data_global
_amcsd_formula_title 'Ge3 K2 O9 Ti'
loop_
_publ_author_name
'Choisnet J'
'Deschanvres A'
'Raveau B'
_journal_name_full 'Journal of Solid State Chemistry'
_journal_volume 7 
_journal_year 1973
_journal_page_first 408
_journal_page_last 417
_publ_section_title
;
 Evolution structural de nouveaux germanates et silicates de type
 Wadeite et de structure apparentee
 _cod_database_code 1001118
;
_database_code_amcsd 0013324
_chemical_formula_sum 'K2 Ti Ge3 O9'
_cell_length_a 11.916
_cell_length_b 11.916
_cell_length_c 10.018
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 1231.892
_exptl_crystal_density_diffrn      3.946
_symmetry_space_group_name_H-M 'P -3 c 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-y,-x,1/2+z'
  'y,-x+y,-z'
  '-x,-x+y,1/2-z'
  '-x+y,-x,z'
  '-x+y,y,1/2+z'
  '-x,-y,-z'
  'y,x,1/2-z'
  '-y,x-y,z'
  'x,x-y,1/2+z'
  'x-y,x,-z'
  'x-y,-y,1/2-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
K1  -0.01400   0.31870   0.42330
Ti1   0.00000   0.00000   0.00000
Ti2   0.33333   0.66667   0.46950
Ge1   0.00000   0.17980   0.25000
Ge2   0.67740   0.52080   0.79000
O1   0.00000   0.43800   0.25000
O2   0.86980   0.93080   0.90280
O3   0.79850   0.65910   0.84150
O4   0.70410   0.46370   0.66900
O5   0.60720   0.43820   0.92340