data_global _amcsd_formula_title 'Mo8 O52 P12 Rb4' loop_ _publ_author_name 'Riou D' 'Goreaud M' _journal_name_full 'Journal of Solid State Chemistry' _journal_volume 79 _journal_year 1989 _journal_page_first 99 _journal_page_last 106 _publ_section_title ; Rb4 Mo8 P12 O52, a Molybdenophosphate of the Cs4 Mo8 P12 O52 Type: Structure and Properties of Host Framework _cod_database_code 1001408 ; _database_code_amcsd 0013648 _chemical_formula_sum 'Rb Mo2 P3 O13' _cell_length_a 6.3847 _cell_length_b 19.088 _cell_length_c 9.7366 _cell_angle_alpha 90 _cell_angle_beta 107.05 _cell_angle_gamma 90 _cell_volume 1134.458 _exptl_crystal_density_diffrn 3.386 _symmetry_space_group_name_H-M 'P 1 21 1' loop_ _space_group_symop_operation_xyz 'x,y,z' '-x,1/2+y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z Rb1 0.22740 0.16000 0.01560 Rb2 0.78410 0.49120 0.36470 Mo1 0.13920 0.49349 0.07160 Mo2 0.56180 0.03325 0.37380 Mo3 0.63900 0.31919 0.05690 Mo4 0.93740 0.28447 0.60910 P1 0.09450 0.33300 0.95980 P2 0.73850 0.12310 0.68960 P3 0.59550 0.48170 0.96990 P4 0.75660 0.19250 0.29650 P5 0.01530 0.06820 0.28640 P6 0.48100 0.24780 0.69850 O1 0.88100 0.03030 0.36900 O2 0.63000 0.28460 0.62120 O3 0.94100 0.30580 0.03970 O4 0.96500 0.05380 0.12970 O5 0.25400 0.05900 0.37190 O6 0.32400 0.31230 0.05170 O7 0.90000 0.17310 0.65910 O8 0.53500 0.26510 0.85570 O9 0.24400 0.25700 0.61120 O10 0.59600 0.14330 0.32780 O11 0.04700 0.29410 0.81780 O12 0.82700 0.25150 0.40440 O13 0.44500 0.50040 0.06170 O14 0.82600 0.09260 0.84100 O15 0.58700 0.40560 0.92830 O16 0.66200 0.06500 0.58430 O17 0.67200 0.22250 0.14760 O18 0.52500 0.16460 0.68670 O19 0.97700 0.15010 0.29770 O20 0.71000 0.36520 0.20750 O21 0.06900 0.41230 0.93350 O22 0.93400 0.36710 0.56320 O23 0.20300 0.44680 0.22000 O24 0.46400 0.02960 0.16110 O25 0.17500 0.00310 0.93520 O26 0.44900 0.44940 0.58500 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Rb1 0.03460 0.02050 0.07100 -0.01040 -0.02070 0.01230 Rb2 0.04860 0.03850 0.01780 0.00190 0.00450 -0.01030 Mo1 0.00450 0.00760 0.00660 0.00120 0.00190 -0.00010 Mo2 0.00450 0.00510 0.00710 -0.00050 0.00170 -0.00080 Mo3 0.00530 0.00690 0.00630 0.00120 0.00140 0.00080 Mo4 0.00660 0.00790 0.00520 -0.00030 0.00100 -0.00050 P1 0.01100 0.00100 0.01000 -0.00140 0.00350 -0.00200 P2 0.00700 0.00800 0.00400 0.00000 0.00140 0.00300 P3 0.00300 0.01500 0.00400 -0.00100 0.00060 0.00200 P4 0.00700 0.00500 0.00900 -0.00300 0.00180 -0.00400 P5 0.00800 0.00800 0.00900 0.00400 0.00270 0.00100 P6 0.00600 0.01000 0.00600 -0.00300 0.00250 -0.00200