Bussenite Zhou H, Rastsvetaeva R K, Khomyakov A P, Ma Z, Shi N Crystallography Reports 47 (2002) 43-46 Crystal structure of new micalike titanosilicate - bussenite, Na2Ba2Fe2+[TiSi2O7][CO3]O(OH)(H2O)F Locality: Khibiny alkaline massif, Kola Peninsula, Russia _database_code_amcsd 0012376 CELL PARAMETERS: 5.3990 7.0160 16.2540 102.440 93.180 90.100 SPACE GROUP: P-1 X-RAY WAVELENGTH: 1.541838 Cell Volume: 600.251 Density (g/cm3): 3.714 MAX. ABS. INTENSITY / VOLUME**2: 6.601971432 RIR: 0.579 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 5.58 55.95 15.8464 0 0 1 2 11.17 100.00 7.9232 0 0 2 2 12.92 25.22 6.8506 0 1 0 2 12.92 22.92 6.8497 0 -1 1 2 15.16 2.97 5.8454 0 1 1 2 16.78 33.41 5.2821 0 0 3 2 17.68 2.80 5.0163 1 0 1 2 19.38 6.86 4.5801 -1 0 2 2 20.45 12.42 4.3426 1 0 2 2 21.08 5.28 4.2141 1 -1 1 2 21.12 5.10 4.2075 1 1 0 2 22.06 30.23 4.0296 -1 1 1 2 22.10 25.88 4.0231 -1 -1 2 2 22.44 1.95 3.9616 0 0 4 2 22.78 44.72 3.9037 1 -1 2 2 22.81 39.33 3.8988 1 1 1 2 22.89 36.73 3.8854 -1 0 3 2 23.38 4.68 3.8048 0 1 3 2 23.39 8.49 3.8037 0 -1 4 2 24.26 33.02 3.6692 1 0 3 2 24.57 23.41 3.6233 -1 1 2 2 24.60 20.63 3.6183 -1 -1 3 2 25.39 61.86 3.5080 0 -2 1 2 25.65 4.12 3.4733 1 -1 3 2 25.67 4.07 3.4700 1 1 2 2 26.01 17.41 3.4253 0 2 0 2 26.02 23.13 3.4248 0 -2 2 2 27.16 4.63 3.2830 -1 0 4 2 27.81 19.42 3.2080 0 2 1 2 27.82 12.30 3.2073 0 -2 3 2 28.04 16.64 3.1827 -1 1 3 2 28.07 21.18 3.1791 -1 -1 4 2 28.16 42.21 3.1693 0 0 5 2 28.35 9.85 3.1476 0 1 4 2 28.36 9.50 3.1468 0 -1 5 2 28.72 1.67 3.1085 1 0 4 2 29.37 36.54 3.0410 1 -1 4 2 29.39 39.60 3.0390 1 1 3 2 30.59 40.98 2.9227 0 2 2 2 30.60 31.89 2.9218 0 -2 4 2 30.73 4.94 2.9095 -1 2 0 2 30.78 3.89 2.9048 -1 -2 2 2 31.09 26.18 2.8768 1 -2 2 2 31.13 23.55 2.8728 1 2 0 2 31.93 25.54 2.8030 -1 0 5 2 32.11 5.58 2.7872 -1 2 1 2 32.17 8.01 2.7828 -1 -2 3 2 32.18 18.46 2.7817 -1 1 4 2 32.21 20.30 2.7792 -1 -1 5 2 32.80 64.53 2.7305 1 -2 3 2 32.84 73.45 2.7272 1 2 1 2 33.24 35.65 2.6951 2 0 0 2 33.40 56.72 2.6824 -2 0 1 2 33.61 32.83 2.6662 1 0 5 2 33.62 6.43 2.6655 0 1 5 2 33.63 