data_global _amcsd_formula_title 'Cd0.6 O4 Sn Zn1.4' loop_ _publ_author_name 'Choisnet J' 'Deschanvres A' 'Raveau B' _journal_name_full 'Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences' _journal_volume 266 _journal_year 1968 _journal_page_first 543 _journal_page_last 545 _publ_section_title ; Substitution du zinc par le cadmium dans le spinelle Zn2 Sn O4. Etude de la repartition des cations dans la solution solide Zn2-2xCd2xSnO4 _cod_database_code 1001190 ; _database_code_amcsd 0012269 _chemical_formula_sum 'Zn1.4 Cd.6 Sn O4' _cell_length_a 8.82 _cell_length_b 8.82 _cell_length_c 8.82 _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_volume 686.129 _exptl_crystal_density_diffrn 6.616 _symmetry_space_group_name_H-M 'F d 3 m' loop_ _space_group_symop_operation_xyz 'x,y,z' 'x,1/2+y,1/2+z' '1/2+x,y,1/2+z' '1/2+x,1/2+y,z' '3/4+z,3/4-x,1/4+y' '3/4+z,1/4-x,3/4+y' '1/4+z,3/4-x,3/4+y' '1/4+z,1/4-x,1/4+y' '-y,1/2+z,1/2-x' '-y,+z,-x' '1/2-y,1/2+z,-x' '1/2-y,+z,1/2-x' '3/4+x,3/4-y,1/4+z' '3/4+x,1/4-y,3/4+z' '1/4+x,3/4-y,3/4+z' '1/4+x,1/4-y,1/4+z' '-z,1/2+x,1/2-y' '-z,+x,-y' '1/2-z,1/2+x,-y' '1/2-z,+x,1/2-y' '3/4+y,3/4-z,1/4+x' '3/4+y,1/4-z,3/4+x' '1/4+y,3/4-z,3/4+x' '1/4+y,1/4-z,1/4+x' '-x,1/2+y,1/2-z' '-x,+y,-z' '1/2-x,1/2+y,-z' '1/2-x,+y,1/2-z' '1/2+x,-z,1/2-y' '1/2+x,1/2-z,-y' '+x,-z,-y' '+x,1/2-z,1/2-y' '3/4-z,3/4+y,1/4+x' '3/4-z,1/4+y,3/4+x' '1/4-z,3/4+y,3/4+x' '1/4-z,1/4+y,1/4+x' '1/2+y,-x,1/2-z' '1/2+y,1/2-x,-z' '+y,-x,-z' '+y,1/2-x,1/2-z' '3/4-x,3/4+z,1/4+y' '3/4-x,1/4+z,3/4+y' '1/4-x,3/4+z,3/4+y' '1/4-x,1/4+z,1/4+y' '1/2+z,-y,1/2-x' '1/2+z,1/2-y,-x' '+z,-y,-x' '+z,1/2-y,1/2-x' '3/4-y,3/4+x,1/4+z' '3/4-y,1/4+x,3/4+z' '1/4-y,3/4+x,3/4+z' '1/4-y,1/4+x,1/4+z' 'x,1/2+z,1/2+y' 'x,+z,+y' '1/2+x,1/2+z,+y' '1/2+x,+z,1/2+y' '1/4-z,3/4-y,3/4-x' '1/4-z,1/4-y,1/4-x' '3/4-z,3/4-y,1/4-x' '3/4-z,1/4-y,3/4-x' 'y,1/2+x,1/2+z' 'y,+x,+z' '1/2+y,1/2+x,+z' '1/2+y,+x,1/2+z' '1/4-x,3/4-z,3/4-y' '1/4-x,1/4-z,1/4-y' '3/4-x,3/4-z,1/4-y' '3/4-x,1/4-z,3/4-y' 'z,1/2+y,1/2+x' 