Fe4 H3 O15 P3 Malaman M, Ijjaali M, Venturini G, Gleitzer C, Soubeyroux J European Journal of Solid State and Inorganic Chemistry 28 (1991) 519-531 Neutron diffraction study of Fe4(PO4)3(OH)3: occurrence of ferromagnetic Fe2O9 clusters _cod_database_code 1008553 _database_code_amcsd 0016444 CELL PARAMETERS: 19.5800 7.3880 7.4510 90.000 102.320 90.000 SPACE GROUP: C2/c X-RAY WAVELENGTH: 1.541838 Cell Volume: 1053.018 Density (g/cm3): 3.528 MAX. ABS. INTENSITY / VOLUME**2: 14.61871342 RIR: 1.349 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 12.85 25.03 6.8918 1 1 0 4 17.02 18.94 5.2086 -1 1 1 4 18.38 11.76 4.8271 3 1 0 4 18.40 8.65 4.8230 1 1 1 4 18.55 18.39 4.7823 4 0 0 2 20.37 8.24 4.3605 -3 1 1 4 23.70 20.77 3.7534 3 1 1 4 24.46 9.14 3.6397 0 0 2 2 25.86 26.83 3.4459 2 2 0 4 26.23 13.44 3.3973 5 1 0 4 26.77 100.00 3.3298 -5 1 1 4 26.81 93.83 3.3258 -1 1 2 4 27.07 2.62 3.2941 0 2 1 4 27.45 9.74 3.2497 -4 0 2 2 27.78 39.08 3.2115 -2 2 1 4 27.99 19.27 3.1882 6 0 0 2 28.03 20.61 3.1834 2 0 2 2 28.60 15.91 3.1209 1 1 2 4 31.09 2.27 2.8767 5 1 1 4 31.45 2.68 2.8442 -4 2 1 4 32.47 3.01 2.7578 -5 1 2 4 33.13 2.40 2.7038 3 1 2 4 33.99 11.35 2.6377 4 0 2 2 34.44 20.49 2.6043 -2 2 2 4 34.52 21.09 2.5982 4 2 1 4 34.70 7.70 2.5850 -7 1 1 4 35.01 2.66 2.5630 7 1 0 4 36.80 7.00 2.4425 1 3 0 4 37.25 5.60 2.4136 6 2 0 4 37.29 4.01 2.4115 2 2 2 4 37.62 7.28 2.3911 8 0 0 2 38.37 4.84 2.3459 -1 1 3 4 38.56 2.24 2.3349 -1 3 1 4 38.71 2.19 2.3261 -7 1 2 4 38.75 2.18 2.3238 -3 1 3 4 39.22 6.58 2.2973 3 3 0 4 39.22 7.05 2.2968 1 3 1 4 39.54 5.19 2.2789 7 1 1 4 39.57 8.24 2.2776 5 1 2 4 40.34 1.49 2.2356 1 1 3 4 40.48 1.57 2.2285 -8 0 2 2 41.41 9.45 2.1802 -6 2 2 4 44.06 11.43 2.0552 -5 3 1 4 44.08 8.58 2.0542 -1 3 2 4 44.35 10.43 2.0426 9 1 0 4 44.41 9.29 2.0398 3 1 3 4 44.63 5.18 2.0305 -8 2 1 4 44.68 6.72 2.0281 0 2 3 4 45.02 1.71 2.0138 -3 3 2 4 46.29 1.20 1.9612 -9 1 2 4 47.29 2.17 1.9223 7 1 2 4 47.97 5.83 1.8964 -5 3 2 4 48.71 2.37 1.8695 9 1 1 4 48.73 3.96 1.8688 -6 2 3 4 48.83 2.79 1.8651 -10 0 2 2 48.91 1.49 1.8622 -2 0 4 2 49.34 8.09 1.8470 0 4 0 2 49.90 8.33 1.8275 8 0 2 2 50.13 5.19 1.8199 0 0 4 2 50.17 2.72 1.8183 5 1 3 4 50.67 3.88 1.8016 -3 1 4 4 52.02 