6.69 2.6649 0 -1 6 2 33.70 4.80 2.6599 1 -1 5 2 33.71 4.54 2.6587 1 1 4 2 33.94 21.77 2.6411 0 0 6 2 34.13 1.69 2.6267 0 2 3 2 34.15 1.00 2.6259 0 -2 5 2 34.42 25.59 2.6057 -1 2 2 2 34.47 31.22 2.6018 -1 -2 4 2 34.53 30.85 2.5972 -2 0 2 2 35.80 20.36 2.5082 2 0 2 2 35.94 1.06 2.4989 2 -1 1 2 36.28 1.25 2.4759 -2 -1 2 2 36.81 1.03 2.4418 -1 1 5 2 37.04 14.64 2.4272 -1 0 6 2 37.16 1.57 2.4197 2 -1 2 2 37.50 5.47 2.3986 -1 2 3 2 37.55 3.70 2.3955 -1 -2 5 2 38.27 3.63 2.3520 0 2 4 2 38.28 3.26 2.3513 0 -2 6 2 38.35 2.99 2.3469 2 0 3 2 38.60 2.61 2.3324 0 -3 1 2 38.60 2.08 2.3323 0 -3 2 2 38.69 2.32 2.3274 1 -2 5 2 38.72 2.95 2.3256 1 2 3 2 38.82 4.17 2.3198 1 0 6 2 39.11 28.05 2.3031 0 1 6 2 39.12 32.07 2.3026 0 -1 7 2 39.21 1.34 2.2977 2 -1 3 2 39.24 2.73 2.2957 2 1 2 2 39.34 26.26 2.2901 -2 0 4 2 39.46 2.52 2.2835 0 3 0 2 39.47 2.05 2.2832 0 -3 3 2 39.82 8.21 2.2638 0 0 7 2 40.04 7.12 2.2519 -2 1 3 2 40.08 5.91 2.2496 -2 -1 4 2 41.59 9.96 2.1713 2 0 4 2 41.99 10.31 2.1517 2 -1 4 2 42.02 13.12 2.1501 2 1 3 2 42.25 18.75 2.1390 2 -2 1 2 42.26 5.23 2.1385 1 -3 2 2 42.31 4.04 2.1360 -1 -3 1 2 42.33 20.01 2.1354 -2 -2 1 2 42.38 9.18 2.1327 -2 2 0 2 42.46 8.37 2.1290 -2 -2 2 2 42.58 12.81 2.1233 1 -2 6 2 42.60 12.09 2.1221 1 2 4 2 42.78 2.27 2.1136 -2 0 5 2 42.79 8.70 2.1133 -1 3 0 2 42.85 7.41 2.1105 -1 -3 3 2 42.85 2.73 2.1103 0 2 5 2 42.87 2.01 2.1096 0 -2 7 2 42.92 2.01 2.1070 2 -2 2 2 43.04 11.96 2.1018 -2 1 4 2 43.08 11.65 2.0999 -2 -1 5 2 43.20 10.37 2.0944 1 -3 3 2 43.25 8.43 2.0921 1 3 0 2 43.31 9.31 2.0891 -2 2 1 2 43.39 11.11 2.0856 -2 -2 3 2 43.55 7.96 2.0781 0 3 2 2 43.56 9.04 2.0776 0 -3 5 2 44.23 5.18 2.0477 -1 3 1 2 44.29 3.46 2.0450 -1 -3 4 2 44.37 19.63 2.0417 2 -2 3 2 44.43 15.60 2.0388 2 2 1 2 44.79 2.35 2.0233 0 1 7 2 44.80 2.88 2.0229 0 -1 8 2 44.89 1.82 2.0192 1 -3 4 2 44.99 14.37 2.0148 -2 2 2 2 45.07 17.19 2.0115 -2 -2 4 2 45.40 2.21 1.9979 2 -1 5 2 45.40 7.16 1.9975 2 0 5 2 45.42 5.77 1.9970 -1 2 5 2 45.43 2.18 1.9966 2 1 4 2 45.47 5.49 1.9950 -1 -2 7 2 46.53 2.70 1.9519 2 -2 4 2 46.59 1.71 1.9494 2 2 2 