54.06 7.28 1.6962 5 10 1 8 54.07 3.31 1.6962 3 5 2 8 54.07 8.74 1.6959 6 4 1 8 54.28 6.87 1.6900 3 15 1 8 54.51 1.95 1.6835 1 17 1 8 54.57 8.12 1.6817 0 10 2 4 54.96 7.62 1.6706 3 6 2 8 55.19 2.48 1.6643 1 10 2 8 55.51 3.69 1.6555 2 9 2 8 55.55 1.64 1.6543 6 10 0 4 55.59 1.47 1.6534 7 1 0 4 55.70 1.20 1.6504 6 6 1 8 55.77 2.48 1.6485 5 11 1 8 55.79 12.34 1.6477 4 16 0 4 56.26 2.79 1.6352 4 14 1 8 56.36 9.59 1.6326 2 17 1 8 56.37 11.57 1.6322 4 0 2 4 56.69 1.37 1.6238 4 2 2 8 56.73 1.80 1.6226 6 7 1 8 56.77 1.05 1.6216 3 16 1 8 56.87 14.25 1.6191 1 11 2 8 57.02 2.93 1.6151 2 10 2 8 57.08 1.65 1.6135 4 3 2 8 57.22 1.28 1.6099 6 11 0 4 57.49 6.52 1.6030 7 5 0 4 57.64 6.34 1.5993 4 4 2 8 57.91 5.63 1.5923 6 8 1 8 58.11 6.25 1.5874 1 20 0 4 58.53 2.69 1.5770 3 9 2 8 58.67 1.65 1.5736 2 11 2 8 59.24 2.70 1.5599 6 9 1 8 59.36 2.00 1.5569 7 7 0 4 59.53 1.56 1.5528 5 13 1 8 60.44 1.43 1.5318 2 12 2 8 60.69 1.87 1.5259 6 10 1 8 60.72 4.23 1.5252 7 1 1 8 61.09 5.59 1.5170 4 18 0 4 61.26 1.62 1.5131 1 21 0 4 61.59 3.10 1.5058 3 11 2 8 61.77 1.72 1.5018 5 1 2 8 61.92 3.61 1.4986 2 19 1 8 62.00 2.69 1.4969 5 2 2 8 62.01 1.05 1.4966 3 18 1 8 62.06 1.38 1.4956 0 14 2 4 62.27 1.32 1.4909 6 11 1 8 62.53 1.34 1.4854 7 5 1 8 62.89 3.06 1.4777 5 4 2 8 63.31 4.55 1.4689 3 12 2 8 63.35 1.29 1.4681 7 6 1 8 63.56 5.85 1.4638 5 5 2 8 63.85 1.66 1.4578 4 19 0 4 64.30 3.68 1.4486 8 0 0 2 64.33 2.69 1.4482 2 14 2 8 64.37 1.44 1.4473 5 6 2 8 64.81 1.91 1.4385 2 20 1 8 64.97 3.90 1.4355 8 3 0 4 65.33 1.31 1.4284 5 7 2 8 65.41 1.18 1.4268 7 8 1 8 65.79 1.32 1.4194 3 21 0 4 66.13 6.17 1.4130 1 21 1 8 66.41 2.18 1.4076 5 8 2 8 66.44 2.87 1.4071 2 15 2 8 66.47 5.53 1.4066 0 16 2 4 66.64 1.22 1.4034 7 9 1 8 66.70 2.89 1.4023 4 20 0 4 67.02 4.05 1.3963 1 16 2 8 67.11 1.36 1.3947 3 14 2 8 67.58 1.32 1.3861 3 20 1 8 67.64 1.02 1.3851 5 9 2 8 67.76 2.57 1.3829 6 14 1 8 68.40 1.31 1.3716 5 17 1 8 68.51 2.93 1.3697 6 3 2 8 68.67 2.44 1.3669 0 22 1 4 68.93 1.05 1.3623 8 8 0 4 69.00 5.80 1.3610 6 4 2 8 69.13 2.88 1.3589 8 1 1 8 69.21 7.47 1.3575 1 22 1 8 69.50 5.43 1.3525 7 11 1 8 69.69 2.03 1.3492 8 3 1 8 70.48 5.63 1.3361 