K7 Nb14.13 O60 P8.87 Leclaire A, Benabbas A, Borel M, Grandin A, Raveau B Journal of Solid State Chemistry 83 (1989) 245-254 A Niobium Phosphate Bronze Closely Related to the ITB Tumgsten Bronzes: K7 Nb14+x P9-x O6$0 (x= 0.13) _cod_database_code 1001417 _database_code_amcsd 0013667 CELL PARAMETERS: 36.8830 10.6030 6.4526 90.000 90.000 90.000 SPACE GROUP: Pmma X-RAY WAVELENGTH: 1.541838 Cell Volume: 2523.421 Density (g/cm3): 3.713 MAX. ABS. INTENSITY / VOLUME**2: 18.97235985 RIR: 1.664 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 9.62 3.33 9.1920 2 1 0 4 13.72 3.48 6.4526 0 0 1 2 13.93 41.67 6.3561 1 0 1 4 14.41 2.33 6.1472 6 0 0 2 14.54 14.91 6.0905 2 0 1 4 15.51 13.60 5.7135 3 0 1 4 16.08 32.12 5.5121 0 1 1 4 16.26 6.07 5.4516 1 1 1 8 16.67 1.66 5.3181 6 1 0 4 16.72 11.64 5.3015 0 2 0 2 16.77 11.82 5.2867 4 0 1 4 17.63 5.63 5.0297 3 1 1 8 19.25 13.16 4.6104 8 0 0 2 19.31 2.73 4.5960 4 2 0 4 19.95 9.89 4.4508 6 0 1 4 21.70 27.28 4.0963 0 2 1 4 21.78 4.01 4.0812 7 0 1 4 21.83 2.28 4.0712 1 2 1 8 22.14 7.04 4.0147 6 2 0 4 22.23 3.38 3.9988 2 2 1 8 22.88 7.27 3.8862 3 2 1 8 23.36 9.73 3.8088 7 1 1 8 23.72 22.53 3.7512 8 0 1 4 23.77 1.60 3.7435 4 2 1 8 24.13 93.32 3.6883 10 0 0 2 25.18 7.78 3.5364 8 1 1 8 25.20 100.00 3.5343 0 3 0 2 25.61 9.98 3.4789 8 2 0 4 25.75 4.52 3.4594 9 0 1 4 27.58 6.82 3.2339 7 2 1 8 27.65 17.64 3.2263 0 0 2 2 27.86 3.00 3.2021 10 0 1 4 28.08 1.83 3.1780 2 0 2 4 28.60 4.12 3.1206 3 0 2 4 28.90 24.81 3.0889 1 3 1 8 28.93 21.34 3.0866 0 1 2 4 29.03 2.85 3.0758 1 1 2 8 29.05 3.89 3.0736 12 0 0 2 29.13 16.23 3.0654 10 1 1 8 29.21 4.29 3.0569 2 3 1 8 29.33 1.66 3.0453 4 0 2 4 29.34 12.26 3.0442 2 1 2 8 29.50 5.00 3.0277 10 2 0 4 29.72 9.43 3.0057 3 3 1 8 30.03 23.62 2.9753 11 0 1 4 30.42 4.35 2.9382 4 3 1 8 30.54 12.70 2.9269 4 1 2 8 31.22 3.16 2.8646 11 1 1 8 31.31 5.37 2.8567 6 0 2 4 31.91 3.00 2.8050 8 3 0 4 32.35 4.83 2.7678 6 3 1 8 32.46 4.08 2.7584 6 1 2 8 32.49 36.13 2.7561 0 2 2 4 32.54 1.09 2.7515 7 0 2 4 32.67 19.31 2.7409 10 2 1 8 32.86 7.57 2.7258 2 2 2 8 33.54 2.88 2.6717 7 3 1 8 33.82 4.63 2.6507 0 4 0 2 33.91 11.05 2.6433 8 0 2 4 33.95 1.02 2.6406 4 2 2 8 34.03 1.59 