2 46.61 6.53 1.9485 0 3 3 2 46.63 7.10 1.9479 0 -3 6 2 46.95 1.82 1.9354 1 -2 7 2 46.97 1.76 1.9346 1 2 5 2 47.28 3.48 1.9227 1 -3 5 2 47.32 4.35 1.9212 1 3 2 2 47.81 4.61 1.9024 0 2 6 2 47.83 3.76 1.9018 0 -2 8 2 49.19 2.38 1.8521 -1 3 3 2 49.26 3.02 1.8499 -1 -3 6 2 49.33 4.18 1.8473 2 -1 6 2 49.36 4.60 1.8464 2 1 5 2 50.06 1.30 1.8222 -1 2 6 2 50.10 1.00 1.8206 -1 -2 8 2 50.24 3.21 1.8161 0 3 4 2 50.25 3.48 1.8155 0 -3 7 2 50.28 1.24 1.8145 1 -3 6 2 50.32 1.73 1.8133 1 3 3 2 50.66 2.44 1.8019 0 1 8 2 50.67 2.26 1.8016 0 -1 9 2 50.72 6.16 1.8001 -2 1 6 2 50.75 5.47 1.7988 -2 -1 7 2 51.19 7.80 1.7844 -2 0 7 2 51.68 3.25 1.7688 2 -3 1 2 51.72 1.89 1.7675 1 -2 8 2 51.74 2.10 1.7670 1 2 6 2 51.77 3.17 1.7658 -2 -3 2 2 51.93 1.83 1.7607 0 0 9 2 52.15 48.57 1.7540 0 -4 2 2 52.65 3.08 1.7383 -1 1 8 2 52.68 3.79 1.7376 -1 -1 9 2 52.81 2.13 1.7336 -3 1 1 2 52.83 1.06 1.7330 2 -3 3 2 52.86 1.97 1.7321 -3 -1 2 2 52.86 1.33 1.7320 3 1 0 2 52.88 1.10 1.7315 -3 0 3 2 52.92 1.55 1.7303 2 3 0 2 53.72 2.20 1.7062 2 -1 7 2 53.75 3.04 1.7055 2 1 6 2 53.82 4.56 1.7034 -3 1 2 2 53.83 4.77 1.7030 3 -1 2 2 53.87 4.51 1.7020 -3 -1 3 2 53.88 5.66 1.7017 3 1 1 2 54.35 6.24 1.6879 0 3 5 2 54.37 6.57 1.6874 0 -3 8 2 54.40 1.13 1.6866 2 0 7 2 54.59 5.53 1.6812 1 -1 9 2 54.59 6.03 1.6810 1 1 8 2 55.17 2.39 1.6648 0 4 1 2 55.18 2.25 1.6645 0 -4 5 2 55.24 1.88 1.6628 -2 1 7 2 55.28 1.75 1.6617 -2 -1 8 2 55.85 1.03 1.6461 1 0 9 2 56.02 4.10 1.6415 -2 0 8 2 56.59 1.74 1.6263 2 -2 7 2 56.60 2.42 1.6261 2 -3 5 2 56.64 1.25 1.6251 2 2 5 2 56.68 2.49 1.6240 2 3 2 2 56.84 9.62 1.6197 1 -2 9 2 56.86 9.09 1.6193 1 2 7 2 57.44 4.56 1.6044 -2 3 3 2 57.50 1.49 1.6028 -3 0 5 2 57.52 2.85 1.6022 3 0 4 2 57.54 3.58 1.6018 -2 -3 6 2 57.59 7.08 1.6004 -3 2 0 2 57.60 6.73 1.6003 3 -2 1 2 57.63 1.09 1.5995 -1 4 1 2 57.68 6.14 1.5981 -3 -2 2 2 57.69 7.69 1.5981 -3 -2 1 2 57.70 1.37 1.5978 -1 -4 5 2 57.75 4.44 1.5965 -3 1 4 2 57.77 2.85 1.5958 3 -1 4 2 57.80 3.79 1.5953 -3 -1 5 2 57.82 2.84 1.5948 3 1 3 2 57.95 2.85 1.5914 -2 2 6 2 58.02 3.06 1.5896 -2 -2 8 2 58.23 2.18 