Sr2Fe2(HPO4)(PO4)2F2 Le Meins J, Hemon-Ribaud A, Courbion G European Journal of Solid State and Inorganic Chemistry 35 (1998) 117-132 Synthesis and crystal structure of two fluorophosphated compounds with different infinite sheets: Sr2Ga(HPO4)(PO4)F2 and Sr2Fe2(HPO4)(PO4)2F2 _cod_database_code 1000487 _database_code_amcsd 0012620 CELL PARAMETERS: 8.0720 8.7940 8.8850 102.460 115.950 89.950 SPACE GROUP: P-1 X-RAY WAVELENGTH: 1.541838 Cell Volume: 550.604 Density (g/cm3): 3.678 MAX. ABS. INTENSITY / VOLUME**2: 7.224369961 RIR: 0.640 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 11.41 19.43 7.7566 0 0 1 2 12.26 12.44 7.2168 1 0 0 2 12.46 6.13 7.1037 -1 0 1 2 15.21 3.98 5.8262 -1 1 0 2 16.91 51.85 5.2431 1 1 0 2 17.13 56.42 5.1771 -1 1 1 2 20.80 2.76 4.2698 1 -1 1 2 21.10 5.71 4.2114 -1 -1 2 2 21.22 25.73 4.1876 0 -2 1 2 22.03 6.49 4.0352 -2 0 1 2 23.04 54.46 3.8594 -1 -2 1 2 23.05 58.55 3.8589 -1 2 0 2 24.35 100.00 3.6560 -2 -1 1 2 24.45 89.71 3.6406 -2 1 1 2 24.58 12.54 3.6218 1 1 1 2 24.67 10.49 3.6084 2 0 0 2 24.93 13.21 3.5714 -1 1 2 2 25.07 5.99 3.5518 -2 0 2 2 25.35 16.51 3.5139 1 2 0 2 25.54 14.16 3.4871 -1 2 1 2 25.76 4.34 3.4585 -2 1 0 2 26.03 38.35 3.4237 1 -2 1 2 26.13 22.89 3.4108 0 2 1 2 26.21 36.88 3.3995 -1 -2 2 2 27.11 6.63 3.2894 0 -2 2 2 27.85 57.50 3.2036 2 1 0 2 28.30 58.67 3.1538 -2 1 2 2 30.11 78.47 2.9685 1 -1 2 2 30.40 37.08 2.9405 -2 -2 1 2 30.48 61.37 2.9329 -1 -1 3 2 30.57 19.97 2.9245 -2 2 1 2 30.67 53.47 2.9149 1 0 2 2 30.69 22.16 2.9131 -2 2 0 2 30.85 14.32 2.8984 -2 -2 2 2 31.08 44.77 2.8775 -1 0 3 2 31.69 4.49 2.8236 2 0 1 2 32.03 1.38 2.7942 1 2 1 2 32.32 5.64 2.7696 -2 0 3 2 32.35 1.47 2.7675 -1 2 2 2 32.52 56.34 2.7529 -1 -3 1 2 32.57 55.49 2.7494 -1 3 0 2 33.12 14.70 2.7045 1 -2 2 2 33.43 21.98 2.6807 -1 -2 3 2 33.70 2.47 2.6593 -3 0 1 2 33.92 4.97 2.6425 1 -3 1 2 33.93 5.99 2.6420 -3 0 2 2 34.03 3.05 2.6342 -1 -3 2 2 34.20 3.44 2.6216 2 2 0 2 34.65 3.95 2.5885 -2 2 2 2 34.66 2.57 2.5877 1 1 2 2 34.69 5.44 2.5855 0 0 3 2 34.78 52.93 2.5795 0 2 2 2 34.98 8.95 