CsK2BiCl6 Benachenhou F, Mairesse G, Nowogrocki G, Thomas D Journal of Solid State Chemistry 65 (1986) 13-26 Structural studies of Cs-K-Bi mixed chlorides relation to the crystal structures of A2BMX6, A3MX6 and A2MX6 _cod_database_code 1004083 _database_code_amcsd 0013585 CELL PARAMETERS: 25.6530 7.7990 12.8740 90.000 99.240 90.000 SPACE GROUP: C2/c X-RAY WAVELENGTH: 1.541838 Cell Volume: 2542.251 Density (g/cm3): 3.306 MAX. ABS. INTENSITY / VOLUME**2: 28.13537447 RIR: 2.771 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 6.98 28.48 12.6601 2 0 0 2 13.49 6.37 6.5659 -1 1 1 4 13.94 3.24 6.3535 0 0 2 2 13.99 53.43 6.3300 4 0 0 2 14.06 89.34 6.3004 1 1 1 4 14.56 41.92 6.0836 -2 0 2 2 16.27 29.24 5.4491 -3 1 1 4 16.59 10.64 5.3449 2 0 2 2 17.91 1.36 4.9521 -1 1 2 4 18.12 3.30 4.8944 -4 0 2 2 21.14 14.55 4.2019 -5 1 1 4 21.35 1.98 4.1625 4 0 2 2 22.00 1.10 4.0409 3 1 2 4 22.80 34.06 3.8995 0 2 0 2 22.95 92.42 3.8744 5 1 1 4 23.36 26.82 3.8084 -6 0 2 2 23.58 1.18 3.7735 -5 1 2 4 23.66 100.00 3.7597 -1 1 3 4 23.87 1.24 3.7279 0 2 1 4 23.88 7.14 3.7267 2 2 0 4 24.57 1.49 3.6226 -2 2 1 4 24.66 3.78 3.6100 1 1 3 4 24.74 1.15 3.5983 -3 1 3 4 26.83 5.14 3.3235 0 2 2 4 26.85 27.44 3.3201 4 2 0 4 27.06 17.20 3.2955 -7 1 1 4 27.16 9.42 3.2830 -2 2 2 4 27.18 1.35 3.2808 6 0 2 2 27.52 15.76 3.2410 3 1 3 4 27.67 13.74 3.2241 -5 1 3 4 27.84 4.65 3.2051 -2 0 4 2 28.09 8.74 3.1767 0 0 4 2 28.35 2.51 3.1481 4 2 1 4 29.08 2.45 3.0707 7 1 1 4 29.28 5.99 3.0499 -4 2 2 4 29.44 4.97 3.0341 -8 0 2 2 30.05 9.17 2.9735 -1 1 4 4 30.08 2.45 2.9707 2 0 4 2 30.66 1.25 2.9161 -3 1 4 4 31.21 1.33 2.8659 -2 2 3 4 31.26 11.04 2.8616 -6 2 1 4 31.44 21.07 2.8458 4 2 2 4 31.78 2.25 2.8155 5 1 3 4 31.98 1.55 2.7989 -7 1 3 4 32.44 7.51 2.7599 -6 0 4 2 32.48 1.17 2.7564 7 1 2 4 32.80 3.29 2.7308 6 2 1 4 32.87 76.33 2.7246 -6 2 2 4 33.53 32.75 2.6724 4 0 4 2 35.45 11.27 2.5320 10 0 0 2 35.54 4.08 2.5260 1 3 1 4 35.68 16.21 2.5161 9 1 1 4 35.77 11.23 2.5105 6 2 2 4 35.89 1.19 2.5024 -6 2 3 4 36.01 7.00 2.4939 -10 0 2 2 36.39 