K4 Mo8 O52 P12 Leclaire A, Monier J, Raveau B Journal of Solid State Chemistry 48 (1983) 147-153 K4 Mo8 P12 O52, A Tunnel Structure Characterized by an Unusual Valence of Molybdenum _cod_database_code 1001236 _database_code_amcsd 0013506 CELL PARAMETERS: 10.7433 14.0839 8.8519 90.000 126.420 90.000 SPACE GROUP: C2/c X-RAY WAVELENGTH: 1.541838 Cell Volume: 1077.765 Density (g/cm3): 3.278 MAX. ABS. INTENSITY / VOLUME**2: 28.16763339 RIR: 2.798 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 12.01 7.69 7.3677 1 1 0 4 12.15 43.41 7.2839 -1 1 1 4 12.57 6.87 7.0420 0 2 0 2 17.71 100.00 5.0078 0 2 1 4 20.55 15.69 4.3225 2 0 0 2 20.80 27.39 4.2706 -2 2 1 4 20.88 3.23 4.2552 -2 0 2 2 21.53 11.57 4.1277 -1 1 2 4 21.54 20.34 4.1256 1 3 0 4 21.62 8.75 4.1107 -1 3 1 4 24.16 9.32 3.6839 2 2 0 4 24.44 1.56 3.6419 -2 2 2 4 25.00 1.68 3.5615 0 0 2 2 26.34 10.70 3.3840 -3 1 1 4 26.53 32.69 3.3594 -3 1 2 4 27.89 20.21 3.1985 1 3 1 4 28.08 31.18 3.1782 0 2 2 4 28.27 9.31 3.1564 0 4 1 4 30.35 21.49 2.9446 -2 4 1 4 31.69 1.59 2.8232 3 1 0 4 31.98 13.07 2.7988 -3 3 1 4 32.14 3.25 2.7849 -3 3 2 4 32.19 15.72 2.7809 -3 1 3 4 32.53 10.30 2.7528 2 2 1 4 32.81 6.89 2.7299 2 4 0 4 32.96 1.33 2.7179 -2 2 3 4 33.01 16.69 2.7134 1 1 2 4 33.02 4.40 2.7127 -2 4 2 4 33.37 4.28 2.6855 -4 0 2 2 35.79 1.70 2.5092 -4 2 2 4 36.59 1.57 2.4559 3 3 0 4 37.03 4.39 2.4280 -3 3 3 4 37.83 2.23 2.3780 -4 2 1 4 38.15 6.58 2.3591 -1 5 2 4 38.21 1.15 2.3554 -4 2 3 4 38.35 7.45 2.3473 0 6 0 2 39.53 5.90 2.2795 2 4 1 4 39.90 3.57 2.2595 -2 4 3 4 41.20 4.70 2.1910 -3 5 1 4 41.32 11.55 2.1852 -3 1 4 4 41.33 1.10 2.1843 -3 5 2 4 41.80 4.36 2.1612 4 0 0 2 42.96 2.02 2.1056 -5 1 2 4 43.17 4.56 2.0957 -5 1 3 4 43.36 2.76 2.0867 2 2 2 4 43.82 1.48 2.0661 4 2 0 4 43.87 1.75 2.0638 -2 2 4 4 43.89 12.50 2.0628 2 6 0 4 44.12 2.28 2.0527 -4 4 1 4 44.48 1.81 2.0367 -4 2 4 4 44.70 7.03 2.0271 3 3 1 4 45.37 4.76 1.9988 -3 5 3 4 45.69 4.82 1.9855 1 1 3 4 45.98 2.86 1.9740 -1 1 4 4 46.11 3.85 1.9686 0 4 3 4 46.20 3.54 1.9651 -1 5 3 4 47.05 6.42 1.9316 -5 3 3 4 47.16 7.13 1.9272 -5 1 4 4 49.42 4.57 1.8443 1 3 3 4 50.01 3.10 1.8237 -1 7 2 4 51.71 3.10 1.7678 3 1 2 4 52.67 1.87 1.7379 4 2 1 4 53.54 1.51 1.7116 -4 2 5 4 53.63 3.53 1.7091 0 8 1 4 53.98 1.36 1.6987 -5 5 2 4 54.16 1.22 1.6935 -5 5 3 4 54.21 1.57 1.6920 -6 2 2 4 54.64 1.68 1.6797 -6 2 4 4 54.88 1.87 1.6729 -2 8 1 4 55.72 1.71 1.6497 3 7 0 4 55.87 3.59 1.6456 -3 3 5 4 56.23 3.55 1.6361 -2 2 5 4 56.31 2.08 1.6338 1 5 3 4 56.56 2.41 1.6273 -1 5 4 4 56.57 2.60 1.6269 1 7 2 4 56.58 1.84 1.6268 -2 8 2 4 56.74 4.32 1.6223 -1 7 3 4 57.58 6.56 1.6008 -5 5 4 4 57.60 2.36 1.6002 -5 3 5 4 57.69 3.26 1.5980 4 4 1 4 58.01 3.11 1.5899 4 6 0 4 58.83 1.70 1.5697 -6 2 1 4 59.14 4.09 1.5621 -6 4 2 4 59.23 1.90 1.5600 1 1 4 4 60.12 1.24 1.5391 -1 9 1 4 61.08 2.63 1.5172 2 8 1 4 61.21 2.37 1.5143 -7 1 4 4 61.59 6.03 1.5059 3 5 2 4 62.39 2.30 1.4884 -3 7 4 4 63.11 1.10 1.4731 -4 0 6 2 63.53 2.88 1.4643 -6 4 1 4 63.62 2.36 1.4625 -5 7 2 4 63.78 1.23 1.4593 -7 1 2 4 63.79 1.15 1.4591 -5 7 3 4 64.07 2.68 1.4533 -7 3 3 4 64.29 1.16 1.4488 3 1 3 4 64.31 1.79 1.4485 -6 4 5 4 64.52 1.82 1.4444 -4 8 1 4 64.69 1.01 1.4408 6 0 0 2 65.77 1.44 1.4199 5 3 1 4 65.85 1.38 1.4184 -6 0 6 2 65.96 1.31 1.4162 -1 7 4 4 67.31 1.90 1.3911 3 3 3 4 67.46 1.81 1.3883 -7 3 5 4 67.83 1.39 1.3816 0 10 1 4 68.41 4.45 1.3715 -2 0 6 2 68.44 1.89 1.3708 2 8 2 4 68.47 2.21 1.3702 -3 9 3 4 68.93 1.80 1.3623 -2 10 1 4 69.27 1.56 1.3564 -4 8 4 4 71.43 1.69 1.3206 0 4 5 4 76.32 1.87 1.2477 -4 6 6 4 76.42 1.21 1.2463 -4 8 5 4 76.71 1.11 1.2424 1 3 5 4 77.34 1.06 1.2338 1 9 3 4 77.78 1.59 1.2280 6 6 0 4 77.98 1.14 1.2252 -5 9 1 4 81.24 1.10 1.1842 -2 6 6 4 83.29 1.12 1.1602 -1 11 3 4 85.79 1.24 1.1326 2 12 0 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.