Mo3 Na O16 P3 Costentin G, Borel M, Grandin A, Leclaire A, Raveau B Journal of Solid State Chemistry 95 (1991) 168-175 A molybdenophosphate with a mixed valence of molybdenum, Mo(VI)-Mo(V): NaMo3P3O16 _cod_database_code 1001730 _database_code_amcsd 0013721 CELL PARAMETERS: 6.4023 7.6097 12.7395 80.031 79.039 83.517 SPACE GROUP: P-1 X-RAY WAVELENGTH: 1.541838 Cell Volume: 598.083 Density (g/cm3): 3.663 MAX. ABS. INTENSITY / VOLUME**2: 11.94244821 RIR: 1.062 RIR based on corundum from Acta Crystallographica A38 (1982) 733-739 2-THETA INTENSITY D-SPACING H K L Multiplicity 7.15 5.53 12.3550 0 0 1 2 11.85 15.13 7.4691 0 1 0 2 12.86 2.34 6.8832 0 1 1 2 14.34 1.22 6.1775 0 0 2 2 14.70 50.80 6.0267 1 0 1 2 16.95 1.57 5.2312 -1 0 1 2 17.15 2.67 5.1715 0 1 2 2 17.41 1.29 5.0931 1 1 1 2 17.71 7.36 5.0078 1 1 0 2 18.33 13.05 4.8405 1 0 2 2 19.23 1.27 4.6152 -1 1 0 2 19.92 98.36 4.4574 1 1 2 2 20.03 58.68 4.4338 0 -1 2 2 20.32 4.71 4.3701 1 -1 1 2 20.70 81.32 4.2914 -1 -1 1 2 20.76 59.16 4.2783 -1 1 1 2 21.58 84.24 4.1183 0 0 3 2 21.90 10.12 4.0589 -1 0 2 2 22.98 5.67 3.8698 0 1 3 2 23.69 67.99 3.7561 1 -1 2 2 23.70 3.62 3.7548 1 0 3 2 23.79 2.81 3.7394 0 2 1 2 23.83 100.00 3.7346 0 2 0 2 24.41 1.72 3.6463 1 1 3 2 24.45 2.43 3.6412 -1 1 2 2 25.48 4.23 3.4958 -1 -1 2 2 25.89 56.61 3.4416 0 2 2 2 25.98 1.35 3.4302 0 -2 1 2 26.29 18.43 3.3905 0 -1 3 2 26.76 2.31 3.3312 1 2 0 2 28.15 23.53 3.1704 2 0 1 2 28.50 1.10 3.1320 2 0 0 2 28.58 8.76 3.1235 1 -1 3 2 28.83 1.63 3.0970 -1 2 0 2 28.91 17.74 3.0888 0 0 4 2 29.43 3.02 3.0348 -1 2 1 2 29.53 35.94 3.0252 0 1 4 2 29.53 5.09 3.0246 -1 1 3 2 29.65 25.11 3.0134 2 0 2 2 29.69 53.01 3.0090 0 2 3 2 29.82 7.81 2.9964 0 -2 2 2 29.94 1.88 2.9843 1 0 4 2 30.01 58.38 2.9775 2 1 0 2 30.05 1.84 2.9742 1 -2 1 2 30.07 3.21 2.9723 1 1 4 2 30.21 5.50 2.9586 2 1 2 2 30.65 21.25 2.9172 -2 0 1 2 31.76 14.86 2.8172 -1 2 2 2 31.88 25.31 2.8067 -2 1 0 2 32.00 22.41 2.7967 2 -1 1 2 32.50 1.55 2.7553 -2 -1 1 2 32.86 2.97 2.7255 2 1 3 2 32.90 1.69 2.7224 1 -2 2 2 33.06 5.07 2.7094 0 -1 4 2 33.38 14.06 2.6841 -1 -2 2 2 33.76 4.42 2.6550 2 -1 2 2 34.78 20.78 2.5794 2 2 1 2 34.85 27.11 2.5745 0 -2 3 2 35.49 1.78 2.5294 -1 1 4 2 35.66 1.03 2.5176 0 3 1 2 35.86 5.93 2.5039 2 2 0 2 36.08 7.22 