data_global _amcsd_formula_title 'KV3P4O17' loop_ _publ_author_name 'Benhamada L' 'Grandin A' 'Borel M' 'Leclaire A' 'Raveau B' _journal_name_full 'Journal of Solid State Chemistry' _journal_volume 97 _journal_year 1992 _journal_page_first 131 _journal_page_last 140 _publ_section_title ; A new mixed-valence vanadium phosphate with an intersecting tunnel structure: KV3P4O17 _cod_database_code 1001593 ; _database_code_amcsd 0013732 _chemical_formula_sum 'V3 P4 K O17' _cell_length_a 7.8654 _cell_length_b 10.0104 _cell_length_c 16.2715 _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_volume 1281.150 _exptl_crystal_density_diffrn 3.048 _symmetry_space_group_name_H-M 'P 21 21 21' loop_ _space_group_symop_operation_xyz 'x,y,z' '-x,1/2+y,1/2-z' '1/2+x,1/2-y,-z' '1/2-x,-y,1/2+z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z V1 0.78800 0.32220 0.15290 V2 0.29100 0.24730 0.49400 V3 0.28460 0.31850 0.15210 P1 0.19120 0.63570 0.18600 P2 0.19970 0.56140 0.46550 P3 0.19020 0.13680 0.31430 P4 0.19200 0.06070 0.03670 K1 0.50400 0.45530 0.32140 O1 0.99800 0.33200 0.16310 O2 0.72900 0.24800 0.26600 O3 0.48600 0.31200 0.14420 O4 0.76000 0.13700 0.11100 O5 0.71700 0.50300 0.19800 O6 0.77700 0.38200 0.04200 O7 0.31300 0.32700 0.59580 O8 0.25800 0.08400 0.55200 O9 0.48300 0.22900 0.46400 O10 0.25400 0.41400 0.44700 O11 0.17700 0.17300 0.40600 O12 0.27400 0.50200 0.20000 O13 0.22300 0.39000 0.04000 O14 0.26600 0.24700 0.26500 O15 0.22800 0.13500 0.11500 O16 0.00200 0.62100 0.21560 O17 0.00300 0.56000 0.48100