1.17 1.7578 4 2 3 4 52.30 3.01 1.7493 -9 1 3 4 52.34 4.24 1.7480 -5 1 4 4 52.49 1.86 1.7432 2 4 1 4 53.16 1.91 1.7230 4 4 0 4 53.37 1.39 1.7167 5 3 2 4 54.18 1.16 1.6927 11 1 0 4 54.86 1.03 1.6735 -11 1 2 4 54.86 1.32 1.6735 -5 3 3 4 55.17 21.00 1.6649 -10 2 2 4 55.24 16.68 1.6629 -2 2 4 4 56.65 3.68 1.6248 -8 0 4 2 56.88 1.17 1.6187 3 1 4 4 57.26 10.50 1.6090 9 3 0 4 57.31 8.40 1.6077 3 3 3 4 57.38 20.50 1.6058 -4 4 2 4 57.68 1.66 1.5982 6 4 0 4 57.70 3.49 1.5976 2 4 2 4 57.72 2.45 1.5972 -6 4 1 4 57.84 9.56 1.5941 12 0 0 2 57.94 11.87 1.5917 4 0 4 2 58.00 2.21 1.5902 -12 0 2 2 58.05 2.10 1.5889 10 2 1 4 58.10 3.01 1.5878 6 2 3 4 58.37 3.60 1.5810 -6 2 4 4 59.73 1.31 1.5482 7 3 2 4 59.77 1.81 1.5473 -11 1 3 4 60.64 1.18 1.5272 6 4 1 4 60.94 1.06 1.5202 9 3 1 4 61.27 3.44 1.5130 4 4 2 4 62.21 1.19 1.4923 5 3 3 4 62.71 1.47 1.4816 -2 4 3 4 62.99 1.21 1.4757 -13 1 1 4 63.66 1.98 1.4617 8 4 0 4 64.06 3.35 1.4535 -9 3 3 4 64.10 4.51 1.4527 -5 3 4 4 64.26 3.79 1.4495 -13 1 2 4 64.38 3.99 1.4471 -1 1 5 4 64.76 1.74 1.4395 3 5 0 4 64.82 5.75 1.4384 10 2 2 4 65.46 1.31 1.4258 11 1 2 4 65.49 1.33 1.4253 9 1 3 4 65.73 1.66 1.4205 11 3 0 4 68.01 1.99 1.3784 -12 2 3 4 68.01 1.79 1.3784 5 5 0 4 68.10 1.78 1.3769 -4 2 5 4 68.15 1.61 1.3759 3 3 4 4 68.29 1.56 1.3735 -1 5 2 4 68.93 1.19 1.3622 13 1 1 4 69.01 1.13 1.3608 7 1 4 4 69.19 2.25 1.3579 1 5 2 4 69.54 3.31 1.3519 6 2 4 4 71.65 1.53 1.3171 3 5 2 4 71.75 1.42 1.3155 -9 3 4 4 71.95 1.59 1.3124 -10 4 2 4 72.01 1.50 1.3114 -2 4 4 4 72.25 1.89 1.3076 -14 2 1 4 72.38 1.34 1.3056 2 2 5 4 72.57 1.27 1.3026 -7 5 1 4 72.80 14.42 1.2991 8 4 2 4 72.98 1.59 1.2963 0 4 4 4 73.97 2.30 1.2815 14 2 0 4 77.74 1.30 1.2284 -11 3 4 4 77.79 1.21 1.2278 -7 3 5 4 77.91 1.21 1.2262 -10 2 5 4 77.91 1.82 1.2261 -15 1 3 4 78.90 1.40 1.2132 9 5 0 4 78.95 1.35 1.2126 3 5 3 4 79.32 1.79 1.2079 13 3 1 4 79.40 1.23 1.2069 7 3 4 4 80.20 1.09 1.1969 15 1 1 4 83.03 4.73 1.1631 -14 2 4 4 83.13 5.07 1.1619 -6 2 6 4 84.90 1.06 1.1422 -9 5 3 4 84.93 1.43 1.1418 -5 5 4 4 85.47 1.16 1.1360 -17 1 1 4 85.65 1.67 1.1341 3 1 6 4 87.21 1.78 1.1178 2 2 6 4 89.15 1.19 1.0984 -8 6 1 4 89.97 1.17 1.0906 16 2 1 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.