Sr2Ga(HPO4)(PO4)F2 Le Meins J, Hemon-Ribaud A, Courbion G European Journal of Solid State and Inorganic Chemistry 35 (1998) 117-132 Synthesis and crystal structure of two fluorophosphated compounds with different infinite sheets: Sr2Ga(HPO4)(PO4)F2 and Sr2Fe2(HPO4)(PO4)2F2 _cod_database_code 1000486 _database_code_amcsd 0012619 CELL PARAMETERS: 8.2570 7.2050 13.5960 90.000 108.020 90.000 SPACE GROUP: P2_1/n X-RAY WAVELENGTH: 1.541838 Cell Volume: 769.174 Density (g/cm3): 4.083 MAX. ABS. INTENSITY / VOLUME**2: 14.34787205 RIR: 1.144 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 13.70 4.00 6.4645 0 0 2 2 14.07 4.40 6.2937 0 1 1 4 14.90 2.61 5.9448 1 0 1 2 16.70 59.50 5.3087 1 1 0 4 18.44 10.74 4.8117 0 1 2 4 19.29 8.73 4.6017 -1 1 2 4 19.36 1.03 4.5854 1 1 1 4 20.21 13.24 4.3947 -1 0 3 2 22.57 5.10 3.9396 -2 0 2 2 22.65 3.51 3.9260 2 0 0 2 23.71 2.19 3.7519 -1 1 3 4 23.81 12.41 3.7372 1 1 2 4 24.06 2.04 3.6985 0 1 3 4 24.71 2.24 3.6025 0 2 0 2 24.86 2.78 3.5821 -2 1 1 4 25.77 75.71 3.4566 -2 1 2 4 25.84 1.45 3.4474 2 1 0 4 26.49 2.35 3.3644 1 0 3 2 27.22 14.11 3.2763 -1 2 1 4 27.24 100.00 3.2743 1 2 0 4 27.60 3.57 3.2323 0 0 4 2 28.36 37.36 3.1469 0 2 2 4 28.42 14.05 3.1401 -2 1 3 4 28.55 13.70 3.1263 2 1 1 4 28.98 2.57 3.0809 1 2 1 4 29.19 65.88 3.0596 -1 1 4 4 29.30 6.11 3.0485 1 1 3 4 29.88 6.40 2.9902 -2 0 4 2 30.06 97.41 2.9724 2 0 2 2 30.31 49.75 2.9491 0 1 4 4 32.13 7.33 2.7861 -1 2 3 4 32.20 44.24 2.7800 1 2 2 4 32.39 1.11 2.7640 0 2 3 4 32.42 56.75 2.7618 -2 1 4 4 32.59 3.12 2.7477 2 1 2 4 32.95 13.81 2.7186 -1 0 5 2 33.00 3.83 2.7144 -2 2 1 4 33.71 11.92 2.6586 -2 2 2 4 33.77 22.82 2.6544 2 2 0 4 35.05 23.67 2.5599 -3 1 2 4 35.41 1.09 2.5353 1 1 4 4 35.93 1.04 2.4992 2 2 1 4 36.41 8.40 2.4676 -3 1 3 4 36.45 4.05 2.4647 -1 2 4 4 36.53 2.29 2.4600 3 1 0 4 36.54 16.77 2.4589 1 2 3 4 36.93 2.79 2.4338 0 1 5 4 37.09 2.75 2.4236 3 0 1 2 37.38 2.98 2.4058 0 2 4 4 39.15 1.81 2.3009 -2 2 4 4 39.30 3.36 2.2927 2 2 2 4 39.94 1.47 2.2573 1 0 5 2 40.47 42.91 2.2287 -1 3 2 4 40.51 1.12 2.2268 1 3 1 4 40.77 5.43 2.2134 -3 0 5 2 41.08 6.53 2.1974 -2 0 6 2 41.31 1.64 2.1856 2 0 4 2 41.62 8.30 2.1700 -1 2 5 4 41.93 6.48 2.1548 0 0 6 2 41.94 9.59 2.1541 1 1 5 4 42.70 22.56 2.1175 3 2 0 4 42.97 1.16 2.1049 1 3 2 4 43.06 7.02 2.1007 0 2 5 4 43.12 6.16 2.0979 0 3 3 4 43.26 9.55 2.0915 2 1 4 4 43.45 3.64 2.0827 -2 2 5 4 43.85 14.37 2.0645 0 1 6 4 43.86 8.16 2.0642 -4 0 2 2 44.16 2.84 