data_global _amcsd_formula_title 'Co2 H40 N2 O44 V10' loop_ _publ_author_name 'Baudrin E' 'Denis S' 'Touboul M' 'Nowogorocki G' _journal_name_full 'European Journal of Solid State and Inorganic Chemistry' _journal_volume 34 _journal_year 1997 _journal_page_first 1011 _journal_page_last 1026 _publ_section_title ; Synthesis, crystal structure and thermal properties of (NH4)2Co2V10O28*16(H2O) _cod_database_code 1004121 ; _database_code_amcsd 0012612 _chemical_formula_sum 'Co V5 O22 N H20' _cell_length_a 8.836 _cell_length_b 10.865 _cell_length_c 11.052 _cell_angle_alpha 65.18 _cell_angle_beta 74.12 _cell_angle_gamma 71.57 _cell_volume 901.311 _exptl_crystal_density_diffrn 2.579 _symmetry_space_group_name_H-M 'P -1' loop_ _space_group_symop_operation_xyz 'x,y,z' '-x,-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z Co1 0.78544 0.73294 0.78312 V1 0.68819 0.73931 0.23876 V2 0.64697 0.45281 0.27020 V3 0.67377 0.50859 0.51952 V4 0.63306 0.27993 0.80066 V5 0.61703 0.22527 0.55014 O1 0.56010 0.84040 0.34340 O2 0.51390 0.59870 0.37790 O3 0.51990 0.64330 0.59110 O4 0.54050 0.80180 0.12580 O5 0.82230 0.82680 0.15180 O6 0.77550 0.57520 0.19690 O7 0.79180 0.61580 0.40930 O8 0.74370 0.33730 0.20460 O9 0.74060 0.37050 0.44000 O10 0.76480 0.41360 0.65790 O11 0.50720 0.44050 0.83800 O12 0.72040 0.17230 0.69250 O13 0.74260 0.20470 0.91650 O14 0.71060 0.11170 0.48150 O15 0.66140 0.81640 0.62070 O16 0.94910 0.85620 0.66680 O17 0.91500 0.56780 0.72220 O18 0.64370 0.89400 0.85280 O19 0.60080 0.62940 0.89320 O20 0.91950 0.65710 0.93700 O21 0.93490 0.83920 0.40290 O22 0.99170 0.94320 0.87600 N1 0.67260 0.08780 0.23110 H1 0.78600 0.06500 0.19100 H2 0.62700 0.15200 0.18300 H3 0.62900 0.02800 0.26500 H4 0.68600 0.10500 0.28900 H5 0.61600 0.77400 0.60700 H6 0.72100 0.84400 0.55100 H7 0.03300 0.85900 0.66500 H8 0.95400 0.87900 0.60700 H9 0.99700 0.54300 0.72000 H10 0.87100 0.52400 0.69300 H11 0.66400 0.95300 0.82200 H12 0.60100 0.87600 0.93500 H13 0.56900 0.60500 0.96900 H14 0.57600 0.57700 0.87300 H15 0.87100 0.63300 0.01400 H16 0.99800 0.65700 0.91800 H17 0.02000 0.85000 0.37200 H18 0.92100 0.79100 0.40300 H19 0.92400 0.97900 0.92300 H20 0.98200 0.89300 0.93500