2.4897 0 3 0 2 36.42 14.04 2.4672 1 1 5 2 36.43 7.05 2.4661 -2 1 2 2 36.48 3.99 2.4629 0 1 5 2 36.70 1.13 2.4490 1 0 5 2 36.85 1.80 2.4390 2 1 4 2 36.86 3.52 2.4387 1 3 1 2 36.95 1.89 2.4327 2 -1 3 2 37.15 14.70 2.4202 2 0 4 2 37.42 8.33 2.4030 1 3 2 2 37.76 7.24 2.3824 -1 -1 4 2 37.76 1.73 2.3823 1 3 0 2 38.49 3.55 2.3389 -1 -2 3 2 39.27 2.11 2.2944 0 3 3 2 39.49 4.74 2.2818 2 -2 1 2 40.06 6.92 2.2509 -1 -3 1 2 40.16 5.35 2.2452 -1 3 1 2 40.18 10.20 2.2442 0 -1 5 2 40.47 17.54 2.2287 2 2 4 2 40.52 2.63 2.2262 0 2 5 2 40.63 6.85 2.2204 -2 1 3 2 40.86 4.14 2.2084 1 -1 5 2 41.14 2.69 2.1940 0 -3 2 2 41.26 6.36 2.1879 -2 -1 3 2 41.29 6.59 2.1864 2 -1 4 2 41.56 4.99 2.1729 -1 0 5 2 41.62 2.14 2.1697 -1 3 2 2 42.03 3.46 2.1497 -1 1 5 2 42.11 3.40 2.1457 -2 -2 2 2 42.25 1.37 2.1391 -2 2 2 2 42.65 3.10 2.1197 1 3 4 2 42.97 5.17 2.1049 0 3 4 2 43.03 7.63 2.1019 3 1 1 2 43.24 4.70 2.0921 1 1 6 2 43.25 12.49 2.0918 3 0 2 2 43.40 1.89 2.0851 2 3 2 2 43.75 1.18 2.0692 0 1 6 2 43.87 7.62 2.0636 1 -3 2 2 43.97 9.30 2.0592 0 0 6 2 44.06 2.70 2.0555 3 1 0 2 44.34 4.10 2.0431 -1 3 3 2 44.37 1.78 2.0416 -1 -2 4 2 44.58 6.55 2.0326 2 3 0 2 44.67 1.80 2.0285 -1 -1 5 2 44.73 1.92 2.0259 2 3 3 2 44.86 1.58 2.0203 3 1 3 2 45.29 11.08 2.0022 -3 0 1 2 45.40 5.76 1.9976 0 -3 3 2 45.68 3.94 1.9859 -2 2 3 2 45.76 2.11 1.9830 3 -1 1 2 45.76 2.08 1.9829 -2 1 4 2 46.00 7.61 1.9731 -1 2 5 2 46.10 1.77 1.9691 -3 1 0 2 46.15 3.11 1.9669 1 2 6 2 46.53 1.44 1.9517 2 -1 5 2 46.82 12.11 1.9405 3 2 2 2 46.83 8.41 1.9400 -2 -2 3 2 46.94 9.54 1.9356 1 3 5 2 46.96 8.11 1.9349 0 2 6 2 47.15 1.38 1.9275 0 -2 5 2 47.60 4.99 1.9105 3 1 4 2 48.08 7.34 1.8925 1 -2 5 2 48.13 3.63 1.8904 -1 3 4 2 48.16 1.33 1.8894 3 0 4 2 48.47 1.59 1.8781 2 -2 4 2 48.49 2.46 1.8774 2 0 6 2 48.56 3.69 1.8749 -2 3 0 2 48.70 7.32 1.8697 0 4 2 2 48.76 1.02 1.8676 1 4 1 2 48.77 6.48 1.8673 0 4 0 2 49.05 4.39 1.8571 -2 3 1 2 49.25 4.29 1.8501 2 -3 1 2 50.43 4.27 1.8097 0 4 3 2 50.54 10.93 1.8058 -3 -2 1 2 50.85 2.42 1.7957 -1 -2 5 2 50.91 3.05 1.7938 -2 0 5 2 51.09 2.84 1.7877 2 -3 2 2 51.31 7.91 1.7808 0 1 7 2 51.62 1.09 1.7708 -2 1 5 2 51.80 6.17 1.7650 0 0 7 2 51.94 1.71 1.7604 -1 -4 1 2 52.06 1.33 1.7568 -1 4 1 2 52.09 2.53 1.7558 1 3 6 2 52.11 1.32 1.7551 1 -3 