2.6345 14 0 0 2 34.53 3.91 2.5972 13 0 1 4 34.57 1.99 2.5946 11 2 1 8 34.88 10.76 2.5724 8 3 1 8 34.98 2.96 2.5648 8 1 2 8 35.17 26.67 2.5518 10 3 0 4 35.70 11.63 2.5149 6 2 2 8 36.55 1.14 2.4585 12 2 1 8 36.65 1.22 2.4519 0 4 1 4 36.73 3.54 2.4465 1 4 1 8 37.02 1.28 2.4284 10 0 2 4 37.40 2.19 2.4046 3 4 1 8 37.92 1.95 2.3730 10 3 1 8 38.04 10.77 2.3656 8 2 2 8 39.20 1.26 2.2980 8 4 0 4 39.21 1.15 2.2977 15 0 1 4 39.59 7.47 2.2761 11 3 1 8 40.87 4.38 2.2078 10 2 2 8 41.46 1.08 2.1779 12 1 2 8 41.60 1.22 2.1708 16 0 1 4 42.43 1.86 2.1305 13 0 2 4 42.64 5.99 2.1206 0 5 0 2 42.68 5.75 2.1187 3 0 3 4 42.72 1.06 2.1168 8 3 2 8 42.98 3.73 2.1045 1 1 3 8 43.56 1.34 2.0776 3 1 3 8 44.03 1.44 2.0565 17 0 1 4 44.20 11.85 2.0491 18 0 0 2 44.22 2.49 2.0481 0 4 2 4 44.36 3.25 2.0419 10 4 1 8 45.00 3.92 2.0146 0 5 1 4 45.07 1.12 2.0116 1 5 1 8 45.36 2.32 1.9994 4 4 2 8 45.51 1.30 1.9931 0 2 3 4 45.55 1.66 1.9913 7 0 3 4 45.58 1.69 1.9902 1 2 3 8 46.14 4.54 1.9674 3 2 3 8 46.40 7.82 1.9571 7 1 3 8 46.50 3.05 1.9530 18 0 1 4 47.24 1.26 1.9241 5 2 3 8 48.54 1.55 1.8756 16 0 2 4 48.65 1.04 1.8717 8 4 2 8 48.86 1.85 1.8642 7 2 3 8 49.26 1.76 1.8498 16 3 1 8 49.34 1.57 1.8469 16 1 2 8 49.42 10.87 1.8441 20 0 0 2 49.59 3.48 1.8384 10 5 0 4 49.68 1.88 1.8351 1 3 3 8 49.83 2.06 1.8301 10 1 3 8 50.20 8.45 1.8172 3 3 3 8 50.41 1.90 1.8104 11 0 3 4 51.00 2.67 1.7906 10 4 2 8 51.19 5.49 1.7846 11 1 3 8 51.41 3.80 1.7775 17 3 1 8 51.56 6.91 1.7727 18 3 0 4 51.58 11.58 1.7721 0 5 2 4 51.70 5.16 1.7680 10 5 1 8 51.73 12.47 1.7672 0 6 0 2 51.83 4.35 1.7640 2 5 2 8 51.94 1.11 1.7604 6 3 3 8 52.16 4.49 1.7534 10 2 3 8 52.31 1.03 1.7489 20 1 1 8 52.59 3.54 1.7402 4 5 2 8 52.76 1.76 1.7349 7 3 3 8 52.94 2.65 1.7297 18 0 2 4 53.03 3.25 1.7269 11 5 1 8 53.46 2.47 1.7140 13 0 3 4 53.48 3.19 1.7133 11 2 3 8 53.62 3.07 1.7094 18 3 1 8 53.69 10.21 1.7071 18 1 2 8 53.70 2.08 1.7068 8 3 3 8 53.84 3.82 1.7027 6 5 2 8 53.85 6.40 1.7026 1 6 1 8 54.12 8.23 1.6947 21 0 1 4 54.34 1.68 1.6883 3 6 1 8 54.57 2.12 1.6816 20 2 1 8 54.75 1.83 1.6765 22 0 0 2 54.98 1.30 1.6702 0 4 3 4 55.04 1.94 1.6685 1 4 3 8 55.53 1.40 1.6550 3 4 3 8 55.56 5.74 1.6541 8 5 2 