1.09 2.4692 -7 1 4 4 36.48 4.98 2.4629 0 2 4 4 36.52 2.10 2.4603 -3 3 1 4 36.57 5.71 2.4574 8 2 0 4 36.72 3.62 2.4472 -8 0 4 2 37.02 3.15 2.4284 7 1 3 4 37.11 9.31 2.4230 -3 1 5 4 37.24 1.91 2.4142 -9 1 3 4 37.33 5.47 2.4091 -1 3 2 4 37.50 2.15 2.3984 -4 2 4 4 37.56 2.78 2.3946 -8 2 2 4 37.94 4.54 2.3714 1 1 5 4 38.09 3.13 2.3623 6 0 4 2 39.07 2.37 2.3053 -5 3 1 4 40.02 2.55 2.2527 -6 2 4 4 40.14 16.13 2.2465 5 3 1 4 40.36 3.03 2.2345 3 1 5 4 40.38 11.25 2.2339 -11 1 1 4 40.41 4.78 2.2321 10 0 2 2 40.57 17.58 2.2235 -1 3 3 4 40.94 17.82 2.2044 4 2 4 4 41.66 18.55 2.1679 -7 1 5 4 42.08 1.21 2.1474 -2 2 5 4 42.11 9.75 2.1456 -2 0 6 2 42.57 3.40 2.1237 5 3 2 4 42.57 2.90 2.1236 10 2 0 4 42.76 4.73 2.1148 -7 3 1 4 42.86 4.91 2.1100 12 0 0 2 42.95 2.50 2.1060 9 1 3 4 43.05 10.56 2.1009 -10 2 2 4 43.07 7.64 2.1001 3 3 3 4 43.17 7.83 2.0955 -5 3 3 4 43.20 1.99 2.0944 -11 1 3 4 43.48 4.17 2.0813 8 0 4 2 43.67 4.55 2.0728 -8 2 4 4 43.91 1.58 2.0620 -7 3 2 4 43.91 4.26 2.0619 5 1 5 4 44.49 3.37 2.0363 2 0 6 2 44.69 3.23 2.0279 -6 0 6 2 46.58 7.51 1.9497 0 4 0 2 46.90 12.18 1.9372 10 2 2 4 47.16 3.75 1.9272 0 4 1 4 47.16 1.37 1.9270 2 4 0 4 47.76 6.83 1.9042 -12 0 4 2 48.42 20.10 1.8798 -2 2 6 4 48.86 1.66 1.8640 0 4 2 4 48.88 2.75 1.8634 4 4 0 4 48.94 1.43 1.8611 0 2 6 4 49.01 5.80 1.8586 9 3 1 4 49.06 4.38 1.8567 -2 4 2 4 49.40 2.20 1.8447 11 1 3 4 49.65 6.47 1.8361 8 2 4 4 49.67 2.94 1.8354 -13 1 3 4 49.78 1.22 1.8317 2 4 2 4 49.88 2.69 1.8281 13 1 1 4 50.05 2.31 1.8224 7 3 3 4 50.12 2.50 1.8201 -3 3 5 4 50.18 1.25 1.8180 -14 0 2 2 50.23 1.75 1.8164 -9 3 3 4 50.41 6.03 1.8104 -11 1 5 4 50.57 2.90 1.8050 2 2 6 4 50.61 1.16 1.8036 10 2 3 4 50.74 3.36 1.7991 -6 2 6 4 51.23 1.57 1.7832 -1 1 7 4 51.28 1.34 1.7816 6 0 6 2 51.78 1.11 1.7657 4 4 2 4 52.74 3.30 1.7357 -11 3 1 4 52.74 5.21 1.7355 -6 4 2 4 53.35 2.59 1.7173 12 2 2 4 53.56 3.90 1.7111 -12 2 4 4 53.64 4.48 1.7086 9 1 5 4 53.79 4.12 1.7043 -7 3 5 4 54.18 1.08 1.6929 -14 0 4 2 54.68 5.92 1.6786 3 1 7 4 54.85 1.23 1.6737 9 3 3 4 54.97 3.57 