data_global _amcsd_formula_title 'Mo O11 P3 Si' loop_ _publ_author_name 'Leclaire A' 'Raveau B' _journal_name_full 'Journal of Solid State Chemistry' _journal_volume 71 _journal_year 1987 _journal_page_first 283 _journal_page_last 290 _publ_section_title ; Mo P3 Si O11: A silicophosphate of molybdenum(III) _cod_database_code 1001344 ; _database_code_amcsd 0013604 _chemical_formula_sum 'Mo P3 Si O11' _cell_length_a 14.584 _cell_length_b 8.416 _cell_length_c 14.180 _cell_angle_alpha 90 _cell_angle_beta 110.05 _cell_angle_gamma 90 _cell_volume 1634.957 _exptl_crystal_density_diffrn 3.193 _symmetry_space_group_name_H-M 'C 1 2/c 1' loop_ _space_group_symop_operation_xyz 'x,y,z' '1/2+x,1/2+y,z' 'x,-y,1/2+z' '1/2+x,1/2-y,1/2+z' '-x,y,1/2-z' '1/2-x,1/2+y,1/2-z' '-x,-y,-z' '1/2-x,1/2-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z Mo1 0.09088 0.25000 0.02267 P1 -0.03788 0.04756 0.14195 P2 0.31616 0.09844 0.14196 P3 0.38628 0.10398 0.35802 Si1 0.21046 0.25007 0.38147 O1 0.23377 0.21326 0.11828 O2 0.08549 0.43527 0.11821 O3 0.04877 0.10172 0.11823 O4 0.12876 0.41264 -0.07075 O5 0.10645 0.06507 -0.07045 O6 -0.05580 0.27268 -0.07059 O7 -0.09733 0.19396 0.15953 O8 0.00000 -0.03410 0.25000 O9 0.25000 0.25000 0.50000 O10 0.21861 0.42708 0.34057 O11 0.27458 0.12886 0.34066 O12 0.39187 0.14213 0.25005