data_global
_chemical_name_mineral 'Vandenbrandeite'
loop_
_publ_author_name
'Rosenzweig A'
'Ryan R R'
_journal_name_full 'Crystal Structure Communications'
_journal_volume 6 
_journal_year 1977
_journal_page_first 53
_journal_page_last 56
_publ_section_title
;
 Vandenbrandeite CuUO2(OH)4
;
_database_code_amcsd 0012336
_chemical_compound_source 'Musonoi Mine, Kolwezi, Katanga, Zaire'
_chemical_formula_sum 'Cu U (O6 H4)'
_cell_length_a 7.855
_cell_length_b 5.449
_cell_length_c 6.089
_cell_angle_alpha 91.44
_cell_angle_beta 101.90
_cell_angle_gamma 89.2
_cell_volume 254.929
_exptl_crystal_density_diffrn      5.232
_symmetry_space_group_name_H-M 'P -1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Cu   0.09210   0.35090   0.85480
U   0.28400   0.14770   0.34220
O-H1   0.39400   0.40600   0.26900
O2   0.83600   0.11300   0.60400
O-H3   0.21900   0.04900   0.94500
O-H4   0.01000   0.31600   0.13800
O5   0.51700   0.89900   0.30400
O-H6   0.18600   0.40200   0.59900
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Cu 0.01526 0.00947 0.01114 0.00339 0.00464 0.00296
U 0.01137 0.00782 0.00989 0.00042 0.00186 0.00247
O-H1 0.02424 0.01097 0.01546 -0.00721 0.00209 -0.00279
O2 0.01436 0.01248 0.01600 -0.00191 0.00093 0.00066
O-H3 0.01796 0.01202 0.00485 0.00339 0.00255 0.00115
O-H4 0.01616 0.00797 0.01240 0.00276 0.00580 0.00592
O5 0.01018 0.02751 0.00935 0.00255 -0.00070 0.00181
O-H6 0.02185 0.01503 0.01078 0.00403 0.00812 0.00871