data_global _amcsd_formula_title 'Co O3.111 Sr0.9999 Tl0.41' loop_ _publ_author_name 'Boullay P' 'Domenges B' 'Hervieu M' 'Groult D' 'Raveau B' _journal_name_full 'Chemistry of Materials' _journal_volume 8 _journal_year 1996 _journal_page_first 1482 _journal_page_last 1489 _publ_section_title ; Evidence for the first misfit layer oxide Tl0.41 (Sr0.9 O)1.12 Co O2 _cod_database_code 1001719 ; _database_code_amcsd 0012211 _chemical_formula_sum 'Sr9 Co9 Tl3.69 O28' _cell_length_a 4.95 _cell_length_b 25.18999 _cell_length_c 11.66 _cell_angle_alpha 90 _cell_angle_beta 97.76 _cell_angle_gamma 90 _cell_volume 1440.576 _exptl_crystal_density_diffrn 5.812 _symmetry_space_group_name_H-M 'C 1 m 1' loop_ _space_group_symop_operation_xyz 'x,y,z' '1/2+x,1/2+y,z' 'x,-y,z' '1/2+x,1/2-y,z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy Sr1 0.02500 0.00000 0.89000 0.90000 Sr2 0.02500 0.20000 0.89000 0.90000 Sr3 0.02500 0.40000 0.89000 0.90000 Sr4 0.02500 0.50000 0.11000 0.90000 Sr5 0.02500 0.70000 0.11000 0.90000 Sr6 0.02500 0.90000 0.11000 0.90000 Co1 0.00000 0.00000 0.50000 1.00000 Co2 0.00000 0.11100 0.50000 1.00000 Co3 0.00000 0.22200 0.50000 1.00000 Co4 0.00000 0.33300 0.50000 1.00000 Co5 0.00000 0.44400 0.50000 1.00000 Tl1 0.40000 0.00000 0.71000 0.61500 Tl2 0.40000 0.22200 0.71000 0.61500 Tl3 0.45000 0.50000 0.28000 0.61500 Tl4 0.45000 0.72250 0.28000 0.61500 O1 0.02000 0.00000 0.11000 1.00000 O2 0.02000 0.20000 0.11000 1.00000 O3 0.02000 0.40000 0.11000 1.00000 O4 0.02000 0.50000 0.89000 1.00000 O5 0.02000 0.70000 0.89000 1.00000 O6 0.02000 0.90000 0.89000 1.00000 O7 0.30000 0.00000 0.40000 1.00000 O8 0.30000 0.11100 0.40000 1.00000 O9 0.30000 0.22200 0.40000 1.00000 O10 0.30000 0.33300 0.40000 1.00000 O11 0.30000 0.44400 0.40000 1.00000 O12 0.20000 0.05550 0.60000 1.00000 O13 0.20000 0.16650 0.60000 1.00000 O14 0.20000 0.27750 0.60000 1.00000 O15 0.20000 0.38850 0.60000 1.00000 O16 0.20000 0.50000 0.60000 1.00000