data_global
_amcsd_formula_title 'H12 In N3 O12 S3'
loop_
_publ_author_name
'Jolibois B'
'Laplace G'
'Abraham F'
'Nowogrocki G'
_journal_name_full 'Journal of Solid State Chemistry'
_journal_volume 40 
_journal_year 1981
_journal_page_first 69
_journal_page_last 74
_publ_section_title
;
 Monoclinic-trigonal transition in some M(I)3 M'(III) (S O4)3 compounds:
 The high temperature form of (N H4) In (S O4)3
 _cod_database_code 1004126
;
_database_code_amcsd 0013421
_chemical_formula_sum 'N3 In S3 O12'
_cell_length_a 15.531
_cell_length_b 15.531
_cell_length_c 9.163
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 1914.111
_exptl_crystal_density_diffrn      2.316
_symmetry_space_group_name_H-M 'R 3 c'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '2/3+x,1/3+y,1/3+z'
  '1/3+x,2/3+y,2/3+z'
  'x,x-y,1/2+z'
  '2/3+x,1/3+x-y,5/6+z'
  '1/3+x,2/3+x-y,1/6+z'
  '-y,-x,1/2+z'
  '2/3-y,1/3-x,5/6+z'
  '1/3-y,2/3-x,1/6+z'
  '-x+y,y,1/2+z'
  '2/3-x+y,1/3+y,5/6+z'
  '1/3-x+y,2/3+y,1/6+z'
  '-y,x-y,z'
  '2/3-y,1/3+x-y,1/3+z'
  '1/3-y,2/3+x-y,2/3+z'
  '-x+y,-x,z'
  '2/3-x+y,1/3-x,1/3+z'
  '1/3-x+y,2/3-x,2/3+z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
N1   0.41480  -0.02600   0.27610
In1   0.00000   0.00000   0.00000
S1   0.17380   0.02610   0.24790
O1   0.02910   0.12410   0.13670
O2   0.12820   0.02090   0.38820
O3   0.23090  -0.02240   0.26530
O4   0.23570   0.12690   0.20380