2.5651 -3 1 1 2 34.98 1.42 2.5649 2 -2 1 2 35.07 1.65 2.5588 -1 1 3 2 35.09 4.68 2.5575 -3 -1 2 2 35.14 4.86 2.5541 2 1 1 2 35.29 1.37 2.5432 -1 3 1 2 35.42 3.35 2.5346 -2 -2 3 2 35.72 2.07 2.5136 -3 -1 1 2 35.79 4.49 2.5089 -2 1 3 2 36.04 3.19 2.4918 0 -2 3 2 36.13 2.86 2.4862 0 3 1 2 37.76 23.88 2.3827 -3 1 0 2 38.00 3.76 2.3679 -3 0 3 2 38.13 2.35 2.3602 -2 3 0 2 38.26 35.77 2.3522 -3 -1 3 2 38.61 3.64 2.3318 -2 -3 1 2 38.82 3.06 2.3198 -2 3 1 2 39.22 1.46 2.2971 -1 -3 3 2 40.01 4.32 2.2536 3 1 0 2 40.30 9.04 2.2381 2 -1 2 2 40.60 2.11 2.2219 -3 -2 1 2 40.69 10.52 2.2173 -3 1 3 2 40.90 5.41 2.2067 1 -1 3 2 41.00 1.06 2.2016 -3 2 2 2 41.00 2.72 2.2011 -2 -1 4 2 41.01 1.28 2.2009 2 -3 1 2 41.08 5.41 2.1970 0 -4 1 2 41.10 4.05 2.1963 2 0 2 2 41.23 1.36 2.1895 2 2 1 2 41.31 4.70 2.1855 -1 -1 4 2 41.39 2.03 2.1813 -1 3 2 2 41.60 2.19 2.1712 -1 2 3 2 41.86 6.70 2.1582 -2 0 4 2 41.87 1.45 2.1576 -2 2 3 2 42.07 21.91 2.1477 1 0 3 2 42.50 28.95 2.1271 2 3 0 2 42.51 29.12 2.1266 -1 0 4 2 42.82 12.67 2.1119 -1 -4 1 2 42.88 5.57 2.1089 -1 4 0 2 42.90 1.06 2.1080 -1 -2 4 2 42.94 20.06 2.1064 -2 3 2 2 43.21 6.88 2.0938 0 -4 2 2 43.31 1.45 2.0891 -1 -4 2 2 43.75 3.18 2.0693 3 -1 1 2 44.13 3.97 2.0522 3 0 1 2 44.56 4.99 2.0335 -3 -1 4 2 44.61 1.03 2.0311 2 1 2 2 44.93 6.14 2.0176 -4 0 2 2 45.39 3.84 1.9983 -2 1 4 2 45.59 7.33 1.9900 1 4 0 2 45.76 13.90 1.9826 -1 4 1 2 45.77 1.57 1.9825 -3 -3 2 2 45.86 5.99 1.9786 -3 3 1 2 46.02 1.68 1.9722 3 -2 1 2 46.17 1.32 1.9660 -4 -1 2 2 46.28 11.57 1.9619 -4 0 1 2 46.29 4.54 1.9611 -4 1 2 2 46.71 1.46 1.9446 -3 -2 4 2 46.74 11.03 1.9435 -4 0 3 2 46.74 2.86 1.9434 1 -3 3 2 46.77 7.78 1.9424 0 4 1 2 46.78 7.52 1.9421 -3 3 0 2 46.81 1.64 1.9408 1 -4 2 2 46.85 4.21 1.9392 0 0 4 2 46.91 15.08 1.9367 2 -3 2 2 46.94 3.20 1.9356 -4 1 1 2 46.98 1.55 1.9342 -1 -4 3 2 47.03 5.89 1.9323 -3 -3 3 2 47.06 1.98 1.9311 -1 -3 4 2 47.09 2.17 1.9297 -2 -4 2 2 47.10 3.22 1.9294 -2 4 0 2 47.11 12.54 1.9289 3 1 1 2 47.28 5.22 1.9224 -4 -1 3 2 47.42 11.47 1.9170 -2 -3 4 2 47.63 6.90 1.9094 -3 -3 1 2 