data_global _amcsd_formula_title 'Ag4 H20 K6 O40 P10' loop_ _publ_author_name 'Averbuch-Pouchot M' 'Durif A' 'Schuelke U' _journal_name_full 'Journal of Solid State Chemistry' _journal_volume 97 _journal_year 1992 _journal_page_first 299 _journal_page_last 304 _publ_section_title ; Silver-potassium cyclodecaphosphate decahydrate, Ag4K6P10O30.10H2O: a new example of a phosphoric 10-member ring anion _cod_database_code 1007220 ; _database_code_amcsd 0015902 _chemical_formula_sum 'Ag2 K3 P5 O20' _cell_length_a 14.267 _cell_length_b 7.305 _cell_length_c 10.319 _cell_angle_alpha 105.38 _cell_angle_beta 101.03 _cell_angle_gamma 87.51 _cell_volume 1017.751 _exptl_crystal_density_diffrn 2.636 _symmetry_space_group_name_H-M 'P -1' loop_ _space_group_symop_operation_xyz 'x,y,z' '-x,-y,-z' loop_ _atom_site_label _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z Ag1 0.05641 0.30269 0.44820 Ag2 0.85582 0.79115 0.83806 K1 0.90610 0.38660 0.05380 K2 0.23880 0.67560 0.64270 K3 0.52070 0.72700 0.18670 P1 -0.09370 0.30930 0.67270 P2 -0.04590 -0.05970 0.20200 P3 0.21440 0.20490 0.73640 P4 0.29180 0.19170 0.49480 P5 0.27130 0.82810 0.28260 O1 0.07460 0.64660 0.45270 O2 0.03700 0.87960 0.31200 O3 0.79810 0.23460 0.63080 O4 0.07980 0.54120 0.19580 O5 -0.02320 0.13900 0.20770 O6 0.06230 0.21020 0.92910 O7 0.13540 0.04680 0.72340 O8 0.16900 0.38730 0.72510 O9 0.70760 0.80090 0.14600 O10 0.74800 0.90190 0.40140 O11 0.21160 0.28070 0.41820 O12 0.37610 0.30830 0.56940 O13 0.21290 0.88930 0.16580 O14 0.65460 0.31900 0.74400 O15 0.32580 0.00510 0.39670 O16 0.69710 0.69650 0.86730 O17 0.55350 0.34000 0.09240 O18 0.72330 0.14370 0.07220 O19 0.58670 0.33750 0.45480 O20 0.47060 0.10860 0.22260 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 Ag1 0.03100 0.02610 0.03610 -0.00130 0.01350 0.00370 Ag2 0.03530 0.02740 0.02240 0.00680 0.00440 0.01080 K1 0.03040 0.02200 0.01660 0.00080 0.00500 0.00320 K2 0.04340 0.02630 0.02510 -0.00130 0.00180 0.00820 K3 0.02850 0.03800 0.03670 0.00170 0.00530 0.01100 P1 0.01920 0.01270 0.01410 0.00000 0.00330 0.00460 P2 0.02210 0.01310 0.01310 0.00050 0.00370 0.00540 P3 0.02470 0.01560 0.01700 0.00070 0.00820 0.00310 P4 0.02760 0.01560 0.01570 0.00030 0.00700 0.00330 P5 0.02100 0.01640 0.01640 -0.00060 0.00600 0.00390 O1 0.03100 0.02500 0.01800 -0.00100 0.00800 0.01000 O2 0.03200 0.01500 0.01600 0.00600 -0.00100 0.00300 O3 0.02100 0.02900 0.01800 -0.00400 0.00400 0.01000 O4 0.02900 0.01500 0.01900 0.00100 0.00300 -0.00300 O5 0.03900 0.01700 0.02400 0.00000 0.00600 0.01300 O6 0.03500 0.02200 0.01200 0.00200 0.00400 0.00200 O7 0.02300 0.01700 0.02800 0.00100 0.01100 0.00300 O8 0.04400 0.01600 0.03300 0.00700 0.01700 0.00500 O9 0.02800 0.04500 0.02400 -0.00300 0.00100 0.00700 O10 0.04400 0.02000 0.02300 0.00400 0.02100 0.00500 O11 0.03900 0.03800 0.02300 0.01400 0.01200 0.01600 O12 0.04300 0.02900 0.02700 -0.01100 0.00500 0.00200 O13 0.04100 0.02400 0.01500 -0.00100 0.00500 0.00600 O14 0.02900 0.02200 0.02800 0.00400 0.01100 0.00000 O15 0.02200 0.01600 0.02300 -0.00200 0.00700 0.00100 O16 0.04800 0.02800 0.03400 -0.00400 0.01300 0.00200 O17 0.06800 0.04700 0.04900 0.01100 0.02100 0.01700 O18 0.05800 0.03500 0.02100 0.00900 0.00900 0.00700 O19 0.04900 0.04000 0.05200 0.00300 0.00600 0.01900 O20 0.05800 0.04100 0.06000 0.00400 0.02000 0.01500