Cu H16 I2 K4 O20 Masse R, Durif A Journal of Solid State Chemistry 73 (1988) 206-210 A Copper(III) Periodate Peroxo Complex: K4 H4 Cu (I O6)2 O2 6(H2 O) _cod_database_code 1007184 _database_code_amcsd 0013612 CELL PARAMETERS: 12.6500 9.7800 7.7100 90.000 95.200 90.000 SPACE GROUP: P2_1/n X-RAY WAVELENGTH: 1.541838 Cell Volume: 949.932 Density (g/cm3): 2.775 MAX. ABS. INTENSITY / VOLUME**2: 15.04299854 RIR: 1.765 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 12.95 93.31 6.8376 -1 0 1 2 14.04 54.87 6.3073 1 0 1 2 14.06 84.21 6.2990 2 0 0 2 14.67 7.99 6.0394 0 1 1 4 15.81 70.65 5.6039 -1 1 1 4 16.73 100.00 5.3006 1 1 1 4 16.74 4.36 5.2956 2 1 0 4 18.14 29.76 4.8900 0 2 0 2 19.47 9.66 4.5586 1 2 0 4 19.63 3.44 4.5234 -2 1 1 4 21.09 9.09 4.2119 2 1 1 4 22.35 4.91 3.9775 -1 2 1 4 23.01 13.92 3.8646 1 2 1 4 23.03 20.77 3.8627 2 2 0 4 23.05 1.45 3.8586 3 1 0 4 23.20 27.17 3.8335 -3 0 1 2 24.92 21.51 3.5737 0 1 2 4 24.95 16.79 3.5691 -3 1 1 4 25.08 4.52 3.5513 3 0 1 2 26.06 6.92 3.4188 -2 0 2 2 26.49 11.97 3.3643 1 1 2 4 26.71 41.90 3.3380 3 1 1 4 27.64 50.94 3.2273 -2 1 2 4 28.01 5.82 3.1858 3 2 0 4 28.28 8.32 3.1560 1 3 0 4 28.34 31.14 3.1495 4 0 0 2 29.58 14.89 3.0197 0 2 2 4 29.61 25.95 3.0169 -3 2 1 4 29.77 30.27 3.0015 2 1 2 4 29.77 2.28 3.0007 0 3 1 4 29.80 2.11 2.9979 4 1 0 4 30.88 33.85 2.8960 1 3 1 4 30.94 2.99 2.8902 1 2 2 4 31.08 4.50 2.8779 -4 1 1 4 31.12 1.51 2.8735 3 2 1 4 31.47 15.69 2.8425 -3 1 2 4 31.94 7.56 2.8019 -2 2 2 4 32.60 16.18 2.7471 -2 3 1 4 33.53 8.55 2.6725 2 3 1 4 33.82 3.16 2.6503 2 2 2 4 33.85 6.37 2.6478 4 2 0 4 34.29 7.53 2.6148 3 1 2 4 34.84 1.65 2.5751 3 3 0 4 34.99 2.73 2.5641 -4 2 1 4 35.14 3.99 2.5537 -1 0 3 2 35.35 4.27 2.5389 -3 2 2 4 36.15 5.60 2.4850 0 3 2 4 36.17 8.12 2.4834 -3 3 1 4 36.28 8.88 2.4760 0 1 3 4 36.36 4.76 2.4709 -1 1 3 4 36.45 1.11 2.4650 1 0 3 2 36.51 1.46 2.4610 -5 0 1 2 36.76 2.92 2.4450 0 4 0 2 37.45 7.80 2.4016 3 3 1 4 37.86 3.82 2.3764 -2 1 3 4 38.14 5.17 2.3593 -2 3 2 4 38.61 1.59 2.3322 5 0 1 2 38.65 4.46 2.3297 0 4 1 4 39.13 2.00 2.3022 -1 4 1 4 39.53 2.83 2.2797 1 4 1 4 39.54 17.16 2.2793 2 4 