48.06 4.56 1.8933 -3 1 4 2 48.06 10.54 1.8932 -3 3 2 2 48.12 1.97 1.8911 -2 -4 1 2 48.16 1.61 1.8894 -4 -1 1 2 48.35 2.11 1.8825 -2 4 1 2 48.36 32.28 1.8822 0 -4 3 2 48.73 3.17 1.8688 -4 1 3 2 48.91 6.54 1.8624 2 -4 1 2 49.12 2.86 1.8547 -2 -4 3 2 49.18 11.02 1.8527 2 3 1 2 49.50 3.99 1.8414 1 3 2 2 49.79 11.29 1.8313 -2 3 3 2 49.86 1.12 1.8289 -1 3 3 2 49.89 7.35 1.8280 -4 -2 2 2 50.09 2.80 1.8213 -4 2 1 2 50.11 2.12 1.8203 -4 2 2 2 50.30 1.77 1.8141 -4 -2 3 2 50.67 20.87 1.8017 3 -3 1 2 51.15 2.20 1.7857 -2 2 4 2 51.19 3.64 1.7844 1 4 1 2 51.23 23.59 1.7833 -3 -3 4 2 51.33 3.80 1.7798 -4 -1 4 2 51.47 3.85 1.7756 -1 4 2 2 51.71 10.15 1.7676 2 -2 3 2 51.88 1.58 1.7623 1 2 3 2 51.92 3.23 1.7611 2 0 3 2 52.05 4.74 1.7570 2 4 0 2 52.31 1.78 1.7489 -1 2 4 2 52.39 13.90 1.7464 -4 -2 1 2 52.46 10.72 1.7444 -2 -2 5 2 52.48 4.16 1.7435 -2 4 2 2 52.61 1.84 1.7395 1 -1 4 2 52.77 1.80 1.7348 -2 0 5 2 52.95 1.41 1.7293 -4 2 0 2 52.98 1.40 1.7284 4 1 0 2 53.03 3.97 1.7269 3 0 2 2 53.03 15.48 1.7268 -4 2 3 2 53.06 2.52 1.7259 -1 -1 5 2 53.10 1.04 1.7247 -3 -1 5 2 53.54 4.61 1.7117 1 -5 1 2 53.56 3.12 1.7110 -1 -5 2 2 53.57 1.87 1.7106 -4 -2 4 2 53.75 3.93 1.7054 0 4 2 2 53.75 1.81 1.7053 -1 -5 1 2 53.84 1.37 1.7029 -1 5 0 2 53.92 1.62 1.7003 -4 1 4 2 54.12 1.85 1.6945 -3 0 5 2 54.66 1.13 1.6791 -1 0 5 2 55.11 5.53 1.6666 2 -3 3 2 55.39 2.44 1.6587 -4 3 1 2 55.70 1.10 1.6502 -4 -3 2 2 55.76 5.15 1.6485 -2 -3 5 2 55.90 3.68 1.6447 0 -4 4 2 56.01 1.39 1.6417 1 -5 2 2 56.14 1.79 1.6384 -1 -5 3 2 56.21 3.13 1.6364 -3 -4 1 2 56.25 12.86 1.6355 3 1 2 2 56.36 1.43 1.6324 -2 1 5 2 56.68 1.17 1.6241 -3 4 2 2 56.70 4.90 1.6234 1 5 0 2 56.88 3.49 1.6187 -1 5 1 2 57.11 1.50 1.6128 -2 -5 2 2 57.17 1.17 1.6113 -2 5 0 2 57.38 13.21 1.6059 -3 1 5 2 57.38 1.98 1.6057 4 0 1 2 57.95 1.51 1.5913 2 3 2 2 57.98 7.91 1.5906 1 1 4 2 58.17 4.90 1.5858 2 -5 1 2 58.21 12.17 1.5850 0 -2 5 2 58.31 1.96 1.5824 -2 -5 3 2 58.45 6.72 1.5789 -1 1 5 2 58.48 2.55 1.5782 2 4 1 2 58.58 1.01 1.5757 -2 -5 1 2 58.60 1.18 1.5753 -5 -1 2 2 58.70 1.30 1.5729 -2 