data_global
_chemical_name_mineral 'Kenoargentotetrahedrite-(Fe)'
loop_
_publ_author_name
'Shu Z'
'Shen C'
'Lu A'
'Gu X'
_journal_name_full 'Crystals'
_journal_volume 12 
_journal_year 2022
_journal_page_first 
_journal_page_last 467
_publ_section_title
;
 Chemical composition and crystal structure of kenoargentotetrahedrite-(Fe),
 Ag6Cu4Fe2Sb4S12, from the Bajiazi Pb-Zn deposit, Liaoning, China
;
_database_code_amcsd 0021071
_chemical_compound_source 'Bajiazi Pb-Zn deposit, Liaoning, China'
_chemical_formula_sum 'Cu4.26 Fe1.74 Zn.3 Ag5.7 Sb4 S12.05'
_cell_length_a 10.4928
_cell_length_b 10.4928
_cell_length_c 10.4928
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 1155.245
_exptl_crystal_density_diffrn      5.392
_symmetry_space_group_name_H-M 'I -4 3 m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,1/2+z'
  '-z,x,-y'
  '1/2-z,1/2+x,1/2-y'
  '-y,z,-x'
  '1/2-y,1/2+z,1/2-x'
  '-x,y,-z'
  '1/2-x,1/2+y,1/2-z'
  'x,-z,-y'
  '1/2+x,1/2-z,1/2-y'
  'z,-y,-x'
  '1/2+z,1/2-y,1/2-x'
  'y,-x,-z'
  '1/2+y,1/2-x,1/2-z'
  'x,z,y'
  '1/2+x,1/2+z,1/2+y'
  'z,y,x'
  '1/2+z,1/2+y,1/2+x'
  'y,x,z'
  '1/2+y,1/2+x,1/2+z'
  '-z,-x,y'
  '1/2-z,1/2-x,1/2+y'
  '-y,-z,x'
  '1/2-y,1/2-z,1/2+x'
  '-x,-y,z'
  '1/2-x,1/2-y,1/2+z'
  'z,-x,-y'
  '1/2+z,1/2-x,1/2-y'
  'y,-z,-x'
  '1/2+y,1/2-z,1/2-x'
  'x,-y,-z'
  '1/2+x,1/2-y,1/2-z'
  '-x,z,-y'
  '1/2-x,1/2+z,1/2-y'
  '-z,y,-x'
  '1/2-z,1/2+y,1/2-x'
  '-y,x,-z'
  '1/2-y,1/2+x,1/2-z'
  '-x,-z,y'
  '1/2-x,1/2-z,1/2+y'
  '-z,-y,x'
  '1/2-z,1/2-y,1/2+x'
  '-y,-x,z'
  '1/2-y,1/2-x,1/2+z'
  'z,x,y'
  '1/2+z,1/2+x,1/2+y'
  'y,z,x'
  '1/2+y,1/2+z,1/2+x'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
CuM1   0.50000   0.00000   0.75000   0.66000   0.01960
FeM1   0.50000   0.00000   0.75000   0.29000   0.01960
ZnM1   0.50000   0.00000   0.75000   0.05000   0.01960
AgM2   0.50000   0.69055   0.50000   0.95000   0.02780
CuM2   0.50000   0.69055   0.50000   0.05000   0.02780
SbX3   0.77036   0.77036   0.77036   1.00000   0.01612
S1   0.62044   0.86480   0.62044   1.00000   0.01460
S2   0.50000   0.50000   0.50000   0.05000   0.03000
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
CuM1 0.01810 0.01810 0.02250 0.00000 0.00000 0.00000
FeM1 0.01810 0.01810 0.02250 0.00000 0.00000 0.00000
ZnM1 0.01810 0.01810 0.02250 0.00000 0.00000 0.00000
AgM2 0.03220 0.01850 0.03220 0.00000 -0.00920 0.00000
CuM2 0.03220 0.01850 0.03220 0.00000 -0.00920 0.00000
SbX3 0.01612 0.01612 0.01612 -0.00204 -0.00204 -0.00204
S1 0.01530 0.01310 0.01530 0.00000 0.00000 0.00000
S2 0.03000 0.03000 0.03000 0.00000 0.00000 0.00000