1.6703 14 0 2 2 54.99 6.03 1.6699 -15 1 1 4 55.06 1.11 1.6678 -11 3 3 4 55.14 1.17 1.6657 -2 4 4 4 55.28 1.76 1.6617 0 4 4 4 57.02 2.31 1.6151 -9 1 7 4 57.91 1.17 1.5924 -6 4 4 4 58.31 2.39 1.5825 16 0 0 2 58.61 5.06 1.5751 4 4 4 4 59.93 1.67 1.5435 1 5 1 4 60.25 3.07 1.5360 -10 4 2 4 60.28 3.44 1.5354 14 2 2 4 60.61 1.06 1.5279 -13 3 3 4 60.91 3.73 1.5209 -8 0 8 2 61.08 2.14 1.5170 -16 0 4 2 61.24 1.46 1.5137 8 2 6 4 61.25 1.83 1.5134 -11 3 5 4 61.62 1.46 1.5051 -12 2 6 4 61.92 2.34 1.4986 7 1 7 4 61.97 1.45 1.4974 -1 3 7 4 62.68 2.00 1.4823 -4 2 8 4 62.89 1.04 1.4778 -16 2 2 4 63.14 1.39 1.4725 5 5 1 4 63.26 1.74 1.4699 4 4 5 4 63.34 2.73 1.4684 10 4 2 4 63.44 1.14 1.4664 16 2 0 4 63.45 2.11 1.4660 -1 5 3 4 63.97 1.02 1.4555 -17 1 3 4 64.12 1.48 1.4524 9 3 5 4 64.59 2.14 1.4430 -2 4 6 4 65.05 2.65 1.4338 3 3 7 4 65.30 1.58 1.4289 3 5 3 4 65.33 2.06 1.4284 -15 3 1 4 65.38 1.19 1.4274 -5 5 3 4 65.52 1.71 1.4247 -13 1 7 4 65.61 1.85 1.4229 8 4 4 4 65.92 2.32 1.4169 -8 2 8 4 66.05 3.13 1.4146 13 1 5 4 66.09 2.81 1.4138 -16 2 4 4 66.38 1.42 1.4083 2 4 6 4 66.45 3.26 1.4069 -3 1 9 4 66.53 1.15 1.4055 -6 4 6 4 68.18 1.23 1.3754 1 1 9 4 68.40 1.12 1.3715 -7 1 9 4 68.93 2.51 1.3623 -12 4 4 4 69.93 1.22 1.3453 9 5 1 4 70.47 1.08 1.3362 8 0 8 2 70.95 1.02 1.3283 -19 1 1 4 71.67 1.52 1.3167 7 3 7 4 72.69 1.41 1.3009 -12 2 8 4 72.97 1.18 1.2964 -11 5 1 4 73.59 1.05 1.2872 -17 3 3 4 73.85 1.09 1.2832 -7 5 5 4 74.85 1.90 1.2685 14 4 2 4 75.05 1.40 1.2657 -13 3 7 4 75.16 1.28 1.2641 8 2 8 4 75.54 1.29 1.2586 13 3 5 4 75.93 1.59 1.2532 -3 3 9 4 76.54 1.17 1.2446 2 0 10 2 76.99 1.23 1.2385 -17 1 7 4 77.61 1.01 1.2302 -6 6 2 4 77.72 1.07 1.2287 16 4 0 4 78.83 1.10 1.2142 14 2 6 4 79.38 1.26 1.2071 -18 2 6 4 79.62 1.98 1.2041 20 2 0 4 79.79 1.40 1.2020 19 1 3 4 80.01 1.98 1.1992 -8 4 8 4 80.14 1.23 1.1977 -21 1 3 4 80.16 1.10 1.1973 -16 4 4 4 81.11 1.66 1.1857 2 2 10 4 86.00 1.32 1.1304 12 2 8 4 86.73 1.05 1.1227 -9 1 11 4 88.80 1.02 1.1018 19 3 3 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.