0 4 39.54 2.06 2.2792 -3 0 3 2 39.73 9.18 2.2686 5 1 1 4 39.75 2.15 2.2676 0 2 3 4 39.77 3.05 2.2666 2 3 2 4 39.80 1.46 2.2651 4 3 0 4 39.82 7.48 2.2637 -1 2 3 4 40.29 1.05 2.2385 2 1 3 4 40.64 6.20 2.2197 -3 1 3 4 40.79 3.60 2.2120 -4 3 1 4 40.93 2.93 2.2049 -2 4 1 4 41.00 7.56 2.2011 1 2 3 4 42.10 1.07 2.1463 -5 1 2 4 42.33 2.68 2.1351 4 3 1 4 42.80 4.25 2.1129 3 4 0 4 42.95 10.89 2.1060 4 2 2 4 43.39 3.11 2.0856 3 3 2 4 43.49 1.06 2.0810 2 2 3 4 43.82 6.61 2.0658 -3 2 3 4 43.92 10.10 2.0614 -3 4 1 4 44.11 2.10 2.0529 6 1 0 4 44.15 1.24 2.0512 -1 4 2 4 44.52 2.54 2.0352 -4 1 3 4 44.88 2.07 2.0196 1 4 2 4 45.02 1.51 2.0139 3 4 1 4 45.10 7.55 2.0104 -1 3 3 4 45.13 6.43 2.0090 -4 3 2 4 46.22 1.70 1.9642 -5 3 1 4 46.36 2.70 1.9585 -2 3 3 4 46.81 1.12 1.9408 6 1 1 4 47.05 10.08 1.9315 3 2 3 4 47.05 8.44 1.9313 4 4 0 4 47.36 5.51 1.9196 0 0 4 2 47.43 2.16 1.9167 -6 0 2 2 47.93 2.21 1.8981 -4 4 1 4 47.94 5.01 1.8975 4 3 2 4 47.96 15.29 1.8968 5 3 1 4 48.21 1.40 1.8876 -1 1 4 4 48.34 1.21 1.8829 -5 0 3 2 48.39 5.63 1.8810 -6 1 2 4 48.40 1.74 1.8806 -1 5 1 4 48.69 2.57 1.8701 5 2 2 4 48.73 1.33 1.8685 4 1 3 4 49.24 2.58 1.8504 -2 1 4 4 49.29 4.33 1.8489 -5 1 3 4 49.29 4.43 1.8488 4 4 1 4 49.93 1.56 1.8264 -2 5 1 4 50.02 1.79 1.8235 -5 3 2 4 51.01 3.52 1.7902 -1 2 4 4 51.12 6.33 1.7868 0 2 4 4 51.79 4.46 1.7652 6 3 0 4 51.79 1.66 1.7652 -4 4 2 4 51.89 3.66 1.7622 2 1 4 4 52.01 8.19 1.7584 -2 2 4 4 52.05 4.74 1.7571 -5 2 3 4 52.28 3.34 1.7497 -6 3 1 4 52.37 3.94 1.7471 6 1 2 4 52.51 5.15 1.7428 0 5 2 4 52.52 1.39 1.7423 -3 5 1 4 52.73 1.57 1.7359 1 4 3 4 52.78 8.06 1.7345 -5 4 1 4 53.28 1.83 1.7193 5 0 3 2 53.48 5.07 1.7133 3 5 1 4 53.61 2.77 1.7094 -4 0 4 2 54.01 2.79 1.6978 -2 5 2 4 54.20 1.58 1.6924 6 3 1 4 54.21 5.46 1.6921 7 1 1 4 54.32 2.05 1.6890 7 2 0 4 54.35 1.03 1.6881 4 4 2 4 54.36 1.58 1.6876 5 4 1 4 54.55 3.81 1.6821 2 2 4 4 54.64 2.10 1.6798 -7 2 1 4 55.02 5.30 1.6690 6 2 2 4 55.26 5.38 1.6622 2 5 2 4 55.56 2.30 1.6541 0 3 4 4 55.62 4.00 1.6523 -6 3 2 4 56.44 6.45 1.6305 -5 3 3 4 56.76 3.55 1.6220 5 2 3 4 57.08 7.65 1.6137 -4 2 4 4 57.84 2.21 1.5941 3 4 3 4 