8 55.92 10.08 1.6444 18 2 2 8 56.27 6.86 1.6350 20 3 0 4 56.42 2.07 1.6309 13 2 3 8 56.77 6.54 1.6217 7 6 1 8 56.95 1.43 1.6170 14 4 2 8 57.06 6.07 1.6142 21 2 1 8 57.10 10.85 1.6132 0 0 4 2 57.66 1.79 1.5987 8 6 1 8 57.72 1.35 1.5973 10 5 2 8 57.86 7.37 1.5937 10 6 0 4 57.87 1.22 1.5933 1 1 4 8 57.92 2.53 1.5921 7 4 3 8 58.28 1.49 1.5831 20 1 2 8 58.57 1.19 1.5759 5 0 4 4 59.72 1.10 1.5483 15 2 3 8 59.98 1.16 1.5422 13 3 3 8 60.00 1.02 1.5419 1 2 4 8 60.40 1.04 1.5327 20 2 2 8 60.60 6.11 1.5281 21 3 1 8 60.62 1.09 1.5275 17 0 3 4 60.89 1.68 1.5215 10 4 3 8 60.98 4.37 1.5194 11 6 1 8 61.19 1.81 1.5147 22 3 0 4 61.19 1.46 1.5147 0 7 0 2 61.32 1.75 1.5119 17 1 3 8 61.91 1.62 1.4988 3 5 3 8 62.88 4.53 1.4780 10 0 4 4 63.37 2.21 1.4678 17 2 3 8 63.38 5.64 1.4675 0 3 4 4 64.16 3.83 1.4516 7 5 3 8 64.31 2.50 1.4486 18 4 2 8 66.56 1.09 1.4049 16 5 2 8 66.71 2.50 1.4021 17 3 3 8 66.96 2.09 1.3975 10 5 3 8 68.10 3.06 1.3769 11 5 3 8 68.46 1.31 1.3705 20 4 2 8 68.80 1.27 1.3645 1 6 3 8 68.86 4.03 1.3635 10 3 4 8 69.04 2.28 1.3604 21 0 3 4 69.05 1.11 1.3603 20 5 1 8 69.23 1.95 1.3571 3 6 3 8 70.22 9.64 1.3404 18 5 2 8 70.23 2.08 1.3403 17 6 1 8 70.35 2.51 1.3382 18 6 0 4 70.67 1.33 1.3330 13 5 3 8 71.23 1.88 1.3239 21 5 1 8 71.25 1.52 1.3235 17 4 3 8 71.36 2.92 1.3218 7 6 3 8 71.61 3.76 1.3177 21 2 3 8 72.91 1.29 1.2975 1 8 1 8 73.36 1.09 1.2906 28 0 1 4 74.22 1.05 1.2778 20 5 2 8 74.34 4.28 1.2759 20 6 0 4 74.78 1.97 1.2696 21 3 3 8 74.92 2.30 1.2675 18 0 4 4 76.92 1.48 1.2394 17 5 3 8 78.03 1.47 1.2246 10 8 1 8 78.39 1.12 1.2198 7 2 5 8 78.67 1.96 1.2163 22 6 0 4 78.83 2.09 1.2142 20 0 4 4 78.97 1.63 1.2123 28 3 1 8 79.03 1.84 1.2116 1 3 5 8 79.60 1.93 1.2044 11 0 5 4 80.50 1.87 1.1931 18 3 4 8 80.64 2.34 1.1914 0 6 4 4 81.74 1.37 1.1781 0 9 0 2 82.43 1.44 1.1701 31 0 1 4 83.44 1.23 1.1584 1 9 1 8 83.69 1.26 1.1556 17 6 3 8 84.34 1.99 1.1483 20 3 4 8 84.64 1.47 1.1450 21 5 3 8 85.10 2.39 1.1400 11 3 5 8 85.69 2.09 1.1337 10 6 4 8 86.64 1.20 1.1236 3 8 3 8 86.78 1.65 1.1223 10 9 0 4 87.83 1.13 1.1115 14 8 2 8 88.19 1.69 1.1079 28 4 2 8 88.65 2.41 1.1033 7 8 3 8 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.