data_global
_amcsd_formula_title 'Mo3 Na O16 P3'
loop_
_publ_author_name
'Costentin G'
'Borel M'
'Grandin A'
'Leclaire A'
'Raveau B'
_journal_name_full 'Journal of Solid State Chemistry'
_journal_volume 95 
_journal_year 1991
_journal_page_first 168
_journal_page_last 175
_publ_section_title
;
 A molybdenophosphate with a mixed valence of molybdenum,
 Mo(VI)-Mo(V): NaMo3P3O16
 _cod_database_code 1001730
;
_database_code_amcsd 0013721
_chemical_formula_sum 'Mo3 P3 Na O16'
_cell_length_a 6.4023
_cell_length_b 7.6097
_cell_length_c 12.7395
_cell_angle_alpha 80.031
_cell_angle_beta 79.039
_cell_angle_gamma 83.517
_cell_volume 598.083
_exptl_crystal_density_diffrn      3.663
_symmetry_space_group_name_H-M 'P -1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '-x,-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
Mo1   0.20382   0.21539   0.54109
Mo2   0.40953   0.75135   0.16255
Mo3   0.05866   0.20623   0.14284
P1   0.57260   0.16560   0.10260
P2   0.30770   0.85430   0.42100
P3   0.06450   0.48180   0.31660
Na1   0.59810   0.33330   0.33160
O1   0.19220   0.04980   0.64510
O2  -0.10020   0.22380   0.52160
O3   0.51790   0.25670   0.52200
O4   0.30390   0.05250   0.42780
O5   0.13660   0.42490   0.62240
O6   0.22690   0.40940   0.38920
O7   0.08720   0.31300   0.01630
O8  -0.02060   0.32980   0.27350
O9  -0.25870   0.20280   0.16650
O10   0.12660  -0.01450   0.13440
O11   0.35750   0.23840   0.16300
O12   0.60570   0.59520   0.18210
O13   0.37700   0.73290   0.01200
O14   0.16030   0.60640   0.21600
O15   0.35420   0.84080   0.30120
O16   0.57720   0.96520   0.10150