2.0507 -2 3 2 4 44.92 2.74 2.0178 -3 2 4 4 45.72 24.67 1.9844 -4 1 2 4 45.79 1.63 1.9816 3 0 3 2 45.87 1.16 1.9783 -2 3 3 4 46.08 1.84 1.9698 -4 0 4 2 46.25 6.27 1.9630 4 0 0 2 46.38 14.70 1.9577 -1 3 4 4 47.42 1.75 1.9172 -1 2 6 4 47.53 3.57 1.9128 1 2 5 4 48.04 17.09 1.8940 4 1 0 4 48.26 8.04 1.8859 -3 2 5 4 48.47 17.94 1.8780 3 2 2 4 48.53 2.72 1.8759 -2 2 6 4 48.69 1.08 1.8701 -1 1 7 4 48.73 3.33 1.8686 2 2 4 4 48.82 5.25 1.8653 1 1 6 4 49.23 5.99 1.8507 -2 1 7 4 49.28 2.18 1.8493 0 2 6 4 50.55 9.33 1.8057 -3 3 2 4 50.58 1.62 1.8047 -3 3 1 4 50.76 2.61 1.7986 4 1 1 4 50.81 18.05 1.7970 1 3 4 4 50.94 7.74 1.7928 -3 0 7 2 50.99 6.79 1.7910 -4 2 2 4 51.05 1.50 1.7892 0 1 7 4 51.65 10.36 1.7696 3 3 0 4 51.96 1.75 1.7597 0 3 5 4 52.09 5.85 1.7556 1 4 0 4 52.30 12.07 1.7491 -2 3 5 4 52.45 6.65 1.7445 -4 0 6 2 52.46 8.80 1.7442 -3 2 6 4 52.72 3.52 1.7363 3 2 3 4 52.76 5.72 1.7352 0 4 2 4 52.76 3.67 1.7350 4 0 2 2 52.98 5.12 1.7283 -4 2 4 4 53.10 2.15 1.7247 -1 4 2 4 53.13 1.61 1.7239 1 4 1 4 53.13 1.55 1.7237 4 2 0 4 53.59 16.89 1.7101 -3 3 4 4 53.74 7.24 1.7056 -1 2 7 4 53.87 2.27 1.7020 1 2 6 4 54.25 2.64 1.6909 -2 2 7 4 54.29 2.55 1.6898 -2 0 8 2 54.44 4.31 1.6855 1 0 7 2 54.55 2.34 1.6822 2 0 6 2 55.15 7.93 1.6654 1 4 2 4 55.45 2.92 1.6569 -4 2 5 4 55.80 3.54 1.6476 -1 3 6 4 55.89 3.20 1.6451 -2 1 8 4 55.90 2.33 1.6449 -1 1 8 4 55.94 2.53 1.6436 0 2 7 4 56.15 5.44 1.6382 2 1 6 4 56.15 2.52 1.6381 -2 4 2 4 56.18 6.57 1.6372 2 4 0 4 56.54 1.08 1.6276 -3 3 5 4 56.74 1.61 1.6226 3 3 2 4 56.98 3.83 1.6161 0 0 8 2 57.31 2.02 1.6076 3 0 5 2 57.71 2.29 1.5974 3 2 4 4 58.09 2.05 1.5880 1 4 3 4 58.25 1.87 1.5839 -5 1 4 4 58.38 2.40 1.5806 -5 1 1 4 58.46 1.36 1.5786 -4 1 7 4 58.58 3.83 1.5759 -5 0 5 2 58.82 1.88 1.5699 4 1 3 4 59.10 2.78 1.5632 4 2 2 4 59.44 2.19 1.5549 -4 3 3 4 59.51 2.00 1.5533 -4 3 1 4 59.95 1.09 1.5429 -2 4 4 4 60.32 4.74 1.5344 5 1 0 4 60.34 3.97 1.5339 -3 3 6 4 60.52 2.03 1.5298 -2 2 8 4 60.53 1.68 1.5297 -1 2 8 4 61.63 7.35 1.5050 1 3 6 4 61.66 1.31 1.5042 5 0 1 2 61.78 2.13 1.5016 -1 4 5 4 61.97 1.54 1.4975 -1 0 9 2 61.98 2.46 1.4973 -2 3 7 4 62.19 3.71 1.4928 2 3 5 4 62.49 3.53 1.4862 4 0 4 2 62.53 1.36 1.4855 -3 4 3 4 62.60 2.23 1.4838 3 4 0 4 62.77 1.22 1.4803 -5 2 4 4 62.84 1.75 1.4788 -5 1 6 4 62.88 1.36 1.4780 0 4 5 4 62.97 4.87 1.4760 -2 1 9 4 63.02 2.69 1.4750 -3 2 8 4 63.09 2.05 1.4735 -4 3 5 4 63.25 2.02 1.4703 2 1 7 4 63.35 3.42 1.4680 3 2 5 4 63.54 