data_global _chemical_name_mineral 'Hutchinsonite' loop_ _publ_author_name 'Matsushita Y' 'Takeuchi Y' _journal_name_full 'Zeitschrift fur Kristallographie' _journal_volume 209 _journal_year 1994 _journal_page_first 475 _journal_page_last 478 _publ_section_title ; Refinement of the crystal structure of hutchinsonite, TlPbAs5S9 ; _database_code_amcsd 0011062 _chemical_formula_sum 'Pb Tl As4.782 Sb.218 S9' _cell_length_a 10.786 _cell_length_b 35.3890 _cell_length_c 8.141 _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_volume 3107.467 _exptl_crystal_density_diffrn 4.638 _symmetry_space_group_name_H-M 'P b c a' loop_ _space_group_symop_operation_xyz 'x,y,z' 'x,1/2-y,1/2+z' '-x,1/2+y,1/2-z' '1/2-x,1/2+y,z' '1/2+x,1/2-y,-z' '1/2+x,y,1/2-z' '1/2-x,-y,1/2+z' '-x,-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy _atom_site_U_iso_or_equiv PbM1 0.36090 0.24688 0.10582 1.00000 0.01317 TlM2 0.33847 0.12202 0.63384 1.00000 0.02305 As1 0.11100 0.19488 0.70450 1.00000 0.00937 As2 0.10210 0.18479 0.12620 0.94490 0.00836 Sb2 0.10210 0.18479 0.12620 0.05510 0.00836 As3 0.43470 0.11605 0.13310 0.83680 0.00950 Sb3 0.43470 0.11605 0.13310 0.16320 0.00950 As4 0.13670 0.04815 0.21610 1.00000 0.01216 As5 0.38230 0.02875 0.95440 1.00000 0.01001 S1 0.39750 0.18930 0.36480 1.00000 0.01140 S2 0.41190 0.19060 0.86370 1.00000 0.01267 S3 0.11500 0.25409 0.36960 1.00000 0.01013 S4 0.13030 0.13740 0.32370 1.00000 0.01267 S5 0.11560 0.14665 0.89600 1.00000 0.01267 S6 0.38760 0.01500 0.68530 1.00000 0.01900 S7 0.19490 0.05700 0.95290 1.00000 0.02280 S8 0.43720 0.06700 0.32670 1.00000 0.01393 S9 0.00760 0.07960 0.58510 1.00000 0.01520