data_global
_amcsd_formula_title 'K4 Mo8 O52 P12'
loop_
_publ_author_name
'Leclaire A'
'Monier J'
'Raveau B'
_journal_name_full 'Journal of Solid State Chemistry'
_journal_volume 48 
_journal_year 1983
_journal_page_first 147
_journal_page_last 153
_publ_section_title
;
 K4 Mo8 P12 O52, A Tunnel Structure Characterized by an Unusual
 Valence of Molybdenum
 _cod_database_code 1001236
;
_database_code_amcsd 0013506
_chemical_formula_sum 'Mo2 K P3 O13'
_cell_length_a 10.7433
_cell_length_b 14.0839
_cell_length_c 8.8519
_cell_angle_alpha 90
_cell_angle_beta 126.42
_cell_angle_gamma 90
_cell_volume 1077.765
_exptl_crystal_density_diffrn      3.278
_symmetry_space_group_name_H-M 'C 1 2/c 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,1/2+z'
  '1/2+x,1/2-y,1/2+z'
  '-x,y,1/2-z'
  '1/2-x,1/2+y,1/2-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Mo1   0.24451   0.08184   0.17016
K1   0.25000   0.25000   0.50000
P1   0.44330   0.20465   0.06075
P2   0.00000   0.01061   0.25000
O1   0.13420   0.07401   0.29269
O2   0.41202   0.15738   0.40193
O3   0.32876   0.13034   0.03349
O4   0.12483   0.22548   0.09672
O5   0.05233   0.05186  -0.08101
O6   0.32703  -0.02462   0.22922
O7   0.50000   0.26041   0.25000