data_global
_amcsd_formula_title 'Bi4 Cu5 O19.06 Sr7.86'
loop_
_publ_author_name
'Caldes M'
'Navarro J'
'Perez F'
'Carrera M'
'Fontcuberta J'
'Casan-Pastor N'
'Miravitlles C'
'Obradors X'
'Rodriguez-Carjaval J'
'Gonzalez-Calbet J'
'Vallet-Regi M'
'Garcia A'
'Fuertes A'
_journal_name_full 'Chemistry of Materials'
_journal_volume 3 
_journal_year 1991
_journal_page_first 844
_journal_page_last 852
_publ_section_title
;
 Electron microscopy, neutron diffraction and physical properties
 of Bi4Sr8Cu5O19+y
 _cod_database_code 1006049
;
_database_code_amcsd 0012198
_chemical_formula_sum 'Bi4 Sr7.86 Cu5 O19.06'
_cell_length_a 5.3671
_cell_length_b 33.9719
_cell_length_c 24.0722
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 4389.098
_exptl_crystal_density_diffrn      6.499
_symmetry_space_group_name_H-M 'F m m m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x,1/2+y,1/2+z'
  '1/2+x,y,1/2+z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  'x,1/2-y,1/2+z'
  '1/2+x,-y,1/2+z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '-x,1/2+y,1/2-z'
  '1/2-x,y,1/2-z'
  '1/2-x,1/2+y,-z'
  '-x,y,z'
  '-x,1/2+y,1/2+z'
  '1/2-x,y,1/2+z'
  '1/2-x,1/2+y,z'
  'x,-y,-z'
  'x,1/2-y,1/2-z'
  '1/2+x,-y,1/2-z'
  '1/2+x,1/2-y,-z'
  'x,y,-z'
  'x,1/2+y,1/2-z'
  '1/2+x,y,1/2-z'
  '1/2+x,1/2+y,-z'
  '-x,-y,z'
  '-x,1/2-y,1/2+z'
  '1/2-x,-y,1/2+z'
  '1/2-x,1/2-y,z'
  '-x,-y,-z'
  '-x,1/2-y,1/2-z'
  '1/2-x,-y,1/2-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
Bi1   0.00000   0.28830   0.18890   1.00000
Bi2   0.00000   0.13430   0.19090   1.00000
Sr1   0.00000   0.21120   0.07410   1.00000
Sr2   0.00000   0.05730   0.08550   0.93000
Sr3   0.00000   0.36520   0.07830   1.00000
Sr4   0.00000   0.44550   0.19610   1.00000
Cu1   0.00000   0.44220   0.00000   1.00000
Cu2   0.00000   0.13390   0.00000   1.00000
Cu3   0.00000   0.29010   0.00000   1.00000
Cu4   0.00000   0.50000   0.08330   1.00000
Cu5   0.00000   0.00000   0.19470   1.00000
O1   0.00000   0.13510   0.10470   1.00000
O2   0.50000   0.20930   0.10260   1.00000
O3   0.00000   0.07400   0.19630   1.00000
O4   0.50000   0.05620   0.08130   0.84200
O5   0.38250   0.27530   0.18350   0.50000
O6   0.40180   0.13290   0.18450   0.50000
O7   0.23500   0.09320   0.00000   0.62000
O8   0.25410   0.17110   0.00000   1.00000
O9   0.25000   0.25000   0.00000   1.00000
O10   0.23940   0.00000   0.13920   0.79600
O11   0.25000   0.00000   0.25000   1.00000
O12   0.35750   0.00000   0.00000   0.54400