2.25 1.4641 0 3 7 4 63.96 1.51 1.4556 4 1 4 4 64.32 1.07 1.4483 -3 4 4 4 64.96 3.18 1.4355 -3 1 9 4 65.34 2.62 1.4281 3 1 6 4 65.90 2.26 1.4173 1 5 0 4 66.31 2.30 1.4097 -1 4 6 4 66.35 1.59 1.4088 0 1 9 4 66.40 1.04 1.4079 1 4 5 4 66.48 2.74 1.4065 0 5 2 4 66.98 4.82 1.3971 -3 4 5 4 67.16 2.70 1.3939 3 4 2 4 67.18 3.58 1.3934 -5 2 6 4 67.47 1.50 1.3881 5 2 1 4 67.82 1.12 1.3818 -1 3 8 4 67.91 1.10 1.3803 1 2 8 4 68.53 5.46 1.3693 -6 0 4 2 68.57 2.84 1.3686 1 5 2 4 69.10 2.18 1.3593 -2 0 10 2 69.15 6.77 1.3585 -5 3 2 4 69.24 2.27 1.3570 -3 2 9 4 69.45 2.25 1.3533 -2 5 2 4 69.60 1.27 1.3507 3 2 6 4 69.76 1.97 1.3481 4 1 5 4 69.94 1.34 1.3451 -5 3 4 4 70.46 1.31 1.3365 -3 4 6 4 70.46 1.14 1.3365 4 3 3 4 70.58 1.52 1.3344 0 2 9 4 70.64 3.04 1.3335 -5 2 7 4 70.67 2.22 1.3329 3 4 3 4 70.89 1.14 1.3293 -4 4 4 4 71.00 1.78 1.3275 5 2 2 4 71.13 2.12 1.3255 -1 5 4 4 71.37 1.31 1.3215 -6 1 1 4 71.54 2.21 1.3189 -1 4 7 4 71.71 2.24 1.3161 0 5 4 4 71.82 2.87 1.3144 5 3 0 4 72.16 1.10 1.3090 2 4 5 4 72.86 2.73 1.2981 -2 5 4 4 73.56 3.79 1.2876 6 1 0 4 74.17 1.67 1.2785 -6 2 2 4 74.32 1.85 1.2762 -4 0 10 2 74.39 3.75 1.2752 -3 5 2 4 74.57 2.81 1.2726 0 1 10 4 74.91 2.72 1.2676 2 2 8 4 74.96 3.23 1.2669 3 4 4 4 75.29 2.68 1.2622 -6 2 5 4 75.81 2.39 1.2548 -5 1 9 4 75.94 1.79 1.2531 2 5 3 4 76.18 2.55 1.2496 4 1 6 4 76.19 2.53 1.2496 4 4 2 4 76.47 2.65 1.2457 3 3 6 4 77.45 1.20 1.2323 -1 4 8 4 77.62 1.24 1.2300 6 2 0 4 78.62 1.29 1.2169 0 2 10 4 79.01 1.10 1.2118 6 0 2 2 79.65 1.14 1.2037 -4 4 7 4 79.69 1.01 1.2032 -3 4 8 4 79.70 1.58 1.2030 2 5 4 4 79.80 2.41 1.2019 -1 1 11 4 79.88 3.78 1.2008 0 6 0 2 79.96 1.02 1.1998 1 1 10 4 80.20 3.76 1.1969 -4 3 9 4 80.34 2.87 1.1951 5 2 4 4 80.35 1.10 1.1950 6 1 2 4 81.45 2.87 1.1816 -4 5 2 4 81.83 1.28 1.1770 -4 5 3 4 82.18 2.16 1.1729 -1 3 10 4 82.70 2.26 1.1668 -4 1 11 4 82.82 1.40 1.1655 2 2 9 4 83.16 2.04 1.1616 4 5 0 4 83.51 2.21 1.1576 -5 4 6 4 83.94 2.19 1.1528 1 2 10 4 84.18 1.05 1.1501 1 4 8 4 84.25 1.03 1.1494 2 5 5 4 84.31 1.33 1.1487 -2 6 2 4 84.36 3.63 1.1481 -6 1 9 4 86.16 1.28 1.1287 2 0 10 2 86.79 1.38 1.1221 -5 0 11 2 86.81 1.97 1.1219 -6 3 7 4 86.85 1.22 1.1215 3 0 9 2 86.97 1.43 1.1202 -7 -2 4 4 87.09 1.38 1.1190 5 4 2 4 87.17 1.81 1.1182 6 3 1 4 87.55 1.55 1.1143 -2 6 4 4 87.64 4.88 1.1134 2 6 2 4 88.98 1.01 1.1000 1 1 11 4 89.10 2.96 1.0990 -2 3 11 4 89.73 1.71 1.0928 4 0 8 2 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.