data_global
_chemical_name_mineral 'Beaverite-(Zn)'
loop_
_publ_author_name
'Sato E'
'Nakai I'
'Terada Y'
'Tsutsumi Y'
'Yokoyama K'
'Miyawaki R'
'Matsubara S'
_journal_name_full 'Journal of Mineralogical and Petrological Sciences'
_journal_volume 103 
_journal_year 2008
_journal_page_first 141
_journal_page_last 144
_publ_section_title
;
 Study of Zn-bearing beaverite Pb(Fe2Zn)(SO4)2(OH)6
 obtained from Mikawa mine, Niigata Prefecture, Japan
;
_database_code_amcsd 0018659
_chemical_compound_source 'Mikawa mine, Niigata Prefecture, Japan'
_chemical_formula_sum 'Pb Fe1.98 Zn.75 Cu.27 Al.09 S2 O14 H6'
_cell_length_a 7.3028
_cell_length_b 7.3028
_cell_length_c 17.0517
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 787.548
_exptl_crystal_density_diffrn      4.305
_symmetry_space_group_name_H-M 'R -3 m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '2/3+x,1/3+y,1/3+z'
  '1/3+x,2/3+y,2/3+z'
  'x,x-y,z'
  '2/3+x,1/3+x-y,1/3+z'
  '1/3+x,2/3+x-y,2/3+z'
  'y,x,-z'
  '2/3+y,1/3+x,1/3-z'
  '1/3+y,2/3+x,2/3-z'
  '-x+y,y,z'
  '2/3-x+y,1/3+y,1/3+z'
  '1/3-x+y,2/3+y,2/3+z'
  '-x,-x+y,-z'
  '2/3-x,1/3-x+y,1/3-z'
  '1/3-x,2/3-x+y,2/3-z'
  '-y,-x,z'
  '2/3-y,1/3-x,1/3+z'
  '1/3-y,2/3-x,2/3+z'
  'x-y,-y,-z'
  '2/3+x-y,1/3-y,1/3-z'
  '1/3+x-y,2/3-y,2/3-z'
  'y,-x+y,-z'
  '2/3+y,1/3-x+y,1/3-z'
  '1/3+y,2/3-x+y,2/3-z'
  '-x+y,-x,z'
  '2/3-x+y,1/3-x,1/3+z'
  '1/3-x+y,2/3-x,2/3+z'
  '-x,-y,-z'
  '2/3-x,1/3-y,1/3-z'
  '1/3-x,2/3-y,2/3-z'
  '-y,x-y,z'
  '2/3-y,1/3+x-y,1/3+z'
  '1/3-y,2/3+x-y,2/3+z'
  'x-y,x,-z'
  '2/3+x-y,1/3+x,1/3-z'
  '1/3+x-y,2/3+x,2/3-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Pb   0.00000   0.00000   0.00000   1.00000   0.03483
FeM   0.50000   0.00000   0.50000   0.66000   0.00228
ZnM   0.50000   0.00000   0.50000   0.25000   0.00228
CuM   0.50000   0.00000   0.50000   0.09000   0.00228
AlM   0.50000   0.00000   0.50000   0.03000   0.00228
S   0.00000   0.00000   0.31370   1.00000   0.03420
O1   0.00000   0.00000   0.40700   1.00000   0.00380
O2   0.22070  -0.22070  -0.04850   1.00000   0.00380
O-H   0.13080  -0.13080   0.12950   1.00000   0.01646