4 2 52.19 2.39 1.7526 3 0 5 2 52.97 2.29 1.7285 -1 4 2 2 53.00 6.74 1.7279 3 -2 2 2 53.05 5.51 1.7261 -3 2 1 2 53.38 1.80 1.7163 -1 -3 4 2 53.42 2.84 1.7151 0 -4 2 2 53.44 6.81 1.7146 -2 3 3 2 53.58 1.36 1.7105 3 3 1 2 53.59 1.17 1.7101 1 -4 1 2 53.63 1.48 1.7091 3 2 5 2 53.81 2.14 1.7037 2 4 1 2 53.89 1.64 1.7012 0 2 7 2 54.01 1.95 1.6977 3 3 3 2 54.03 1.03 1.6972 2 1 7 2 54.10 2.47 1.6952 0 -2 6 2 54.56 3.49 1.6819 1 -2 6 2 54.97 5.25 1.6705 -2 -3 3 2 55.01 1.72 1.6693 3 3 0 2 55.09 2.26 1.6670 2 0 7 2 55.13 1.92 1.6659 -1 -4 2 2 55.14 3.24 1.6656 2 4 0 2 55.18 1.19 1.6645 3 -2 3 2 55.27 1.82 1.6619 -3 2 2 2 55.31 1.11 1.6609 0 -1 7 2 55.95 4.45 1.6434 2 2 7 2 55.98 2.80 1.6427 1 -4 2 2 56.01 2.33 1.6419 3 -1 5 2 56.37 10.54 1.6323 2 4 4 2 56.39 2.48 1.6316 0 -3 5 2 57.01 5.22 1.6154 0 4 5 2 57.08 2.87 1.6135 3 0 6 2 57.25 3.70 1.6092 0 -4 3 2 57.42 4.33 1.6049 -3 0 4 2 57.48 1.23 1.6032 -3 -3 1 2 57.50 1.79 1.6029 1 -3 5 2 57.86 2.86 1.5937 2 -3 4 2 57.90 1.38 1.5928 3 2 6 2 58.05 6.59 1.5888 1 1 8 2 58.07 4.37 1.5885 4 0 1 2 58.09 3.83 1.5879 -2 1 6 2 58.10 10.49 1.5877 4 1 1 2 58.20 1.11 1.5852 4 0 2 2 58.36 3.49 1.5811 3 -2 4 2 58.49 2.01 1.5780 -3 2 3 2 59.04 4.08 1.5647 2 -1 7 2 59.06 1.34 1.5642 1 0 8 2 59.28 5.33 1.5587 0 3 7 2 59.34 1.71 1.5574 1 -4 3 2 59.37 2.25 1.5567 4 0 3 2 59.40 2.67 1.5560 -1 -3 5 2 60.18 6.15 1.5377 -2 -1 6 2 60.80 5.66 1.5235 4 1 4 2 60.86 1.40 1.5221 -2 -4 2 2 60.87 4.04 1.5219 4 -1 1 2 60.93 1.79 1.5206 -3 3 1 2 60.96 2.50 1.5199 3 -1 6 2 61.19 2.04 1.5147 4 2 3 2 61.47 2.66 1.5085 1 5 2 2 61.47 1.19 1.5084 -4 -1 1 2 61.50 4.04 1.5078 0 -2 7 2 61.56 1.17 1.5065 0 5 2 2 61.65 2.76 1.5045 0 4 6 2 61.92 7.90 1.4985 -1 4 5 2 61.97 3.26 1.4974 3 4 2 2 62.14 3.14 1.4938 0 5 0 2 62.22 1.78 1.4922 2 0 8 2 62.51 6.10 1.4858 3 3 6 2 62.61 5.80 1.4838 -3 2 4 2 62.66 2.75 1.4827 4 -1 3 2 62.78 2.42 1.4800 0 5 3 2 62.83 2.50 1.4790 1 -1 8 2 63.13 2.00 1.4727 -4 1 1 2 63.25 1.73 1.4703 -2 4 3 2 63.48 6.76 1.4654 -3 -2 4 2 63.91 1.11 1.4567 3 -3 3 2 64.46 2.07 1.4455 1 3 8 2 64.61 3.01 1.4426 -4 -1 2 2 64.63 5.27 1.4422 -1 0 8 2 64.86 2.34 1.4376 -1 -5 1 2 64.98 2.15 1.4352 -1 5 1 2 64.99 1.13 1.4351 0 5 4 2 65.08 2.62 1.4331 -2 -4 3 2 65.41 1.89 1.4269 4 2 5 2 65.42 1.67 