5 11 2 8 70.49 5.05 1.3358 3 21 1 8 70.52 1.61 1.3354 0 24 0 2 70.82 1.44 1.3305 8 5 1 8 70.83 1.16 1.3304 2 22 1 8 70.87 8.67 1.3296 5 18 1 8 70.91 1.27 1.3290 4 14 2 8 71.00 5.82 1.3276 2 17 2 8 71.12 2.18 1.3256 7 12 1 8 71.37 2.64 1.3215 4 20 1 8 71.59 5.56 1.3180 8 6 1 8 72.00 1.08 1.3116 6 16 1 8 72.09 6.78 1.3102 5 12 2 8 72.47 1.57 1.3042 1 2 3 8 72.50 3.18 1.3038 8 7 1 8 73.43 1.55 1.2894 2 18 2 8 73.49 1.00 1.2886 3 22 1 8 73.54 1.29 1.2879 8 8 1 8 73.56 2.13 1.2876 6 9 2 8 73.85 2.48 1.2832 2 1 3 8 74.15 3.92 1.2787 0 6 3 4 74.22 1.06 1.2777 4 21 1 8 74.29 3.24 1.2768 6 17 1 8 74.40 1.43 1.2751 2 3 3 8 74.68 1.10 1.2710 1 6 3 8 74.71 4.57 1.2706 8 9 1 8 74.86 1.04 1.2683 6 10 2 8 75.07 8.30 1.2653 4 16 2 8 75.50 2.35 1.2592 2 5 3 8 75.61 1.16 1.2576 1 24 1 8 76.01 2.16 1.2520 8 10 1 8 76.08 2.76 1.2511 0 8 3 4 76.23 1.82 1.2490 8 13 0 4 76.25 1.02 1.2487 2 6 3 8 76.41 2.55 1.2465 3 0 3 4 76.54 4.26 1.2447 7 5 2 8 77.07 3.98 1.2374 1 20 2 8 77.38 1.06 1.2333 6 20 0 4 77.44 1.05 1.2324 8 11 1 8 77.49 1.27 1.2317 3 4 3 8 77.93 3.49 1.2259 9 8 0 4 78.10 1.47 1.2236 3 5 3 8 78.17 1.38 1.2228 7 7 2 8 78.33 4.25 1.2207 9 2 1 8 78.52 2.42 1.2182 0 10 3 4 78.85 2.89 1.2139 3 6 3 8 79.19 3.51 1.2095 6 19 1 8 79.69 3.81 1.2032 4 18 2 8 79.85 1.25 1.2012 1 21 2 8 80.30 1.30 1.1956 4 2 3 8 81.04 1.24 1.1866 7 17 1 8 81.86 1.23 1.1767 0 26 1 4 81.99 1.48 1.1752 2 11 3 8 82.11 1.60 1.1738 8 16 0 4 82.18 1.28 1.1730 4 19 2 8 82.59 2.87 1.1682 8 0 2 4 83.15 3.68 1.1618 3 10 3 8 83.19 3.15 1.1613 8 3 2 8 83.32 1.21 1.1598 4 7 3 8 83.56 1.38 1.1571 5 24 0 4 83.95 1.20 1.1527 3 21 2 8 84.70 1.15 1.1443 5 1 3 8 84.78 2.36 1.1435 4 20 2 8 84.90 1.31 1.1421 5 2 3 8 85.18 1.25 1.1391 1 28 0 4 85.24 1.20 1.1385 5 3 3 8 85.47 2.36 1.1361 1 14 3 8 85.90 1.09 1.1314 1 27 1 8 86.71 7.23 1.1229 4 10 3 8 87.03 1.25 1.1196 5 6 3 8 87.39 1.32 1.1159 1 15 3 8 87.43 2.69 1.1156 2 27 1 8 87.84 1.52 1.1114 10 1 1 8 88.34 1.38 1.1064 0 24 2 4 88.94 1.01 1.1005 0 16 3 4 89.43 1.05 1.0957 10 5 1 8 89.55 1.15 1.0945 1 28 1 8 90.00 5.15 1.0903 4 26 1 8 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.