1.5844 -3 2 1 2 58.24 3.42 1.5841 3 -2 2 2 58.28 1.00 1.5831 1 -4 5 2 58.32 2.42 1.5821 -3 -2 3 2 58.33 2.79 1.5820 3 2 0 2 58.33 1.27 1.5819 1 4 1 2 58.46 2.47 1.5786 -1 1 9 2 58.49 2.75 1.5781 -1 -1 10 2 59.38 3.24 1.5565 2 -3 6 2 59.45 3.23 1.5548 2 3 3 2 59.47 2.35 1.5542 2 0 8 2 59.49 1.25 1.5537 -3 2 2 2 59.51 1.02 1.5533 3 -2 3 2 59.59 1.02 1.5516 -3 -2 4 2 60.39 1.03 1.5328 -2 3 4 2 60.41 8.99 1.5323 -1 2 8 2 60.46 8.18 1.5313 -1 -2 10 2 60.66 3.58 1.5267 -3 0 6 2 60.69 3.77 1.5260 3 0 5 2 60.93 2.99 1.5205 2 -2 8 2 60.97 2.33 1.5195 2 2 6 2 61.36 1.24 1.5108 -3 2 3 2 61.47 1.11 1.5085 3 2 2 2 62.42 2.97 1.4877 -1 4 3 2 62.43 1.40 1.4875 -2 2 7 2 62.50 2.99 1.4861 -1 -4 7 2 62.50 1.58 1.4860 -2 -2 9 2 62.69 2.14 1.4821 2 -3 7 2 62.76 2.49 1.4806 2 3 4 2 63.20 4.83 1.4712 2 -4 2 2 63.30 6.91 1.4692 2 -4 1 2 63.31 5.51 1.4689 -2 -4 2 2 63.41 7.06 1.4668 -2 -4 3 2 63.47 3.07 1.4657 1 -4 7 2 63.50 3.13 1.4649 1 4 3 2 63.68 4.00 1.4613 0 4 4 2 63.68 1.28 1.4612 2 -1 9 2 63.70 4.18 1.4609 0 -4 8 2 63.80 2.20 1.4588 -3 2 4 2 63.83 2.42 1.4582 3 -2 5 2 63.86 3.71 1.4576 -2 3 5 2 63.89 2.55 1.4569 -3 -2 6 2 63.91 1.94 1.4566 3 2 3 2 63.96 3.83 1.4555 -2 -3 8 2 64.00 6.38 1.4548 -2 4 0 2 64.12 6.17 1.4524 -2 -4 4 2 64.53 1.49 1.4440 -1 1 10 2 64.56 1.28 1.4436 -1 -1 11 2 64.71 3.28 1.4406 0 0 11 2 64.82 3.13 1.4384 2 -4 4 2 64.92 3.06 1.4364 2 4 0 2 65.64 1.19 1.4224 -1 4 4 2 65.67 1.44 1.4218 -3 3 0 2 65.68 1.35 1.4216 3 -3 2 2 65.71 1.29 1.4209 -1 -4 8 2 65.80 1.30 1.4193 -3 -3 3 2 65.80 1.55 1.4193 -3 -3 1 2 66.08 2.32 1.4139 -1 2 9 2 66.13 2.47 1.4131 -1 -2 11 2 66.49 3.12 1.4062 2 -3 8 2 66.56 1.04 1.4050 -3 3 1 2 66.56 3.33 1.4050 2 3 5 2 66.57 1.43 1.4047 3 -3 3 2 66.65 1.88 1.4033 1 -1 11 2 66.65 1.84 1.4032 1 1 10 2 66.68 1.09 1.4026 -3 -3 4 2 66.69 1.41 1.4025 3 3 0 2 66.74 1.80 1.4015 -2 0 10 2 67.17 2.15 1.3936 -2 4 2 2 67.27 1.91 1.3918 1 -3 10 2 67.29 1.95 1.3915 1 3 7 2 67.29 2.32 1.3914 -2 -4 6 2 67.32 1.42 1.3909 -2 2 8 2 67.39 1.21 1.3896 -2 -2 10 2 67.82 1.43 1.3818 -2 3 6 2 67.92 1.26 1.3800 -2 -3 9 2 