data_global
_amcsd_formula_title 'Bi0.7 La0.3 O1.38'
loop_
_publ_author_name
'Mercurio D'
'El Farissi M'
'Champarnaud Mesjard J'
'Frit B'
'Conflant P'
'Roult G'
_journal_name_full 'Journal of Solid State Chemistry'
_journal_volume 80 
_journal_year 1989
_journal_page_first 133
_journal_page_last 143
_publ_section_title
;
 Etude structurale par diffraction X sur monocristal et diffraction
 neutronique sur poudre de l'oxyde mixte Bi.7 La.3 O1.5
 _cod_database_code 1004087
;
_database_code_amcsd 0013654
_chemical_formula_sum 'La.9 Bi2.1 O4.14'
_cell_length_a 4.040
_cell_length_b 4.040
_cell_length_c 27.557
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 120
_cell_volume 389.516
_exptl_crystal_density_diffrn      8.059
_symmetry_space_group_name_H-M 'R -3 m'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '2/3+x,1/3+y,1/3+z'
  '1/3+x,2/3+y,2/3+z'
  'x,x-y,z'
  '2/3+x,1/3+x-y,1/3+z'
  '1/3+x,2/3+x-y,2/3+z'
  'y,x,-z'
  '2/3+y,1/3+x,1/3-z'
  '1/3+y,2/3+x,2/3-z'
  '-x+y,y,z'
  '2/3-x+y,1/3+y,1/3+z'
  '1/3-x+y,2/3+y,2/3+z'
  '-x,-x+y,-z'
  '2/3-x,1/3-x+y,1/3-z'
  '1/3-x,2/3-x+y,2/3-z'
  '-y,-x,z'
  '2/3-y,1/3-x,1/3+z'
  '1/3-y,2/3-x,2/3+z'
  'x-y,-y,-z'
  '2/3+x-y,1/3-y,1/3-z'
  '1/3+x-y,2/3-y,2/3-z'
  'y,-x+y,-z'
  '2/3+y,1/3-x+y,1/3-z'
  '1/3+y,2/3-x+y,2/3-z'
  '-x+y,-x,z'
  '2/3-x+y,1/3-x,1/3+z'
  '1/3-x+y,2/3-x,2/3+z'
  '-x,-y,-z'
  '2/3-x,1/3-y,1/3-z'
  '1/3-x,2/3-y,2/3-z'
  '-y,x-y,z'
  '2/3-y,1/3+x-y,1/3+z'
  '1/3-y,2/3+x-y,2/3+z'
  'x-y,x,-z'
  '2/3+x-y,1/3+x,1/3-z'
  '1/3+x-y,2/3+x,2/3-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
La1   0.00000   0.00000   0.00000   0.90000
Bi1   0.00000   0.00000   0.00000   0.10000
Bi2   0.00000   0.00000   0.22480   1.00000
O1   0.00000   0.00000   0.29960   1.00000
O2   0.00000   0.00000   0.09360   0.80000
O3   0.00000   0.00000   0.42380   0.27000
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
La1 0.00810 0.00210 0.02670 0.00410 0.00000 0.00000
Bi1 0.00810 0.00210 0.02670 0.00410 0.00000 0.00000
Bi2 0.02410 0.02410 0.01010 0.01210 0.00000 0.00000
O1 0.05760 0.05760 0.03310 0.02880 0.00000 0.00000
O2 0.05900 0.05900 0.03210 0.02950 0.00000 0.00000