1.4267 -1 5 0 2 65.54 1.03 1.4244 2 -2 7 2 65.72 1.74 1.4208 -4 1 2 2 66.04 1.39 1.4147 1 1 9 2 66.04 1.28 1.4146 -1 -3 6 2 66.26 1.75 1.4106 3 4 5 2 66.29 1.23 1.4099 4 -2 1 2 66.44 3.59 1.4071 4 3 1 2 66.49 3.59 1.4063 -1 2 8 2 66.61 5.60 1.4040 -3 -4 1 2 67.03 3.21 1.3962 1 5 5 2 67.05 1.13 1.3959 -1 5 3 2 67.08 1.35 1.3952 3 -3 4 2 67.09 2.24 1.3952 -2 3 6 2 67.36 1.10 1.3901 3 -2 6 2 67.40 1.24 1.3895 0 -4 5 2 67.47 2.31 1.3881 4 3 4 2 67.58 3.01 1.3861 -2 -1 7 2 67.61 1.76 1.3857 -4 0 3 2 67.71 4.43 1.3839 -1 -1 8 2 67.85 3.94 1.3814 2 4 7 2 67.90 1.29 1.3803 -1 -5 2 2 67.96 1.66 1.3793 -4 2 1 2 68.43 1.27 1.3710 2 1 9 2 68.65 2.22 1.3671 1 -4 5 2 69.05 1.24 1.3602 3 0 8 2 69.57 1.62 1.3513 3 4 6 2 70.29 3.63 1.3391 0 -5 3 2 70.84 2.83 1.3301 -3 4 1 2 71.83 1.19 1.3143 -1 -5 3 2 72.20 2.27 1.3084 -2 5 1 2 72.46 2.21 1.3043 4 -1 6 2 72.79 2.67 1.2993 3 5 3 2 72.81 1.05 1.2990 -2 -3 6 2 73.04 1.12 1.2955 3 -2 7 2 73.28 1.13 1.2917 -1 -2 8 2 73.56 1.46 1.2875 -4 1 4 2 73.58 1.77 1.2872 0 -4 6 2 73.98 1.80 1.2813 -4 -3 2 2 74.42 1.89 1.2748 3 1 9 2 75.17 2.12 1.2639 -4 3 1 2 75.20 1.31 1.2636 1 6 2 2 75.26 2.34 1.2626 2 -5 2 2 75.33 1.49 1.2617 3 2 9 2 76.04 2.60 1.2516 3 0 9 2 76.11 1.45 1.2506 0 1 10 2 76.46 1.74 1.2458 4 4 5 2 76.51 4.26 1.2452 -3 0 7 2 76.63 1.46 1.2434 4 -3 3 2 77.51 1.31 1.2315 0 2 10 2 77.53 1.81 1.2312 4 1 8 2 77.65 1.02 1.2296 -3 -5 1 2 77.78 1.68 1.2279 3 -4 4 2 78.49 1.08 1.2185 5 2 0 2 78.82 2.82 1.2144 3 5 6 2 78.92 1.88 1.2130 2 -4 6 2 79.40 1.13 1.2069 -3 -4 4 2 79.69 1.28 1.2033 1 -1 10 2 79.78 1.37 1.2021 -1 6 0 2 80.48 1.48 1.1934 0 -4 7 2 81.18 1.23 1.1848 -1 -3 8 2 82.88 1.15 1.1648 1 6 6 2 83.63 1.36 1.1562 -4 3 4 2 83.74 1.61 1.1550 1 -6 2 2 83.81 1.07 1.1543 4 5 4 2 83.89 2.25 1.1534 -4 0 6 2 83.99 1.62 1.1523 4 -4 1 2 84.69 1.10 1.1445 3 -5 2 2 85.63 1.20 1.1343 -1 6 5 2 85.72 1.74 1.1334 1 -3 9 2 86.08 1.36 1.1295 3 6 1 2 86.64 1.83 1.1237 3 -2 9 2 86.82 1.02 1.1218 -3 4 6 2 87.18 1.97 1.1181 4 -3 6 2 87.55 1.05 1.1144 4 4 8 2 ================================================================================ XPOW Copyright 1993 Bob Downs, Ranjini Swaminathan and Kurt Bartelmehs For reference, see Downs et al. (1993) American Mineralogist 78, 1104-1107.