68.76 1.37 1.3652 2 -4 6 2 68.85 1.43 1.3636 2 4 2 2 69.69 6.84 1.3492 -4 0 1 2 69.79 5.22 1.3475 4 0 0 2 69.95 1.82 1.3449 1 -5 4 2 70.01 1.65 1.3439 -1 -5 1 2 70.05 1.00 1.3432 -3 3 3 2 70.19 1.01 1.3408 3 3 2 2 70.47 6.07 1.3363 4 0 1 2 70.66 8.86 1.3331 2 0 10 2 70.71 1.67 1.3324 -1 5 0 2 70.72 1.55 1.3321 -1 3 8 2 70.78 1.51 1.3311 -1 -5 5 2 70.78 1.68 1.3311 -1 -3 11 2 70.85 1.09 1.3300 2 -2 10 2 70.89 1.20 1.3294 2 2 8 2 71.22 2.59 1.3240 -4 0 3 2 71.44 2.97 1.3205 0 0 12 2 72.63 2.29 1.3018 -2 0 11 2 73.01 2.16 1.2960 1 -5 6 2 73.06 2.21 1.2952 1 5 1 2 74.49 1.34 1.2738 -1 5 2 2 74.57 1.23 1.2726 -1 -5 7 2 75.44 1.62 1.2600 -4 2 0 2 75.55 1.62 1.2586 -4 -2 2 2 76.03 1.06 1.2518 4 -1 4 2 76.03 2.74 1.2517 -2 4 5 2 76.08 1.00 1.2511 4 1 3 2 76.16 2.86 1.2500 -2 -4 9 2 76.92 1.13 1.2394 -4 2 2 2 76.93 1.46 1.2394 -3 1 9 2 76.97 1.39 1.2388 -3 -1 10 2 76.98 1.22 1.2387 3 -1 9 2 77.01 1.28 1.2383 3 1 8 2 77.03 1.19 1.2380 -4 -2 4 2 77.41 1.77 1.2329 4 -2 3 2 77.51 1.74 1.2316 4 2 1 2 78.27 1.13 1.2214 1 -3 12 2 78.28 1.11 1.2213 1 3 9 2 78.67 1.95 1.2163 0 5 4 2 78.69 1.94 1.2160 0 -5 9 2 80.53 1.09 1.1928 2 -5 6 2 80.64 1.09 1.1914 2 5 1 2 81.75 1.08 1.1780 4 -1 6 2 81.80 1.21 1.1775 4 1 5 2 82.14 3.39 1.1735 4 0 6 2 82.49 2.58 1.1693 0 -6 3 2 83.05 1.01 1.1628 2 4 6 2 83.50 1.20 1.1578 0 1 13 2 83.51 1.17 1.1577 0 -1 14 2 83.58 1.10 1.1569 0 -6 1 2 83.59 1.08 1.1567 0 -6 5 2 83.96 1.20 1.1525 -3 4 4 2 84.05 1.57 1.1515 0 2 12 2 84.07 1.63 1.1513 0 -2 14 2 84.07 1.52 1.1513 -4 1 7 2 84.13 1.55 1.1507 -4 -1 8 2 84.13 1.19 1.1506 -3 -4 8 2 84.64 1.01 1.1450 -4 0 8 2 85.54 2.37 1.1353 -2 0 13 2 86.09 2.24 1.1295 1 -6 5 2 86.15 2.31 1.1288 -1 -6 1 2 86.98 1.47 1.1202 -1 6 0 2 87.07 1.43 1.1193 -1 -6 6 2 87.19 1.19 1.1180 4 -3 5 2 87.33 1.24 1.1166 4 3 2 2 87.60 1.60 1.1138 1 -2 14 2 87.60 1.58 1.1138 1 2 12 2 87.64 1.59 1.1134 0 4 9 2 87.67 1.61 1.1131 0 -4 13 2 88.89 1.09 1.1009 -4 0 9 2 89.32 1.18 1.0968 3 -5 4 2 89.50 1.25 1.0950 -3 -5 1 2 89.99 1.20 1.0903 1 -5 11 2 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.