data_global
_chemical_name_mineral 'Griphite'
loop_
_publ_author_name
'Rinaldi R'
_journal_name_full 'Bulletin de Mineralogie'
_journal_volume 101 
_journal_year 1978
_journal_page_first 543
_journal_page_last 547
_publ_section_title
;
 The crystal structure of griphite, a complex phosphate, not a garnetoid
;
_database_code_amcsd 0012066
_chemical_compound_source 'Alberes, East Pyrenees, France'
_chemical_formula_sum 'Mn3.54 Na1.02 Li.54 Ca1.42 Fe1.08 Mg.06 Al2.05 P5.82 O24.4 F1.6 H1.12'
_cell_length_a 12.205
_cell_length_b 12.205
_cell_length_c 12.205
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 1818.081
_exptl_crystal_density_diffrn      3.646
_symmetry_space_group_name_H-M 'P a 3'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+z,x,1/2-y'
  'z,1/2-x,1/2+y'
  '1/2-z,1/2+x,y'
  '-z,-x,-y'
  '1/2+y,1/2-z,-x'
  '1/2-y,-z,1/2+x'
  '-y,1/2+z,1/2-x'
  'y,z,x'
  'x,1/2-y,1/2+z'
  '1/2-x,1/2+y,z'
  '1/2+x,y,1/2-z'
  '-x,-y,-z'
  '1/2-z,-x,1/2+y'
  '-z,1/2+x,1/2-y'
  '1/2+z,1/2-x,-y'
  'z,x,y'
  '1/2-y,1/2+z,x'
  '1/2+y,z,1/2-x'
  'y,1/2-z,1/2+x'
  '-y,-z,-x'
  '-x,1/2+y,1/2-z'
  '1/2+x,1/2-y,-z'
  '1/2-x,-y,1/2+z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Mn   0.00570   0.12080   0.26080   0.59000   0.01688
Na   0.00570   0.12080   0.26080   0.17000   0.01688
Li   0.00570   0.12080   0.26080   0.09000   0.01688
Ca   0.00570   0.12080   0.26080   0.07000   0.01688
Fe2+   0.00570   0.12080   0.26080   0.05000   0.01688
Mg   0.00570   0.12080   0.26080   0.01000   0.01688
Ca   0.00000   0.00000   0.00000   1.00000   0.01298
Fe2+   0.50000   0.50000   0.50000   0.70000   0.01330
Al   0.50000   0.50000   0.50000   0.13000   0.01330
Al   0.28460   0.28460   0.28460   0.96000   0.01165
Fe3+   0.28460   0.28460   0.28460   0.04000   0.01165
P   0.04030   0.35970   0.23520   0.97000   0.01216
O1   0.12760   0.28480   0.28760   0.97000   0.01482
O-H1   0.12760   0.28480   0.28760   0.03000   0.01482
O2   0.27850   0.44030   0.28280   0.97000   0.01596
O-H2   0.27850   0.44030   0.28280   0.03000   0.01596
O3   0.07820   0.39590   0.11940   0.97000   0.01798
O-H3   0.07820   0.39590   0.11940   0.03000   0.01798
O4   0.01710   0.46040   0.30360   0.97000   0.01976
O-H4   0.01710   0.46040   0.30360   0.03000   0.01976
F   0.11450   0.11450   0.11450   0.80000   0.02356
O-H   0.11450   0.11450   0.11450   0.20000   0.02356