57.89 6.00 1.5929 6 4 0 4 58.14 1.36 1.5868 3 5 2 4 58.51 1.16 1.5774 -5 1 4 4 58.62 3.96 1.5747 8 0 0 2 59.45 1.50 1.5547 8 1 0 4 59.56 1.43 1.5522 -4 5 2 4 60.58 3.27 1.5286 -2 5 3 4 60.84 3.29 1.5225 -1 1 5 4 60.93 1.36 1.5206 -7 1 3 4 61.47 1.54 1.5085 -6 4 2 4 61.82 1.74 1.5007 4 2 4 4 61.91 1.54 1.4987 5 5 1 4 62.03 1.00 1.4961 -1 6 2 4 62.20 1.09 1.4926 -2 4 4 4 62.30 2.48 1.4904 1 1 5 4 62.32 5.12 1.4899 2 5 3 4 62.40 1.15 1.4881 -8 1 2 4 62.61 1.48 1.4837 1 6 2 4 63.29 1.92 1.4695 -3 1 5 4 63.34 1.26 1.4683 -7 2 3 4 64.33 1.59 1.4480 2 6 2 4 64.56 4.01 1.4436 -7 4 1 4 65.30 1.32 1.4290 -3 6 2 4 65.65 2.42 1.4221 -3 2 5 4 65.70 3.87 1.4212 -6 2 4 4 66.19 1.11 1.4119 4 6 1 4 66.84 1.24 1.3996 -9 0 1 2 67.44 1.88 1.3886 1 7 0 4 67.50 4.65 1.3877 3 1 5 4 68.23 1.22 1.3746 0 7 1 4 68.26 1.95 1.3740 -1 6 3 4 68.40 1.33 1.3716 -1 5 4 4 68.54 1.83 1.3690 -6 5 2 4 68.55 1.18 1.3689 -1 7 1 4 68.56 1.42 1.3687 1 3 5 4 69.08 3.26 1.3596 1 6 3 4 69.12 1.40 1.3590 -5 6 1 4 69.20 2.07 1.3576 7 2 3 4 69.23 4.81 1.3572 8 2 2 4 69.39 1.36 1.3544 -5 1 5 4 69.50 1.35 1.3524 -3 3 5 4 69.79 1.13 1.3475 -2 7 1 4 70.01 2.03 1.3439 6 1 4 4 70.08 1.91 1.3427 9 1 1 4 71.11 1.14 1.3258 -3 6 3 4 71.12 1.26 1.3257 3 7 0 4 71.23 1.47 1.3239 8 4 0 4 71.92 2.01 1.3129 0 7 2 4 72.73 1.41 1.3001 3 7 1 4 73.52 1.95 1.2882 3 6 3 4 73.84 1.72 1.2834 -6 5 3 4 73.93 1.67 1.2821 -8 4 2 4 74.09 1.10 1.2797 0 0 6 2 74.37 1.00 1.2755 -8 0 4 2 74.95 1.74 1.2671 -9 1 3 4 75.37 1.10 1.2611 -5 3 5 4 75.97 1.67 1.2527 6 3 4 4 76.04 1.74 1.2517 9 3 1 4 76.08 1.14 1.2511 5 1 5 4 76.70 2.33 1.2425 0 6 4 4 77.31 2.24 1.2342 -8 2 4 4 77.59 1.72 1.2305 -10 0 2 2 78.17 1.24 1.2228 2 1 6 4 78.24 1.10 1.2219 5 7 0 4 78.31 1.37 1.2209 -10 1 2 4 78.57 1.65 1.2175 6 5 3 4 79.11 1.20 1.2106 -1 5 5 4 79.67 1.32 1.2034 -1 8 1 4 79.88 1.13 1.2008 6 6 2 4 79.94 1.28 1.2001 2 8 0 4 80.78 2.19 1.1897 -9 3 3 4 80.95 1.48 1.1876 -7 2 5 4 81.30 1.18 1.1834 -3 5 5 4 81.34 1.59 1.1829 5 6 3 4 81.88 1.05 1.1765 5 3 5 4 84.21 1.25 1.1498 4 0 6 2 84.49 1.03 1.1467 -4 3 6 4 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.