data_global _amcsd_formula_title 'Fe4V2Mo3O20' loop_ _publ_author_name 'Laligant Y' 'Permer L' 'Le Bail A' _journal_name_full 'European Journal of Solid State and Inorganic Chemistry' _journal_volume 32 _journal_year 1995 _journal_page_first 325 _journal_page_last 334 _publ_section_title ; Crystal structure of Fe4V2Mo3O20 determined from conventional X-ray powder diffraction data _cod_database_code 1000123 ; _database_code_amcsd 0012595 _chemical_formula_sum '(Mo3.02 V1.98) Fe4 O20' _cell_length_a 9.5390 _cell_length_b 9.5390 _cell_length_c 17.1411 _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_volume 1559.712 _exptl_crystal_density_diffrn 3.977 _symmetry_space_group_name_H-M 'P 41 2 2' loop_ _space_group_symop_operation_xyz 'x,y,z' 'y,x,3/4-z' '-y,x,1/4+z' '-x,y,-z' '-x,-y,1/2+z' '-y,-x,1/4-z' 'y,-x,3/4+z' 'x,-y,1/2-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy Mo1 0.40100 0.26270 0.09410 0.86000 V1 0.40100 0.26270 0.09410 0.14000 Mo2 0.00000 0.83860 0.00000 0.86000 V2 0.00000 0.83860 0.00000 0.14000 Mo3 0.50000 0.83270 0.00000 0.22000 V3 0.50000 0.83270 0.00000 0.78000 Mo4 0.00000 0.33420 0.00000 0.22000 V4 0.00000 0.33420 0.00000 0.78000 Fe1 0.24850 0.59180 0.06010 1.00000 Fe2 0.74620 0.09300 0.06120 1.00000 O1 0.28200 0.15200 0.05340 1.00000 O2 0.57500 0.22200 0.07450 1.00000 O3 0.38900 0.44300 0.06400 1.00000 O4 0.40500 0.24800 0.42680 1.00000 O5 0.90600 0.74500 0.42550 1.00000 O6 0.04100 0.11000 0.19690 1.00000 O7 0.11100 0.57100 0.45350 1.00000 O8 0.24400 0.64000 0.94430 1.00000 O9 0.61700 0.05900 0.45420 1.00000 O10 0.27200 0.91300 0.18610 1.00000