3 4 2 59.08 3.10 1.5637 -2 4 3 2 59.38 1.10 1.5564 -4 -2 5 2 59.45 1.67 1.5547 3 3 1 2 59.60 4.77 1.5513 0 0 5 2 59.61 6.96 1.5509 1 3 3 2 59.68 1.57 1.5493 -5 0 1 2 59.97 2.38 1.5425 -5 1 1 2 60.03 3.30 1.5412 -1 3 4 2 60.41 2.03 1.5324 -3 3 4 2 60.57 2.70 1.5287 -5 -1 4 2 61.04 1.58 1.5180 1 -5 3 2 61.17 1.73 1.5150 -5 2 2 2 61.54 6.02 1.5069 -5 -1 1 2 61.77 2.81 1.5019 2 -5 2 2 62.09 3.36 1.4948 -2 -5 4 2 62.13 3.50 1.4939 3 -1 3 2 62.14 1.06 1.4939 4 -3 1 2 62.15 1.09 1.4937 1 5 1 2 62.18 4.25 1.4930 2 -1 4 2 62.38 2.74 1.4887 -5 1 4 2 62.39 4.91 1.4885 -5 2 1 2 62.41 3.81 1.4880 -1 5 2 2 62.49 1.23 1.4862 -4 -4 3 2 62.73 1.93 1.4811 0 4 3 2 62.85 6.32 1.4785 -5 -2 4 2 62.98 1.94 1.4759 -4 -3 5 2 63.07 3.96 1.4739 -2 -1 6 2 63.34 3.08 1.4684 -3 -1 6 2 63.34 1.00 1.4682 -3 5 0 2 63.49 11.76 1.4653 -3 -5 2 2 63.59 5.58 1.4632 0 -6 1 2 63.71 4.27 1.4607 -3 5 1 2 63.72 3.66 1.4605 1 2 4 2 63.91 8.90 1.4565 -4 4 0 2 63.97 1.80 1.4553 4 3 0 2 64.08 7.00 1.4532 0 -6 2 2 64.19 5.02 1.4510 -1 2 5 2 64.28 5.67 1.4492 -4 -4 4 2 64.30 2.60 1.4488 -5 1 0 2 64.57 5.23 1.4434 5 0 0 2 64.68 1.77 1.4411 1 -6 1 2 65.01 2.42 1.4347 -4 3 4 2 65.07 2.80 1.4334 2 -3 4 2 65.23 1.65 1.4303 1 -1 5 2 65.34 1.82 1.4282 -5 -1 5 2 65.61 1.69 1.4230 0 6 0 2 65.72 1.61 1.4209 -1 -1 6 2 65.72 4.61 1.4207 -5 0 5 2 65.85 1.97 1.4183 -2 -3 6 2 66.07 5.75 1.4142 4 -2 2 2 66.07 1.85 1.4141 -3 -5 1 2 66.09 1.88 1.4138 -5 2 0 2 66.23 1.46 1.4111 -4 2 5 2 66.56 2.19 1.4049 -3 5 2 2 67.00 1.72 1.3968 -5 -2 5 2 67.34 5.45 1.3905 -4 -2 6 2 67.50 3.07 1.3876 1 -3 5 2 67.77 1.64 1.3827 4 -4 1 2 67.93 1.99 1.3799 -1 -3 6 2 68.01 2.08 1.3785 -5 3 3 2 68.27 1.08 1.3738 -3 1 6 2 68.49 1.08 1.3700 -4 -4 5 2 69.21 1.71 1.3574 0 2 5 2 69.51 2.87 1.3523 2 -4 4 2 69.76 1.35 1.3481 1 5 2 2 69.94 5.23 1.3451 -6 0 3 2 69.98 1.02 1.3443 -2 -6 1 2 70.10 1.41 1.3424 -1 5 3 2 70.22 3.28 1.3403 -2 -4 6 2 70.26 1.75 1.3397 -2 6 1 2 70.62 1.45 1.3338 -1 -6 4 2 71.17 2.65 1.3248 1 3 4 2 71.39 1.73 1.3212 2 -6 2 2 71.60 5.05 1.3179 1 -4 5 2 71.65 2.55 1.3171 -2 -6 4 2 71.66 3.31 1.3169 5 0 1 2 71.99 4.69 1.3117 -1 -4 6 2 72.05 2.71 1.3108 4 4 0 2 72.31 1.88 1.3067 -6 -1 2 2 72.72 3.33 1.3004 -5 -4 3 2 72.95 3.11 1.2968 -5 4 2 2 72.97 2.59 1.2965 -6 1 4 2 73.12 2.40 1.2943 -4 4 4 2 73.14 2.04 1.2939 2 2 4 2 73.21 4.45 1.2929 -5 0 6 2 73.22 1.53 1.2928 0 0 6 2 73.24 1.00 1.2923 -5 -4 4 2 73.41 8.07 1.2897 0 4 4 2 73.63 1.08 1.2865 -3 -6 3 2 74.03 2.24 1.2806 1 6 1 2 74.11 1.35 1.2794 -2 2 6 2 74.15 1.36 1.2788 -6 -2 4 2 74.29 4.35 1.2766 -1 6 2 2 74.39 2.94 1.2753 5 1 1 2 74.55 1.85 1.2729 -5 -4 2 2 74.96 1.02 1.2669 2 -1 5 2 75.13 1.89 1.2644 4 -5 1 2 75.22 3.70 1.2632 -5 4 3 2 75.24 1.18 1.2629 4 -1 3 2 75.73 1.82 1.2560 -4 -5 5 2 76.02 1.13 1.2519 -5 1 6 2 76.76 1.38 1.2416 1 -6 4 2 76.79 1.69 1.2413 3 -5 3 2 76.89 1.35 1.2399 -4 -1 7 2 77.02 1.34 1.2382 -1 -6 5 2 77.36 1.64 1.2336 2 5 2 2 77.52 1.44 1.2314 -2 -3 7 2 77.52 1.98 1.2313 1 -5 5 2 77.62 2.07 1.2301 -3 -5 6 2 78.05 1.62 1.2243 -2 0 7 2 78.63 1.02 1.2167 -5 3 5 2 78.99 1.32 1.2122 5 2 1 2 79.37 3.84 1.2073 3 3 3 2 79.75 2.42 1.2025 4 4 1 2 79.80 5.25 1.2018 0 -6 5 2 79.90 5.54 1.2006 -6 -2 1 2 80.20 1.74 1.1969 4 1 3 2 80.23 1.10 1.1965 2 -7 1 2 80.23 3.60 1.1964 -2 -7 2 2 80.27 1.54 1.1960 -2 -7 3 2 80.37 3.93 1.1947 -2 7 0 2 80.72 3.67 1.1905 -3 3 6 2 80.96 1.51 1.1875 2 1 5 2 81.12 2.09 1.1856 -4 4 5 2 81.18 5.78 1.1849 -6 2 5 2 81.30 1.35 1.1834 -4 6 1 2 82.03 1.28 1.1748 -2 1 7 2 84.13 1.36 1.1506 4 -6 1 2 84.62 1.23 1.1452 -4 -6 5 2 85.20 1.27 1.1390 1 -6 5 2 85.22 1.09 1.1387 -3 -7 3 2 85.53 1.10 1.1354 -1 -6 6 2 85.63 1.74 1.1343 3 -5 4 2 86.69 1.28 1.1231 -3 -5 7 2 86.73 2.22 1.1228 -4 -6 1 2 86.82 1.65 1.1218 1 -7 4 2 86.98 1.34 1.1202 5 -5 1 2 87.04 2.85 1.1195 -1 -7 5 2 87.76 1.34 1.1122 2 5 3 2 87.91 1.09 1.1107 -5 -5 6 2 88.02 3.37 1.1096 3 -3 5 2 88.17 3.17 1.1081 0 0 7 2 88.65 2.29 1.1033 -2 5 5 2 88.88 1.77 1.1010 5 2 2 2 89.07 2.35 1.0992 -6 4 0 2 89.18 5.20 1.0982 4 0 4 2 89.48 2.35 1.0953 3 -7 2 2 89.90 1.54 1.0912 -3 -7 5 2 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.