data_global
_amcsd_formula_title 'O19 P5 Si V3'
loop_
_publ_author_name
'Leclaire A'
'Chahboun H'
'Groult D'
'Raveau B'
_journal_name_full 'Journal of Solid State Chemistry'
_journal_volume 65 
_journal_year 1986
_journal_page_first 168
_journal_page_last 177
_publ_section_title
;
 V3 P5 Si O19, a vanadosilicophospahte built up from V2 O9 octahedra
 clusters
 _cod_database_code 1001683
;
_database_code_amcsd 0013586
_chemical_formula_sum 'V3 P5 Si O19'
_cell_length_a 14.4671
_cell_length_b 14.4671
_cell_length_c 7.4605
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 1352.264
_exptl_crystal_density_diffrn      3.142
_symmetry_space_group_name_H-M 'P 63'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  'x-y,x,1/2+z'
  '-y,x-y,z'
  '-x,-y,1/2+z'
  '-x+y,-x,z'
  'y,-x+y,1/2+z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
V1   0.34500   0.32100   0.05614
V2   0.33930   0.32480   0.44450
P1   0.21190   0.43340   0.24920
P2   0.51630   0.09610   0.26080
P3   0.23340   0.08410   0.25050
P4   0.00000   0.00000   0.29110
Si1  -0.33330   0.33333   0.21770
Si2   0.33333  -0.33330   0.29750
O1   0.30430   0.20700   0.25100
O2   0.45990   0.39740   0.25320
O3   0.26640   0.36540   0.24520
O4   0.24490   0.04150   0.07410
O5   0.24750   0.03190   0.41690
O6   0.26720  -0.14230   0.08380
O7   0.26880  -0.15710   0.42310
O8   0.45870   0.07420   0.08660
O9   0.44890   0.05040   0.42270
O10   0.24490  -0.30630   0.22230
O11  -0.42270   0.21940   0.29750
O12   0.00000   0.00000  -0.00190
O13   0.11850   0.06770   0.25270
O14  -0.33330   0.33333   0.00800