'z,+y,+x' '1/2+z,1/2+y,+x' '1/2+z,+y,1/2+x' '1/4-y,3/4-x,3/4-z' '1/4-y,1/4-x,1/4-z' '3/4-y,3/4-x,1/4-z' '3/4-y,1/4-x,3/4-z' '3/4+z,1/4+x,3/4-y' '3/4+z,3/4+x,1/4-y' '1/4+z,1/4+x,1/4-y' '1/4+z,3/4+x,3/4-y' '-y,1/2-z,1/2+x' '-y,-z,+x' '1/2-y,1/2-z,+x' '1/2-y,-z,1/2+x' '3/4+x,1/4+y,3/4-z' '3/4+x,3/4+y,1/4-z' '1/4+x,1/4+y,1/4-z' '1/4+x,3/4+y,3/4-z' '-z,1/2-x,1/2+y' '-z,-x,+y' '1/2-z,1/2-x,+y' '1/2-z,-x,1/2+y' '3/4+y,1/4+z,3/4-x' '3/4+y,3/4+z,1/4-x' '1/4+y,1/4+z,1/4-x' '1/4+y,3/4+z,3/4-x' '-x,1/2-y,1/2+z' '-x,-y,+z' '1/2-x,1/2-y,+z' '1/2-x,-y,1/2+z' '1/4-z,3/4+x,3/4+y' '1/4-z,1/4+x,1/4+y' '3/4-z,3/4+x,1/4+y' '3/4-z,1/4+x,3/4+y' 'y,-z,-x' 'y,1/2-z,1/2-x' '1/2+y,-z,1/2-x' '1/2+y,1/2-z,-x' '1/4-x,3/4+y,3/4+z' '1/4-x,1/4+y,1/4+z' '3/4-x,3/4+y,1/4+z' '3/4-x,1/4+y,3/4+z' 'z,-x,-y' 'z,1/2-x,1/2-y' '1/2+z,-x,1/2-y' '1/2+z,1/2-x,-y' '1/4-y,3/4+z,3/4+x' '1/4-y,1/4+z,1/4+x' '3/4-y,3/4+z,1/4+x' '3/4-y,1/4+z,3/4+x' 'x,-y,-z' 'x,1/2-y,1/2-z' '1/2+x,-y,1/2-z' '1/2+x,1/2-y,-z' '1/2-x,1/2+z,-y' '1/2-x,+z,1/2-y' '-x,1/2+z,1/2-y' '-x,+z,-y' '1/4+z,3/4-y,3/4+x' '1/4+z,1/4-y,1/4+x' '3/4+z,3/4-y,1/4+x' '3/4+z,1/4-y,3/4+x' '1/2-y,1/2+x,-z' '1/2-y,+x,1/2-z' '-y,1/2+x,1/2-z' '-y,+x,-z' '1/4+x,3/4-z,3/4+y' '1/4+x,1/4-z,1/4+y' '3/4+x,3/4-z,1/4+y' '3/4+x,1/4-z,3/4+y' '1/2-z,1/2+y,-x' '1/2-z,+y,1/2-x' '-z,1/2+y,1/2-x' '-z,+y,-x' '1/4+y,3/4-x,3/4+z' '1/4+y,1/4-x,1/4+z' '3/4+y,3/4-x,1/4+z' '3/4+y,1/4-x,3/4+z' '-x,-z,y' '-x,1/2-z,1/2+y' '1/2-x,-z,1/2+y' '1/2-x,1/2-z,y' '3/4+z,3/4+y,1/4-x' '3/4+z,1/4+y,3/4-x' '1/4+z,3/4+y,3/4-x' '1/4+z,1/4+y,1/4-x' '-y,-x,z' '-y,1/2-x,1/2+z' '1/2-y,-x,1/2+z' '1/2-y,1/2-x,z' '3/4+x,3/4+z,1/4-y' '3/4+x,1/4+z,3/4-y' '1/4+x,3/4+z,3/4-y' '1/4+x,1/4+z,1/4-y' '-z,-y,x' '-z,1/2-y,1/2+x' '1/2-z,-y,1/2+x' '1/2-z,1/2-y,x' '3/4+y,3/4+x,1/4-z' '3/4+y,1/4+x,3/4-z' '1/4+y,3/4+x,3/4-z' '1/4+y,1/4+x,1/4-z' '1/4-z,1/4-x,1/4-y' '1/4-z,3/4-x,3/4-y' '3/4-z,1/4-x,3/4-y' '3/4-z,3/4-x,1/4-y' 'y,z,x' 'y,1/2+z,1/2+x' '1/2+y,z,1/2+x' '1/2+y,1/2+z,x' '1/4-x,1/4-y,1/4-z' '1/4-x,3/4-y,3/4-z' '3/4-x,1/4-y,3/4-z' '3/4-x,3/4-y,1/4-z' 'z,x,y' 'z,1/2+x,1/2+y' '1/2+z,x,1/2+y' '1/2+z,1/2+x,y' '1/4-y,1/4-z,1/4-x' '1/4-y,3/4-z,3/4-x' '3/4-y,1/4-z,3/4-x' '3/4-y,3/4-z,1/4-x' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy Zn1 0.00000 0.00000 0.00000 0.50000 Zn2 0.62500 0.62500 0.62500 0.45000 Cd1 0.00000 0.00000 0.00000 0.50000 Cd2 0.62500 0.62500 0.62500 0.05000 Sn1 0.62500 0.62500 0.62500 0.50000 O1 0.39000 0.39000 0.39000 1.00000